Importance of the position of vinyl group on β-cyclodextrin for the effective imprinting of amino acid derivatives and oligopeptides in water

Macromolecules

Volumn 39, Issue 7, 2006, Pages 2460-2466

  Osawa, Tomo ^a   Shirasaka, Kazumi ^a   Matsui, Takahiko ^a   Yoshihara, Shinji ^a   Akiyama, Tomohiro ^a   Hishiya, Takayuki ^a   Asanuma, Hiroyuki ^a,b,c   Komiyama, Makoto ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c NAGOYA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AMINO ACIDS; MONOMERS; POLYMERIZATION; PROTEINS; WATER;

CYCLODEXTRIN; IMPRINTING; OLIGOPEPTIDES;

OLIGOMERS;

EID: 33645989169     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma060064f     Document Type: Article

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22. -1 at 10°C) as determined by NMR analyses. Thus, considerably longer retention times for Acr-CyD are probably attributable to the difference in the polymerization reactivity of Acr-CyD and 3-AAm-CyD.
23. Actual HPLC profiles of the Z-D-Tyr-imprinted polymer were depicted in Figure S1 in the Supporting Information. Imprinting made the profile tailing, probably due to the inhomogeneity of the binding sites, because about half of the CyD would remain uncomplexed during the polymerization as estimated from the binding constant.
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27. Tetrapeptides used here are rather flexible and will not take fixed structure. Therefore, imprinting did not work very well compared with protected amino acids.