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To the best of our knowledge, the only examples of desulfitative C-C cross-couplings of organosulfur compounds containing thiol groups involve Ni-catalyzed Kumada-type couplings of thiophenols with Grignard reagents: E. Wenkert, T. W. Ferreira, E. L. Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637-638.
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To the best of our knowledge, the only examples of desulfitative C-C cross-couplings of organosulfur compounds containing thiol groups involve Ni-catalyzed Kumada-type couplings of thiophenols with Grignard reagents: E. Wenkert, T. W. Ferreira, E. L. Michelotti, J. Chem. Soc., Chem. Commun. 1979, 637-638.
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We have additionally evaluated the scope of boronic acid diversity in a series of couplings involving 3-cyano-4-(4-methoxyphenyl)-5,6,7,8- tetrahydroquinoline2(1H)-thione (Table 1, entry 4) and have confirmed that satisfactory yields of cross-coupling products were obtained for a range of diverse arylboronic acids see the Supporting Information for details
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We have additionally evaluated the scope of boronic acid diversity in a series of couplings involving 3-cyano-4-(4-methoxyphenyl)-5,6,7,8- tetrahydroquinoline2(1H)-thione (Table 1, entry 4) and have confirmed that satisfactory yields of cross-coupling products were obtained for a range of diverse arylboronic acids (see the Supporting Information for details).
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