Syntheses and characterization of alkylzirconium complexes containing two silanolato ligands with a bowl-shaped framework

Journal of Organometallic Chemistry

Volumn 692, Issue 11, 2007, Pages 2115-2119

  Shimo, Isao ^a   Okumura, Tomoko ^a   Goto, Kei ^b   Kawashima, Takayuki ^a  

^a UNIVERSITY OF TOKYO   (Japan)

^b TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Alkylzirconium complex; Bowl shaped molecule; Cationic zirconium complex; Silanolato ligand

Indexed keywords

CATALYSTS; COMPLEXATION; LIGANDS; OLEFINS; POLYMERIZATION; SILICA; SYNTHESIS (CHEMICAL);

ALKYLZIRCONIUM COMPLEXES; BOWL SHAPED MOLECULES; CATIONIC ZIRCONIUM COMPLEXES; SILANOLATO LIGANDS;

ZIRCONIUM COMPOUNDS;

EID: 34047179940     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2007.01.050     Document Type: Article

References (65)

1. For recent reviews, see:. Piers W.E., and Emslie D.J.H. Coord. Chem. Rev. 233-234 (2002) 131
2. Hultzsch K.C., Gribkov D.V., and Hampel F. J. Organomet. Chem. 690 (2005) 4441
3. Mountford P., and Word B.D. Chem. Commun. (2003) 1797
4. Edelmann F.T., Freckmann D.M.M., and Schumann H. Chem. Rev. 102 (2002) 1851
5. Hanusa T.P. Coord. Chem. Rev. 210 (2000) 329
6. For recent reviews of olefin polymerization, see:. Britovsek G.J.P., Gibson V.C., and Wass D.F. Angew. Chem., Int. Ed. 38 (1999) 428
7. Gibson V.C., and Spitzmesser S.K. Chem. Rev. 103 (2003) 283
8. Imanishi Y., and Naga N. Prog. Polym. Sci. 26 (2001) 1147
9. Stephan D.W., Guérin F., Spence R.E.V.H., Koch L., Gao X., Brown S.J., Swabey J.W., Wang Q., Xu W., Zoricak P., and Harrison D.G. Organometallics 18 (1999) 2046
10. Hollink E., Stewart J.C., Wei P., and Stephan D.W. Dalton Trans. (2003) 3968
11. Stepan D.W. Organometallics 24 (2005) 2548
12. Scollard J.D., and McConville D.H. J. Am. Chem. Soc. 118 (1996) 10008
13. Horton A.D., de With J., van der Linden A.J., and van de Weg H. Organometallics 15 (1996) 2672
14. Guérin F., McConville D.H., and Payne N.C. Organometallics 15 (1996) 5085
15. Baumann R., Davis W.M., and Schrock R.R. J. Am. Chem. Soc. 119 (1997) 3830
16. Schrock R.R., Adamchuk J., Ruhland K., and Lopez L.P.H. Organometallics 24 (2005) 857
17. Shafir A., and Arnold J. Organometallics 22 (2003) 567
18. Uhrhammer R., Black D.G., Gardner T.G., Olsen J.D., and Jordan R.F. J. Am. Chem. Soc. 115 (1993) 8493
19. Martin A., Uhrhammer R., Gardner T.G., and Jordan R.F. Organometallics 17 (1998) 382
20. Lavanant L., Silvestru A., Faucheux A., Toupet L., Jordan R.F., and Carpentier J.-F. Organometallics 24 (2005) 5604
21. Mack H., and Eisen M.S. J. Chem. Soc., Dalton Trans. (1998) 917
22. van der Linden A., Schaverien C.J., Meijboom N., Ganter C., and Orpen A.G. J. Am. Chem. Soc. 117 (1995) 3008
23. Porri L., Ripa A., Colombo P., Miano E., Capelli S., and Meille S.V. J. Organomet. Chem. 514 (1996) 213
24. Bei X., Swenson D.C., and Jordan R.F. Organometallics 16 (1997) 3282
25. Thorn M.G., Etheridge Z.C., Fanwick P.E., and Rothwell I.P. Organometallics 17 (1998) 3636
26. Thorn M.G., Etheridge Z.C., Fanwick P.E., and Rothwell I.P. J. Organomet. Chem. 591 (1999) 148
27. Matsui S., Mitani M., Saito J., Tohi Y., Makio H., Matsukawa N., Takagi Y., Tsuru K., Nitabaru M., Nakano T., Tanaka H., Kashiwa N., and Fujita T. J. Am. Chem. Soc. 123 (2001) 6847
28. Bryliakov K.P., Kravtsov E.A., Pennington D.A., Lancaster S.J., Bochmann M., Brintzinger H.H., and Talsi E.P. Organometallics 24 (2005) 5660
