Synthesis, structure and electronic structure of a new polymorph of CaGe2

Journal of Solid State Chemistry

Volumn 180, Issue 5, 2007, Pages 1575-1581

  Tobash, Paul H ^a   Bobev, Svilen ^a  

^a UNIVERSITY OF DELAWARE   (United States)

Author keywords

CaGe2; Crystal structure; Flux growth; Polymorph; Zintl phase

Indexed keywords

CRYSTAL STRUCTURE; CRYSTALLIZATION; ELECTRONIC STRUCTURE; GERMANIUM COMPOUNDS; POLYMORPHISM; SYNTHESIS (CHEMICAL);

ELECTRON COUNTING; FLUX GROWTH; GERMANIUM POLYANIONIC LAYERS; ZINTL PHASE;

CALCIUM COMPOUNDS;

EID: 34248584695     PISSN: 00224596     EISSN: 1095726X     Source Type: Journal    
DOI: 10.1016/j.jssc.2007.03.003     Document Type: Article

References (47)

1. Sanfilippo S., Elsinger H., Núñez-Regueiro M., Laborde O., LeFloch S., Affronte M., Olcese G.L., and Palenzona A. Phys. Rev. B 61 (2000) R3800
2. Mudring A.-V., and Corbett J.D. J. Am. Chem. Soc. 126 (2004) 5277
3. Imai M., and Kikegawa T. Chem. Mater. 15 (2003) 2543
4. Nakamura T., Suemasu T., Takakura K., Hasegawa F., Wakahara A., and Imai M. Appl. Phys. Lett. 81 (2002) 1032
5. Imai M., Naka T., Furubayashi T., Abe H., Nakama T., and Yagasaki K. Appl. Phys. Lett. 86 (2005) 032102-1
6. Grosche F.M., Yuan H.Q., Carrillo-Cabrera W., Paschen S., Langhammer C., Kromer F., Sparn G., Baenitz M., Grin Yu., and Steglich F. Phys. Rev. Lett. 87 (2001) 247003-1
7. Evers J. J. Solid State Chem. 32 (1980) 77
8. Schäfer H., Janzon K.H., and Weiss A. Angew. Chem. Int. Ed. 2 (1963) 393
9. Vogg G., Brandt M.S., and Stutzmann M. Adv. Mater. 12 (2000) 1278
10. Pettigrew K.A., Liu Q., Power P.P., and Kauzlarich S.M. Chem. Mater. 15 (2003) 4005
11. Armatas G.S., and Kanatzidis M.G. Nature 441 (2006) 1122
12. Tobash P.H., and Bobev S. J. Am. Chem. Soc. 128 (2006) 3532
13. Wu L.-M., Kim S., and Seo D.-K. J. Am. Chem. Soc. 127 (2005) 15682
14. Kanatzidis M.G., Pöttgen R., and Jeitschko W. Angew. Chem. Int. Ed. 44 (2005) 6996
15. Tobash P.H., Lins D., Bobev S., Lima A., Hundley M.F., Thompson J.D., and Sarrao J.L. Chem. Mater. 17 (2005) 5567
16. Smart J.S. Effective Field Theories of Magnetism (1966), Saunders, Philadelphia, PA
17. In: Villars P., and Calvert L.D. (Eds). Pearson's Handbook of Crystallographic Data for Intermetallic Compounds. second ed. (1991), American Society for Metals, Materials Park, OH
18. In: Massalski T.B. (Ed). Binary Alloy Phase Diagrams (1990), American Society for Metals, Materials Park, OH
19. Palenzona A., Manfrinetti P., and Fornasini M.L. J. Alloys Compds. 345 (2002) 144
20. Vogg G., Brandt M.S., Stutzmann M., Genchev I., Bergmaier A., Görgens L., and Dollinger L.G. J. Cryst. Growth 212 (2000) 148
21. Bobev S., Bauer E.D., Thompson J.D., Sarrao J.L., Miller G.J., Eck B., and Dronskowski R. J. Solid State Chem. 177 (2004) 3545
22. Grytsiv A., Kaczorowski D., Leithe-Jasper A., Rogl P., Potel M., Noël H., Pikul A.P., and Velikanova Y. J. Solid State Chem. 165 (2002) 178-181
23. Bruker SMART and SAINT, Bruker AXS Inc., Madison, WI, USA, 2002.
24. G.M. Sheldrick, SADABS, University of Göttingen, Germany, 2003.
25. G.M. Sheldrick, SHELXTL, University of Göttingen, Germany, 2001.
26. 2 structure had been previously established by the Rietveld method only [Ref. 12], single-crystal data collection was carried out and the structure was refined with anisotropic displacement parameters. The CIF for this refinement has a depository number CSD-417611.
27. R.W. Tank, O. Jepsen, A. Burckhardt, O.K. Andersen, TB-LMTO-ASA Program, Version 4.7, Max-Planck-Institut Für Festkörperforschung, Stuttgart, Germany, 1998.
28. Andersen O.K., and Jepsen O. Phys. Rev. Lett. 53 (1984) 2571
29. Blöchl P., Jepsen O., and Andersen O.K. Phys. Rev. B 34 (1994) 16223
30. Dronskowski R., and Blöchl P. J. Phys. Chem. 97 (1993) 8617
31. Hughbanks T., and Hoffmann R. J. Am. Chem. Soc. 105 (1983) 3528
32. Xia S.-Q., and Bobev S. Inorg. Chem. 46 (2007) 874
33. Pauling L. The Nature of the Chemical Bond. third ed. (1960), Cornell University Press, Ithaca, NY
34. Vaughey J.T., Miller G.J., Gravelle S., Leon-Escamilla E.A., and Corbett J.D. J. Solid State Chem. 133 (1997) 501
35. Manfrinetti P., Fornasini M.L., and Palenzona A. Intermetallics 8 (2000) 223
36. Tobash P.H., Lins D., Bobev S., Hur N., Thompson J.D., and Sarrao J.L. Inorg. Chem. 45 (2006) 7286 and references therein
37. Salvador J.R., Gour J.R., Bilc D., Mahanti S.D., and Kanatzids M.G. Inorg. Chem. 43 (2004) 1403
38. Fahy S., and Hamann D.R. Phys. Rev. B 41 (1990) 7587
39. Bisi O., Braicovich L., Carbone C., Lindau I., Iandelli A., Olcese G.L., and Palenzona A. Phys. Rev. B 40 (1989) 10194
40. Budnyk S., Weitzer F., Kubata C., Prots Y., Akselrud L.G., Schnelle W., Hiebl K., Nesper R., Wagner F.R., and Grin Y. J. Solid State Chem. 179 (2006) 2329
41. Weitzer F., Prots Y., Schnelle W., Hiebl K., and Grin Y. J. Solid State Chem. 177 (2004) 2115
42. Grytsiv A., Kaczorowski D., Leithe-Jasper A., Tran V.H., Pikul A., Rogl P., Potel M., Noël H., Bohn M., and Velikanova T. J. Solid State Chem. 163 (2002) 178
43. Evers J., and Weiss A. Mater. Res. Bull. 9 (1974) 549
44. Affronte M., Laborde O., Olcese G.L., and Palenzona A. J. Alloys Compds. 274 (1998) 68
45. Imai Y., Watanabe A., and Mukaida M. J. Alloys Compds. 358 (2003) 257
46. Zintl E. Angew. Chem. 52 (1939) 1
47. In: Kauzlarich S.M. (Ed). Chemistry, Structure and Bonding of Zintl Phases and Ions (1996), VCH Publishers, New York and the references therein