Anion Encapsulation by Neutral Supramolecular Assemblies of Cyclic Cu II Complexes: A Series of Five Polymerization Isomers, [{cis-Cu II(μ-OH)(μ-pz)}n], n = 6, 8, 9, 12, and 14

Angewandte Chemie - International Edition

Volumn 43, Issue 5, 2004, Pages 574-577

  Mezei, Gellert ^a   Baran, Peter ^a   Raptis, Raphael G ^a  

^a UNIVERSITY OF PUERTO RICO   (Puerto Rico)

Author keywords

Copper; Host guest systems; Hydrogen bonds; Self assembly; Supramolecular chemistry

Indexed keywords

COMPLEXATION; COPPER COMPOUNDS; HYDROGEN BONDS; ISOMERS; NEGATIVE IONS; ORGANOMETALLICS; POLYMERIZATION;

DIPOLAR INTERACTIONS; METAL-COORDINATION GEOMETRY;

SUPRAMOLECULAR CHEMISTRY;

AMMONIUM DERIVATIVE; ANION; BIS(TRIPHENYLPHOSPHORANYLIDENE)AMMONIUM; CALIXARENE; CARBONIC ACID; CATION; CHLORIDE; COPPER COMPLEX; PYRAZOLE; SULFATE; UNCLASSIFIED DRUG;

ANION TRANSPORT; ARTICLE; CRYSTAL STRUCTURE; DIPOLE; GEOMETRY; HYDROGEN BOND; HYDROPHILICITY; HYDROPHOBICITY; ISOMERISM; OLIGOMERIZATION; POLYMERIZATION; RING CLOSING METATHESIS; RING OPENING; SUPRAMOLECULAR CHEMISTRY; TEMPERATURE;

EID: 1042288528     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352636     Document Type: Article

References (34)

1. J.-M. Lehn, Science 2002, 295, 2400-2403.
2. P. D. Beer, P. A. Gale, Angew. Chem. 2001, 113, 502-532; Angew. Chem. Int. Ed. 2001, 40, 486-516.
3. P. D. Beer, P. A. Gale, Angew. Chem. 2001, 113, 502-532; Angew. Chem. Int. Ed. 2001, 40, 486-516.
4. R. Dultzler, E. B. Campbell, M. Cadene, B. T. Chait, R. MacKinnon, Nature 2002, 415, 287-294.
5. R. Dutzler, E. B. Campbell, R. MacKinnon, Science 2003, 300, 108-112.
6. F. P. Schmidtchen, M. Berger, Chem. Rev. 1997, 97, 1609-1646.
7. P. D. Beer, D. K. Smith, Prog. Inorg. Chem. 1997, 46, 1-96.
8. P. A. Gale, Coord. Chem. Rev. 2000, 199, 181-233.
9. P. A. Gale, Coord. Chem. Rev. 2001, 213, 79-128.
10. J. J. Bodwin, A. D. Cutland, R. G. Malkani, V. L. Pecoraro, Coord. Chem. Rev. 2001, 216-217, 489-512.
11. E. Cadot, F. Sécheresse, Chem. Commun. 2002, 2189-2197.
12. M. M. G. Antonisse, D. N. Reinhoudt, Chem. Commun. 1998, 443-448.
13. S. Mason, T. Clifford, L. Seib, K. Kuczera, K. Bowman-James, J. Am. Chem. Soc. 1998, 120, 8899-8900.
14. Md. A. Hossain, J. M. Llinares, D. Powell, K. Bowman-James, Inorg. Chem. 2001, 40, 2936-2937.
15. A. Szumna, J. Jurczak, Eur. J. Org. Chem. 2001, 4031-4039.
16. R. Herges, A. Dikmans, U. Jana, F. Köhler, P. G. Jones, I. Dix, T. Fricke, Eur. J. Org. Chem. 2002, 3004-3014.
17. S. Kubik, R. Kirchner, D. Nolting, J. Seidel, J. Am. Chem. Soc. 2002, 124, 12752-12760.
18. J.-H. Liao, C.-T. Chen, J.-M. Fang, Org. Lett. 2002, 4, 561-564.
19. D.-W. Yoon, H. Hwang, C.-H. Lee, Angew. Chem. 2002, 114, 1835-1837; Angew. Chem. Int. Ed. 2002, 41, 1757-1759.
20. D.-W. Yoon, H. Hwang, C.-H. Lee, Angew. Chem. 2002, 114, 1835-1837; Angew. Chem. Int. Ed. 2002, 41, 1757-1759.
21. 2 = 0.1425 for I > 2σ(I); GOF = 0.979. Refinement details can be found as Supporting Information. CCDC-212810 (1+4), CCDC-212812 (2) and CCDC-212811 (3) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
22. P. A. Angaridis, P. Baran, R. Boca, F. Cervantes-Lee, W. Haase, G. Mezei, R. G. Raptis, R. Werner, Inorg. Chem. 2002, 41, 2219-2228.
23. Cu2+N.N(pz)-14], respectively.
24. A. J. Stemmler, J. W. Kampf, V. L. Pecoraro, Inorg. Chem. 1995, 34, 2271-2272.
25. V. L. Pecoraro, A. J. Stemmler, B. R. Gibney, J. J. Bodwin, H. Wang, J. W. Kampf, A. Barwinski, Prog. Inorg. Chem. 1997, 45, 83-177.
26. G. A. Ardizzoia, M. A. Angaroni, G. La Monica, F. Cariati, S. Cenini, M. Moret, M. Masciocchi, Inorg. Chem. 1991, 30, 4347-4353.
27. D. T. Puerta, S. Cohen, Chem. Commun. 2003, 1278-1279.
28. R. W. Saalfrank, I. Bernt, E. Uller, F. Hampel, Angew. Chem. 1997, 109, 2596-2599; Angew. Chem. Int. Ed. Engl. 1997, 36, 2482-2485.
29. R. W. Saalfrank, I. Bernt, E. Uller, F. Hampel, Angew. Chem. 1997, 109, 2596-2599; Angew. Chem. Int. Ed. Engl. 1997, 36, 2482-2485.
30. J. D. Higgins III, J. W. Suggs, Inorg. Chim. Acta 1988, 145, 247-252.
31. S. A. Ivanov, M. A. Kozee, W. A. Merrill, S. Agarwal, L. F. Dahl, Dalton Trans. 20002, 4105-4115.
32. F. Köhler, A. Schell, B. Weber, Chem. Eur. 2002, 8, 5219-5227.
33. B. Hasenknopf, J.-M. Lehn, N. Boumediene, A. Dupont-Gervais, A. Van Dorsselaer, B. Kneisel, D. Fenske, J. Am. Chem. Soc. 1997, 119, 10956-10962.
34. H. Nierengarten, J. Roho, E. Leize, J.-M. Lehn, A. Van Dorsselaer, Eur. J. Inorg. Chem. 2002, 573-579.