Self-assembly of a high-nuclearity chloride-centered copper(II) cluster. Structure and magnetic properties of [Au(PPh3)2][trans- Cu6(μ-OH)6{μ-(3,5-CF3) 2pz}6Cl]

Inorganic Chemistry

Volumn 46, Issue 7, 2007, Pages 2348-2349

  Mohamed, Ahmed A ^a   Burini, Alfredo ^b   Galassi, Rossana ^b   Paglialunga, Daniele ^b   Galán Mascarós, José Ramón ^a   Dunbar, Kim R ^a   Fackler Jr , John P ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b UNIVERSITY OF CAMERINO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

BIS(TRIPHENYLPHOSPHINE)GOLD(0) CHLOROHEXAKIS(MU HYDROXO)HEXAKIS(3,5 BIS(TRIFLUOROMETHYL)PYRAZOLATE)HEXACOPPER(II); BIS(TRIPHENYLPHOSPHINE)GOLD(0) CHLOROHEXAKIS(MU-HYDROXO)HEXAKIS(3,5-BIS(TRIFLUOROMETHYL)PYRAZOLATE)HEXACOPPER(II); CHLORIDE; COPPER; ORGANOMETALLIC COMPOUND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; TEMPERATURE;

CHLORIDES; COPPER; MODELS, MOLECULAR; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; TEMPERATURE;

EID: 34247158172     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic062299d     Document Type: Article

References (18)

1. (a) Lehn, J.-M. Science 2002, 295, 2400.
2. (b) Karlin, K. D.; Gultneh, Y. In Progress in Inorganic Chemistry; Lippard, J., Ed.; Wiley: New York, 1987; Vol. 35, p 219.
3. Cingolani, A.; Galli, S.; Masciocchi, N.; Pandolfo, L.; Pettinari, C.; Sironi, A. J. Am. Chem. Soc. 2005, 127, 6144.
4. Ardizzoia, G. A.; Angaroni, M. A.; La Monica, G.; Cariati, F.; Cenini, S.; Moret, M.; Masciocchi, M. Inorg. Chem. 1991, 30, 4347.
5. (a) La Monica, G.; Ardizzoia, G. A. Prog. Inorg. Chem. 1997, 46, 151.
6. (b) Masciocchi, N.; Galli, S.; Sironi, A. Comments Inorg. Chem. 2005, 37, 1.
7. (c) Ruiz, E; Cano, J.; Alvarez, S.; Caneschi, A.; Gatteschi, D. J. Am. Chem. Soc. 2003, 6791 and ref 11.
8. (a) Liu, C. W.; Irwin, M. D.; Mohamed, A. A.; Fackler, J. P. Inorg. Chim. Acta 2004, 357, 3950.
9. (b) Liu, C. W.; Staples, R. J.; Fackler, J. P., Jr. Coord. Chem. Rev. 1998, 174, 147.
10. Mezei, G.; Baran, P.; Raptis, R. Angew. Chem., Int. Ed. 2004, 43, 574 and private communication.
11. 6: C, 32.24; N, 6.84; H, 1.72. Found: C, 32.14; N, 6.83; H, 1.65. Electrospray ionization mass spectrometry (ESI-MS) shows an anion peak at m/z 1737 with a trinuclear pyrazolate + Cl peak at m/z 834.7.
12. 3, Z = 4, R1 = 0.0524, wR2 = 0.1242.
13. dc magnetic measurements were performed with an applied field of 2000 G in the 2-300 K temperature range with a Quantum Design SQUID magnetometer MPMS-XL. Data were corrected for the diamagnetic contributions calculated from the Pascal constants.
14. Crawford, V. H.; Richarson, H. W.; Wasson, J. R.; Hodgson, D. J.; Hatfield, W. E. Inorg. Chem. 1976, 15, 2107.
15. (a) Lascialfari, A.; Jang, Z. H.; Borsa, F.; Gatteschi, D.; Cornia, A.; Rovai, D.; Caneschi, A.; Carretta, P. Phys. Rev. B 2000, 61, 6839.
16. (b) Rentschler, E.; Gatteschi, D.; Cornia, A.; Fabretti, A. C.; Barra, A.-L.; Shchegolikhina, O. I.; Zhdanov, A. A. Inorg. Chem. 1996, 35, 4427.
17. (a) Borrás-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblat, B. S. Inorg. Chem. 1999, 38, 6081.
18. (b) Borrás-Almenar, J. J.; Clemente-Juan, J. M.; Coronado, E.; Tsukerblat, B. S. J. Comput. Chem. 2001, 22, 985.