Using low-field NMR to infer the physical properties of glassy oligosaccharide/water mixtures

Biomacromolecules

Volumn 8, Issue 3, 2007, Pages 1038-1046

  Aeberhardt, Kasia ^a   Bui, Quang D ^a   Normand, Valery ^a  

^a Analysis and Perception Department   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROGEN BONDS; LAPLACE TRANSFORMS; MATHEMATICAL MODELS; MIXTURES; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE; RELAXATION TIME; STATISTICAL METHODS; WATER CONTENT;

FREE INDUCTION DELAY (FID); GLASSY OLIGOSACCHARIDE/WATER MIXTURES;

OLIGOSACCHARIDES;

HYDROGEN; HYDROXYL GROUP; OLIGOSACCHARIDE; OXYGEN; PROTON; WATER;

ARTICLE; CALCULATION; CARBOHYDRATE ANALYSIS; CONTROLLED STUDY; ENERGY TRANSFER; HYDROGEN BOND; MOLECULAR WEIGHT; NUCLEAR MAGNETIC RESONANCE; PHYSICAL MODEL; PHYSICAL PARAMETERS; PRIORITY JOURNAL; PROBABILITY; SIGNAL PROCESSING; SOLVATION; STATISTICAL MODEL; WATER CONTENT;

BIOPHYSICS; CHEMISTRY; DIFFUSION; HYDROGEN BONDING; MACROMOLECULAR SUBSTANCES; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; MODELS, STATISTICAL; NORMAL DISTRIBUTION; OLIGOSACCHARIDES; POLYMERS; POLYSACCHARIDES; PROBABILITY; TIME FACTORS; WATER;

EID: 33947659043     PISSN: 15257797     EISSN: None     Source Type: Journal    
DOI: 10.1021/bm061054p     Document Type: Article

References (23)

1. Rubel, G. Simultaneous determination of oil and water contents in different oilseeds by pulsed nuclear magnetic resonance. JAOCS 1994, 71 (10), 1057-1062.
2. Brosio, E.; Conti, F.; Di Nola, A.; Scorano, O.; Balestrieri, F. Simultaneous determination of oil and water content in olive husk by pulsed low resolution nuclear magnetic resonance. J. Food Technol. 1981, 16, 629-636.
3. Todt, H.; Burk, W.; Guthausen, G.; Guthausen, A.; Kamlowski, A.; Schmalbein, D. Quality control with time-domain NMR. Eur. J. Lipid Sci. Technol. 2001, 103, 835-840.
4. Derbyshire, W.; van den Bosch, M.; van Dusschoten, D.; McNaughtan, W.; Farhat, I. A.; Hemminga, M. A.; Mitchell, J. R. Fitting of the beat pattern observed in NMR free-induction decay signals of concentrated carbohydrate-water solutions. J. Magn. Reson. 2004, 168, 278-283.
5. Avaltroni, F.; Bouquerand, P.-E.; Normand, V. Oligosaccharide molecular weight distribution influence on the glass transition temperature and viscosity in aqueous solutions. Carbohydr. Polym. 2004, 58 (3), 323-334.
6. Aeberhardt, K.; de Saint Laumer, J.-Y.; Bouquerand, P.-E.; Normand, V. Ultrasonic study of sugars oligomers and oligosaccharide solutions: Persistence length and radius of gyration. Int. J. Biol. Macromol. 2005, 36 (5), 275-282.
7. Normand, V.; Avaltroni, F.; Bouquerand, P.-E. Mathematical discretisation of Size-Exclusion-Chromatograms applied to commercial corn oligosaccharides, J. Chromatogr. Sci. 2006, 44 (2), 91-95.
8. Abragam A. The principle of Nuclear Magnetism; Clarendon Press: Oxford, 1961.
9. 1H NMR. J. Phys. Chem. B. 1998, 102, 10483-10489.
10. Radosta, S.; Schierbaum, F. Polymer-water interaction of oligosaccharides, Part II: NMR study of bound water in liquid oligosaccharide-water systems. Starch/Stärke 1989, 41 (11), 428-430.
11. Bouquerand, P. E.; Maio, S.; Atkins, D.; Singleton S.; Normand, V. Swelling and erosion affecting flavor release from glassy particles in water, AIChE J. 2004, 50 (12), 3257-3270.
12. Lippincott, E. R. Deviation of an intermolecular potential function from a quantum mechanical model. J. Chem. Phys. 1955, 23, 603.
13. Ouali, L.; Leon, G.; Normand, V.; Benczédi, D.; Johnsen, H.; Dyrli, A.; Schmid, R. Mechanism of Romascone release from hydrolysed vinyl acetate nano-particles: thermogravimetric method. Polym. Adv. Technol. 2006, 17 (1), 45-52.
14. Schroeder, R.; Lippincott, E. R. Potential function model of hydrogen bonds. J. Phys. Chem. 1957, 61, 921-928.
15. Moulton, W. G.; Kromhout, R. A. Nuclear Magnetic Resonance: Structure of the Amino Group. II. J. Chem. Phys. 1956, 25 (1), 34-37.
16. Veytsman, B. Thermodynamics of hydrogen-bonded fluids: effects of bond cooperativity. J. Phys. Chem. 1993, 97, 7144-7146.
17. Veytsman, B. Equation of state for hydrogen-bonded systems. J. Phys. Chem. B 1998, 102, 7515-7517.
18. Kumagai, H.; McNaughtan, W.; Farhat, I. A.; Mitchell, J. R. The infuence of carrageenan on the molecular mobility in low moisture amorphous sugars. Carbohydr. Polym. 2002, 48, 341-349.
19. Couchman, P. R. Compositional variation of glass transition temperature. 2. Application of the thermodynamic theory to compatible polymer blends. Macromolecules 1978, 11 (6), 1156-1161.
20. Benczédi, D.; Tomka, I.; Escher, F. Thermodynamics of amorphous starch-water systems. 1. Volume fluctuations. Macromolecules 1998, 31 (9), 3055-3061.
21. Schwarzl, F. R. Polymermechanik; Springer-Verlag: Berlin, Heidelberg, and New York, 1990; p 338.
22. Schwarzl, F. R.; Staverman, A. J. Higher approximation methods for the relaxation spectrum from static and dynamic measurements of visco-elastic materials. Appl. Sci. Res. 1953, A4, 127-141.
23. Alfrey, T.; Doty, P. The methods of specifying the properties of viscoelastic materials. J. Appl. Phys. 1945, 16, 700-713.