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For conventional molecular imprinting, see the following references: a
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For conventional molecular imprinting, see the following references: (a) Wulff, G. Angew. Chem., Int. Ed. Engl. 1995, 34, 1812.
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Nishino, H.; Huang, C.-S.; Shea, K. J. Angew. Chem. 2006, 118, 2452; Angew. Chem., Int. Ed. 2006, 45, 2392.
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(c) Nishino, H.; Huang, C.-S.; Shea, K. J. Angew. Chem. 2006, 118, 2452; Angew. Chem., Int. Ed. 2006, 45, 2392.
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34249737949
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Reviews on CyDs: (a) Bender, M. L.; Komiyama, M. Cyclodextrin Chemistry; Springer-Verlag: Berlin, 1978.
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Reviews on CyDs: (a) Bender, M. L.; Komiyama, M. Cyclodextrin Chemistry; Springer-Verlag: Berlin, 1978.
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(b) Szèjtlí, J. Cyclodextrin Technology; Kluwer Academic Publishers: Budapest, 1988.
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Cyclodextrin Technology
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21
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Previous molecular imprinting of CyD: (a) Hishiya, T.; Shibata, M.; Kakazu, M.; Asanuma, H.; Komiyama, M. Macromolecules 1999, 32, 2265.
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Previous molecular imprinting of CyD: (a) Hishiya, T.; Shibata, M.; Kakazu, M.; Asanuma, H.; Komiyama, M. Macromolecules 1999, 32, 2265.
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(b) Hishiya, T.; Asanuma, H.; Komiyama, M. J. Am. Chem. Soc. 2002, 124, 570.
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Asanuma, H.1
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(d) Osawa, T.; Shirasaka, K.; Matsui, T.; Yoshihara, S.; Akiyama, T.; Hishiya, T.; Asanuma, H.; Komiyama, M. Macromolecules 2006, 39, 2460.
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Osawa, T.1
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Yoshihara, S.4
Akiyama, T.5
Hishiya, T.6
Asanuma, H.7
Komiyama, M.8
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(e) Matsui, T.; Osawa, T.; Shirasaka, K.; Katayama, M.; Hishiya, T.; Asanuma, H.; Komiyama, M. J. Inclusion Phenom. Macrocyclic Chem. 2006, 56, 39.
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J. Inclusion Phenom. Macrocyclic Chem
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Matsui, T.1
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Hishiya, T.5
Asanuma, H.6
Komiyama, M.7
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Acrylamido groups were introduced to the surface of silica gel (Nucleosil 300-10 from Macherey-Nagel; specific surface area 100 m2 g -1) by treating the silica gel with acrylamidopropyltriethoxylsilane in xylene.7e According to the titration with KMnQ4, about 140 μmol of vinyl groups was introduced to 1 g of the silica gel (this corresponds to ∼1 acrylamidopropyl group per 1 nm2, In the presence of this vinylated silica gel (600 mg) and template oligopeptide (7.5 μmol, 6-AAm-β-CyD (30 μmol) and MBAAm (180/μmol) were polymerized at 35 °C under nitrogen for 20 h by the combination of potassium persulfate (3 mg) and N,N,N′,N′-tetramethylethylenediamine 3 μL, About 50 mg of β-CyD polymer was bound to 1 g of the silica gel, as determined by the weight loss observed upon its combustion under air. There exists 1 β-CyD molecule in ∼4 nm2 of the surface of the silica gel
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-1. The capacity factor k was determined by using acetone as void marker.
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Nonimprinted polymer bound AI also more strongly than AII, although the difference is far smaller. The solution structure of AI would be more favorable for nonspecific apolar interactions with the polymer/silica gel composites
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Nonimprinted polymer bound AI also more strongly than AII, although the difference is far smaller. The solution structure of AI would be more favorable for nonspecific apolar interactions with the polymer/silica gel composites.
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34249698644
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At pH 3, AI should take a stretching structure because of accumulated positive charges
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At pH 3, AI should take a stretching structure because of accumulated positive charges.
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29
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0037517107
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Spyroulias, G. A.; Nikolakopoulou, P.; Tzakos, A.; Gerothanassis, I. P.; Magafa, V.; Manessi-Zoupa, E.; Cordopatis, P. Eur. J. Biochem. 2003, 270, 2163.
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(2003)
Eur. J. Biochem
, vol.270
, pp. 2163
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Spyroulias, G.A.1
Nikolakopoulou, P.2
Tzakos, A.3
Gerothanassis, I.P.4
Magafa, V.5
Manessi-Zoupa, E.6
Cordopatis, P.7
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0020475449
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The hydropathy indexes of the side chains of He and Val are 4.5 and 4.2, respectively (Kyte, J.; Doolittle, R. F. J. Mol Biol. 1982, 157, 105).
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The hydropathy indexes of the side chains of He and Val are 4.5 and 4.2, respectively (Kyte, J.; Doolittle, R. F. J. Mol Biol. 1982, 157, 105).
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31
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0020604052
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6 (Fermandjian, S.; Sakarellos, C; Piriou, F.; Juy, M.; Toma, F.; Thanh, H. L.; Lintner, K.; Khosla, M. C.; Smeby, R. R.; Bumpus, F. M. Biopolymers 1983, 22, 227).
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6 (Fermandjian, S.; Sakarellos, C; Piriou, F.; Juy, M.; Toma, F.; Thanh, H. L.; Lintner, K.; Khosla, M. C.; Smeby, R. R.; Bumpus, F. M. Biopolymers 1983, 22, 227).
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