Activation of N2O Reduction by the Fully Reduced μ 4-Sulfide Bridged Tetranuclear Cuz Cluster in Nitrous Oxide Reductase

Journal of the American Chemical Society

Volumn 125, Issue 51, 2003, Pages 15708-15709

  Ghosh, Somdatta ^a   Gorelsky, Serge I ^a   Chen, Peng ^a   Cabrito, Inês ^b   Moura, José J G ^b   Moura, Isabel ^b   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b UNIVERSIDADE NOVA DE LISBOA   (Portugal)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER; NITROUS OXIDE; NITROUS OXIDE REDUCTASE; SULFIDE; OXIDOREDUCTASE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; ELECTRON SPIN RESONANCE; ELECTRON TRANSPORT; ENZYME ACTIVITY; INCUBATION TIME; OXIDATION REDUCTION REACTION; REDUCTION; CHEMISTRY; ENZYME ACTIVATION; KINETICS; METABOLISM; THERMODYNAMICS;

COPPER; ELECTRON SPIN RESONANCE SPECTROSCOPY; ENZYME ACTIVATION; KINETICS; MODELS, MOLECULAR; NITROUS OXIDE; OXIDATION-REDUCTION; OXIDOREDUCTASES; SULFIDES; THERMODYNAMICS;

EID: 0347625837     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja038344n     Document Type: Article

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13. 2, N end-on, O end-on.
14. The optimized N-N and N-O distances are 1.180 and 1.247 Å (BP86/LanL2DZ) and 1.143 and 1.192 Å (BP86/6-311G*), respectively.
15. I form has a greater Coulombic barrier for proton attack due to its higher positive charge.