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Volumn 692, Issue 15, 2007, Pages 3300-3305

Electrochemical reduction of Ru(η6-arene)(κ3-tris(pyrazolyl)methane) dicationic complexes

Author keywords

19 Electron radical; Dimerization; Electrochemistry; Hapticity changes; Reduction; Ruthenium arene; tris(Pyrazolyl)methane

Indexed keywords

COMPLEXATION; DIMERIZATION; ELECTROCHEMISTRY; ELECTRON TRANSPORT PROPERTIES; LIGANDS; ORGANOMETALLICS; REDUCTION;

EID: 34250207377     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2006.12.016     Document Type: Short Survey
Times cited : (7)

References (29)
  • 16
    • 34250222295 scopus 로고    scopus 로고
    • note
    • 2+, a compound with essentially the same size to charge ratio.
  • 19
    • 34250213454 scopus 로고    scopus 로고
    • note
    • + is actually second-order in complex.
  • 24
    • 34250223272 scopus 로고    scopus 로고
    • note
    • Transfer coefficients are defined using α for reductions and β(=1 - α) for oxidations. The oxidation of the Rh complex was determined to have a β value of 0.33 [1c]. Important to the present argument is the fact that redox couples in which bond making and breaking are concomitant with electron transfer generally do not have α values close to 0.5, which would imply a transition state structure midway between reactant and product. See Ref. [8, pp. 97-98], for a discussion of transfer coefficients.
  • 25
    • 34250199947 scopus 로고    scopus 로고
    • note
    • p values were measured if the Au electrode was replaced by a Pt electrode. Freshly re-polished gold electrodes did, however, give reproducible results.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.