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In principle, EN can be determined by a linear extrapolation of the charge density plot for the monolayer covered electrode (Figure 3) to σM, 0 and then the product C1EN could be calculated. Such extrapolation is very long, and its uncertainty may be large. However, since the σM vs E plot is assumed to be linear and its slope is C1, the product C1EN is equal to the negative of the experimental value of σM for the film-covered electrode at Epzc0 (C1EN, σMEpzc0
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