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Volumn 45, Issue 25, 2006, Pages 4134-4137

High-nuclearity, high-symmetry, high-spin molecules: A mixed-valence Mn10 cage possessing rare T symmetry and an S = 22 ground state

Author keywords

Azides; Cluster compounds; Magnetic properties; Manganese; N,O ligands

Indexed keywords

CRYSTAL SYMMETRY; FERROMAGNETIC MATERIALS; GROUND STATE; MAGNETIC PROPERTIES;

EID: 33746291093     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600691     Document Type: Article
Times cited : (146)

References (31)
  • 3
    • 0034595262 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2000, 39, 1605-1609.
    • (2000) Angew. Chem. Int. Ed. , vol.39 , pp. 1605-1609
  • 18
    • 33746274830 scopus 로고    scopus 로고
    • note
    • int = 0.0582), R1 = 0.0351 and wR2 = 0.0840, based on 1755 reflections with I > 2σ(I);
  • 19
    • 33746304300 scopus 로고    scopus 로고
    • b) CCDC-298873 and CCDC-298874 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
  • 20
    • 33746281903 scopus 로고    scopus 로고
    • note
    • a) Bond-valence-sum (BVS) calculations for the Mn ions of 1 gave values of 1.98 (for Mn1) and 2.97 (for Mn2);
  • 25
    • 33746298842 scopus 로고    scopus 로고
    • note
    • The magnetic behavior of the two complexes is similar. As a result of the high yield of complex 2 (compared to that of 1), magnetic data are presented only for the former cluster.
  • 29
    • 0041863979 scopus 로고    scopus 로고
    • Angew. Chem. Int. Ed. 2003, 42, 3781-3784.
    • (2003) Angew. Chem. Int. Ed. , vol.42 , pp. 3781-3784
  • 31


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.