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The preceding discussion refers to the dominant component of the NTO analysis for a given state. Additional details are given in the Supporting Information
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The preceding discussion refers to the dominant component of the NTO analysis for a given state. Additional details are given in the Supporting Information.
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These samples are all rigorously oxygen-free since they were prepared in an inert atmosphere drybox using deoxygenated solvents. Thus, excited-state lifetimes are not impacted by quenching from oxygen
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These samples are all rigorously oxygen-free since they were prepared in an inert atmosphere drybox using deoxygenated solvents. Thus, excited-state lifetimes are not impacted by quenching from oxygen.
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The analogous uranium complexes do not emit, even at 77 K, presumably because the lower-lying manifold of ligand field states are very efficient at non-radiatively relaxing the otherwise emissive ligand-based excited states.
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The analogous uranium complexes do not emit, even at 77 K, presumably because the lower-lying manifold of ligand field states are very efficient at non-radiatively relaxing the otherwise emissive ligand-based excited states.
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