29. Saito J., Suzuki Y., Makio H., Tanaka H., Onda M., and Fujita T. Macromolecule 39 (2006) 4023
30. Cuomo C., Strianese M., Vuenca T., Sanz M., and Grassi A. Maclomolecule 37 (2004) 7469
31. Knight P.D., Clarkson G., Hammond M.L., Kimberley B.S., and Scott P. J. Orgnomet. Chem. 690 (2005) 5125
32. Wolczanski P.T. Polyhedron 14 (1995) 3335
33. For recent reviews, see:. Copéret C., Chabanas M., Saint-Arroman R.R., and Basset J.-M. Angew. Chem., Int. Ed. 42 (2003) 156
34. Severn J.R., Chadwick J.C., Duchateau R., and Friederichs N. Chem. Rev. 105 (2005) 4073
35. Hlatky G.G. Chem. Rev. 100 (2000) 1347
36. Fink G., Steinmetz B., Zechlin J., Przybyla C., and Tesche B. Chem. Rev. 100 (2000) 1337
37. Schwartz J., and Ward M.D. J. Mol. Catal. 8 (1980) 465
38. Zakharov V.A., Dudchenko V.K., Paukshtis E.A., Karakchiev L.G., and Yermakov Y.I. J. Mol. Catal. 2 (1977) 421
39. Ballard D.G.H., Jones E., Wyatt R.J., Murray R.T., and Robinson P.A. Polymer 15 (1974) 169
40. Covert K.J., Mayol A.-R., and Wolczanski P.T. Inorg. Chem. Acta 263 (1997) 263
41. Schweder B., Görls H., and Walther D. Inorg. Chim. Acta 286 (1999) 14
42. Duchateau R., Abbenhuis H.C.L., van Santen R.A., Meetsma A., Thiele S.K.-H., and van Tol M.F.H. Organometallics 17 (1998) 5663
43. Duchateau R., Cremer U., Harmsen R.J., Mohamud S.I., Abbenhuis H.C.L., van Santen R.A., Meersma A., Thiele S.K.-H., van Tol M.F.H., and Kranenburg M. Organometallics 18 (1999) 5447
44. Goto K., Tokitoh N., and Okazaki R. Angew. Chem., Int. Ed. Engl. 34 (1995) 1124
45. Goto K., Hino Y., Kawashima T., Kaminaga M., Yano E., Yamamoto G., Takagi N., and Nagase S. Tetrahedron Lett. 41 (2000) 8479
46. Goto K., Shimo I., and Kawashima T. Bull. Chem. Soc. Jpn. 76 (2003) 2389
47. Ohzu Y., Goto K., and Kawashima T. Angew. Chem., Int. Ed. 42 (2003) 5714
48. Ohzu Y., Goto K., Sato H., and Kawashima T. J. Organomet. Chem. 690 (2005) 4175
49. Goto K., Okumura T., and Kawashima T. Chem. Lett. (2001) 1258
50. The related bowl-type molecules have also been reported by other groups:. Matsumoto T., Kasai T., and Tatsumi K. Chem. Lett. (2002) 346
51. Niyomura O., Tokunaga M., Obora Y., Iwasawa T., and Tsuji Y. Angew. Chem., Int. Ed. 42 (2003) 1287
52. Niyomura O., Iwasawa T., Sawada N., Tokunaga M., Obora Y., and Tsuji Y. Organometallics 24 (2005) 3468
53. 6) δ -15.8.
54. 6) δ -21.1.
55. 2 = 0.2219. The structure was solved by the direct method and refined using full-matrix least squares in shelxl-97 [22]. The asymmetric unit was seen to contain one molecule of 2 · L and 0.5 molecule of benzene. The complex was seen to exhibit 9:1 disorder with respect to Zr(1).
56. Sheldrick G.M. shelxl-97. Computer Program for Crystal Structure Refinement (1997), Unversity of Göttingen
57. 19F nuclei).
58. Axenov K.V., Kilpeläinen I., Klinga M., Leskelä M., and Repo T. Organometallics 25 (2006) 463
59. Horton D., and de With J. Chem. Commun. (1996) 1375
60. 2 = 0.2118. The structure was solved by the direct method and refined using full-matrix least squares in shelxl-97 [22].
61. Pellecchia C., Grassi A., and Immirzi A. J. Am. Chem. Soc. 115 (1993) 1160
62. For examples, see:. Jordan R.F., Bajgur C.S., Willett R., and Scott B. J. Am. Chem. Soc. 108 (1986) 7410
63. Pellecchia C., Immirzi A., Pappalardo D., and Peluso A. Organometallics 13 (1994) 3773
64. Yang X., Stern C.L., and Marks T.J. J. Am. Chem. Soc. 116 (1994) 10015
65. Zuccaccia C., Stahl N.G., Macchioni A., Chen M.-C., Roberts J.A., and Marks T.J. J. Am. Chem. Soc. 126 (2004) 1448