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Volumn 111, Issue 10, 2007, Pages 1827-1834

Hydration of aprotic donor solvents studied by means of FTIR spectroscopy

Author keywords

[No Author keywords available]

Indexed keywords

APROTIC DONOR SOLVENTS; BIOLOGICAL AQUEOUS SYSTEMS; ELECTRON DONORS; WATER NETWORKS;

EID: 34047261096     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp065599p     Document Type: Article
Times cited : (24)

References (56)
  • 32
    • 34047269275 scopus 로고    scopus 로고
    • According to the Glew and Rath work28 with regard to water diluted in a number of organic solvents, the composite H2O band intensity is directly proportional to the red-shift of the asymmetric stretching frequency, v3, and can be ascribed by the formula I, 131.3(3756, v3, The starting wavenumber 3756 cm-1 is the gas phase value for v3. In our method, the calculated total area of the composite H2O band (Ig, referred to the position of the gravity center (vg, represents one mole of H2O in the hypothetical state characterized by vg. The measured area of each component of H2O spectrum, Si, characterized by its band position at maximum, vio, coincident with the gravity center for analytical symmetric band, can be corrected (obtaining S ic) using appropriate factors: Sic, S
    • i, denotes mole fraction of water in the distinct state.
  • 55
  • 56
    • 0039114448 scopus 로고    scopus 로고
    • H. Visser, C.; Heuvelsland, W. J. M.; Dunn, L. A.; Somsen, G. J. Chem. Soc. Faraday Trans. 1978, 74, 1159.
    • H. Visser, C.; Heuvelsland, W. J. M.; Dunn, L. A.; Somsen, G. J. Chem. Soc. Faraday Trans. 1978, 74, 1159.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.