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Chemical shift in CD3OD/ppm KD1: 9.60 (d, 1H), 9.45 (d, 1H), 9.01 (s, 1H), 8.89 (s, 1H), 8.59 (d, 1H), 8.44 (d, 1H), 8.28 (d, 1H), 8.19 (t, 1H), 7.84 (t, 2H), 7.63 (d, 1H), 7.57 (d, 1H), 7.17 (t, 1H), KD2: 9.62 (d, 1H), 9.22 (d, 1H), 9.01 (s, 1H), 8.86 (s, 1H), 8.44 (s, 1H), 8.32 (s, 1H), 8.25 (d, 1H), 7.83 (d, 1H), 7.67 (d, 1H), 7.62 (d, 1H), 7.33 (d, 1H), 7.00 (d, 1H).
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Chemical shift in CD3OD/ppm KD1: 9.60 (d, 1H), 9.45 (d, 1H), 9.01 (s, 1H), 8.89 (s, 1H), 8.59 (d, 1H), 8.44 (d, 1H), 8.28 (d, 1H), 8.19 (t, 1H), 7.84 (t, 2H), 7.63 (d, 1H), 7.57 (d, 1H), 7.17 (t, 1H), KD2: 9.62 (d, 1H), 9.22 (d, 1H), 9.01 (s, 1H), 8.86 (s, 1H), 8.44 (s, 1H), 8.32 (s, 1H), 8.25 (d, 1H), 7.83 (d, 1H), 7.67 (d, 1H), 7.62 (d, 1H), 7.33 (d, 1H), 7.00 (d, 1H).
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We used PC instead of AN for the measurement, which makes it easy to compare with previously reported absorption transient results by other groups
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We used PC instead of AN for the measurement, which makes it easy to compare with previously reported absorption transient results by other groups.
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- to dye cation becomes slow so that plateau was seen, which is consistent with the data shown in ref 4. Our data with TBAI is shown in the Supporting Information.
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- to dye cation becomes slow so that plateau was seen, which is consistent with the data shown in ref 4. Our data with TBAI is shown in the Supporting Information.
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In ref 18, initial difference of dye cation halftime between Z907 and N719 was a factor of 15, and the difference became a factor of 2.5 after storing at 80 °C for 72 hours. The authors suggested a possibility that initially electrolyte penetrated insufficiently so that all dyes were not covered by the electrolyte, and the long dye cation lifetime might be due to the noncovered dye. After 72 hours, since the originally uncovered dyes would be covered by the electrolyte, dye cations were reduced more efficiently
-
In ref 18, initial difference of dye cation halftime between Z907 and N719 was a factor of 15, and the difference became a factor of 2.5 after storing at 80 °C for 72 hours. The authors suggested a possibility that initially electrolyte penetrated insufficiently so that all dyes were not covered by the electrolyte, and the long dye cation lifetime might be due to the noncovered dye. After 72 hours, since the originally uncovered dyes would be covered by the electrolyte, dye cations were reduced more efficiently.
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