Reactions of o-aminothiophenol and o-aminophenyl disulfide with itaconic anhydride and (-)-dimenthyl itaconate: Access to enantiomerically pure 1,5-benzothiazepines and benzothiazolyl-2-methylacrylic acid

Synthesis

Volumn , Issue 3, 2007, Pages 0457-0463

  Baag, Md Merajuddin ^a   Sahoo, Manoj Kumar ^a   Puranik, Vedavati G ^a   Argade, Narshinha P ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

Benzothiazepines; Benzothiazoles; Chemo , regio and stereoselective reactions; Dimenthyl itaconate; Itaconic anhydride; o aminothiophenol; Synthesis

Indexed keywords

BENZOTHIAZEPINES; BENZOTHIAZOLES; DIMENTHYL ITACONATE; ITACONIC ANHYDRIDES;

ADDITION REACTIONS; AMINES; CHEMICAL BONDS; MOLECULAR STRUCTURE; REGIOSELECTIVITY; SYNTHESIS (CHEMICAL);

PHENOLS;

(4 OXO 2,3,4,5 TETRAHYDROBENZO[B][1,5]THIAZEPIN 3 YL)ACETIC ACID; (4 OXO 2,3,4,5 TETRAHYDROBENZO[B][1,5]THIAZEPIN 3 YL)ACETIC ACID ETHYL ESTER; (4 OXO 2,3,4,5 TETRAHYDROBENZO[B][1,5]THIAZEPIN 3 YL)ACETIC ACID METHYL ESTER; 2 (2 AMINOPHENYLSULFANYLMETHYL)SUCCINIC ACID; 2 (2 AMINOPHENYLSULFANYLMETHYL)SUCCINIC ACID BIS(2 ISOPROPYL 5 METHYLCYCLOHEXYL)ESTER; 2 (2 AMINOPHENYLSULFANYLMETHYL)SUCCINIC ACID DIMETHYL ESTER; 2 [[2 [2 (3 CARBOXYBUT 3 ENOYLAMINO)PHENYLDISULFANYL]PHENYLCARBAMOYL]METHYL]ACRYLIC ACID; 2 BENZOTHIAZOL 2 YLMETHYLACRYLIC ACID; 2 METHYLENESUCCINIC ACID BIS(2 ISOPROPYL 5 METHYLCYCLOHEXYL)ESTER; ACID ANHYDRIDE; ADENOSINE TRIPHOSPHATE; BENZOTHIAZEPINE DERIVATIVE; BENZOTHIAZOLE DERIVATIVE; DICARBOXYLIC ACID; DISULFIDE; ITACONIC ACID; METHACRYLIC ACID; SULFUR; THIOPHENOL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; DISULFIDE BOND; ENANTIOMER; MICHAEL ADDITION; REDUCTION; RING OPENING; STEREOCHEMISTRY;

EID: 33947595389     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2006-958977     Document Type: Article

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