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0011522020
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Ar angles of 150-159° are typically found for highly sterically demanding 2,6-disubstituted phenoxide ligands. See: (a) M.M. Olmskao, G. Sigel, H. Hope, X. Xu and P.R. Power, J. Am. Chem. Soc., 107 (1985) 3087;
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and references cited therein
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33751157397
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[14] For the influence of electron donating substituents of cyclopentadienyl and related ligands on the activity of metallocene catalysts see: (a) W. Spaleck, F. Küber, A. Winter, J. Rohrmann, B. Bachmann, M. Antberg, V. Dolle and E.F. Paulus, Organometallics, 13 (1994) 954;
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