Synthesis of lariat organochalcogenoethers based on azacalix[3]arenes for the potentiometric detection of [UO2]2+ ions

Tetrahedron Letters

Volumn 48, Issue 20, 2007, Pages 3605-3608

  Khan, Shabana ^a   Singh, Jai Deo ^a   Mahajan, Rakesh Kumar ^b   Sood, Pallavi ^b  

^a INDIAN INSTITUTE OF TECHNOLOGY DELHI   (India)

^b GURU NANAK DEV UNIVERSITY   (India)

Author keywords

Azacalix 3 arenes; Host guest systems; Ion selective electrodes; O, N, Se Te donors; UO22 + ion

Indexed keywords

ALKALI; ALKALINE EARTH METAL; BARIUM ION; CADMIUM; CALCIUM ION; CALIXARENE; CHALCOGEN; COBALT; COPPER ION; ETHER DERIVATIVE; FERRIC ION; HETEROCYCLIC COMPOUND; LEAD; MAGNESIUM ION; METAL ION; NICKEL; ORGANIC COMPOUND; POLYMER; POLYVINYLCHLORIDE; POTASSIUM ION; SILVER; SODIUM ION; URANIUM DERIVATIVE; ZINC ION;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; COMPLEX FORMATION; CYCLIZATION; HYDROGEN BOND; ION SELECTIVE ELECTRODE; ONE POT SYNTHESIS; POTENTIOMETRY; PROTON NUCLEAR MAGNETIC RESONANCE; QUANTUM YIELD; REACTION ANALYSIS; ULTRAVIOLET SPECTROSCOPY;

EID: 34247115140     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2007.03.083     Document Type: Article

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42. Different plasticizers were used to study their effect on the potentiometric response of the electrode (E1). The plasticizers used in the present study were tributyl phosphate (TBP), dioctylsebacate (DOS), o-nitrophenyloctyl ether (o-NPOE), dibutylphthalate (DBP), bis(2-ethylhexyl)adipate (DOA), dioctyl phthalate (DOP). Electrode (E1) with TBP as plasticizer was selected for further studies, as it gave a near-Nernstian slope over a wide concentration range, as compared to other membrane electrodes.