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Volumn 40, Issue 10, 2007, Pages 3530-3532

Recognition of solution structures of peptides by molecularly imprinted cyclodextrin polymers

Author keywords

[No Author keywords available]

Indexed keywords

BIOACTIVITY; CONFORMATIONS; CYCLODEXTRINS; MONOMERS; POLYMERIZATION;

EID: 34249654022     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma070348f     Document Type: Article
Times cited : (39)

References (31)
  • 6
    • 0028873867 scopus 로고
    • For conventional molecular imprinting, see the following references: a
    • For conventional molecular imprinting, see the following references: (a) Wulff, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 1812.
    • (1995) Angew. Chem., Int. Ed. Engl , vol.34 , pp. 1812
    • Wulff, G.1
  • 14
    • 34249670651 scopus 로고    scopus 로고
    • Nishino, H.; Huang, C.-S.; Shea, K. J. Angew. Chem. 2006, 118, 2452; Angew. Chem., Int. Ed. 2006, 45, 2392.
    • (c) Nishino, H.; Huang, C.-S.; Shea, K. J. Angew. Chem. 2006, 118, 2452; Angew. Chem., Int. Ed. 2006, 45, 2392.
  • 17
    • 34249737949 scopus 로고    scopus 로고
    • Reviews on CyDs: (a) Bender, M. L.; Komiyama, M. Cyclodextrin Chemistry; Springer-Verlag: Berlin, 1978.
    • Reviews on CyDs: (a) Bender, M. L.; Komiyama, M. Cyclodextrin Chemistry; Springer-Verlag: Berlin, 1978.
  • 21
    • 0033528625 scopus 로고    scopus 로고
    • Previous molecular imprinting of CyD: (a) Hishiya, T.; Shibata, M.; Kakazu, M.; Asanuma, H.; Komiyama, M. Macromolecules 1999, 32, 2265.
    • Previous molecular imprinting of CyD: (a) Hishiya, T.; Shibata, M.; Kakazu, M.; Asanuma, H.; Komiyama, M. Macromolecules 1999, 32, 2265.
  • 26
    • 34249684263 scopus 로고    scopus 로고
    • Acrylamido groups were introduced to the surface of silica gel (Nucleosil 300-10 from Macherey-Nagel; specific surface area 100 m2 g -1) by treating the silica gel with acrylamidopropyltriethoxylsilane in xylene.7e According to the titration with KMnQ4, about 140 μmol of vinyl groups was introduced to 1 g of the silica gel (this corresponds to ∼1 acrylamidopropyl group per 1 nm2, In the presence of this vinylated silica gel (600 mg) and template oligopeptide (7.5 μmol, 6-AAm-β-CyD (30 μmol) and MBAAm (180/μmol) were polymerized at 35 °C under nitrogen for 20 h by the combination of potassium persulfate (3 mg) and N,N,N′,N′-tetramethylethylenediamine 3 μL, About 50 mg of β-CyD polymer was bound to 1 g of the silica gel, as determined by the weight loss observed upon its combustion under air. There exists 1 β-CyD molecule in ∼4 nm2 of the surface of the silica gel
    • -1. The capacity factor k was determined by using acetone as void marker.
  • 27
    • 34249698969 scopus 로고    scopus 로고
    • Nonimprinted polymer bound AI also more strongly than AII, although the difference is far smaller. The solution structure of AI would be more favorable for nonspecific apolar interactions with the polymer/silica gel composites
    • Nonimprinted polymer bound AI also more strongly than AII, although the difference is far smaller. The solution structure of AI would be more favorable for nonspecific apolar interactions with the polymer/silica gel composites.
  • 28
    • 34249698644 scopus 로고    scopus 로고
    • At pH 3, AI should take a stretching structure because of accumulated positive charges
    • At pH 3, AI should take a stretching structure because of accumulated positive charges.
  • 30
    • 0020475449 scopus 로고    scopus 로고
    • The hydropathy indexes of the side chains of He and Val are 4.5 and 4.2, respectively (Kyte, J.; Doolittle, R. F. J. Mol Biol. 1982, 157, 105).
    • The hydropathy indexes of the side chains of He and Val are 4.5 and 4.2, respectively (Kyte, J.; Doolittle, R. F. J. Mol Biol. 1982, 157, 105).
  • 31
    • 0020604052 scopus 로고    scopus 로고
    • 6 (Fermandjian, S.; Sakarellos, C; Piriou, F.; Juy, M.; Toma, F.; Thanh, H. L.; Lintner, K.; Khosla, M. C.; Smeby, R. R.; Bumpus, F. M. Biopolymers 1983, 22, 227).
    • 6 (Fermandjian, S.; Sakarellos, C; Piriou, F.; Juy, M.; Toma, F.; Thanh, H. L.; Lintner, K.; Khosla, M. C.; Smeby, R. R.; Bumpus, F. M. Biopolymers 1983, 22, 227).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.