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A pentasubstituted benzene (shown below) was generated in a trace amount as a single regioisomer. Because cyclotrimerization of 8 is also sluggish under the present reaction conditions, formation of metallacyclopentadiene from two molecules of 8 may not be involved. Accordingly, the regioselective formation of this compound can be explained by the reaction of rhodacycle B with 8 instead of 2.equation presented
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A pentasubstituted benzene (shown below) was generated in a trace amount as a single regioisomer. Because cyclotrimerization of 8 is also sluggish under the present reaction conditions, formation of metallacyclopentadiene from two molecules of 8 may not be involved. Accordingly, the regioselective formation of this compound can be explained by the reaction of rhodacycle B with 8 instead of 2.equation presented
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In the present study, n-C6F13CCH (2) and n-C7F15CN (15) were used because of their commercial availability, their low toxicity, and their high solubility in (CH2Cl)2. The effect of alkyl chain length will be investigated in due course
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2. The effect of alkyl chain length will be investigated in due course.
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