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43
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33947130545
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Relevant data demonstrating the β-deshielding effect: (a) C-2 in adamantane at δ 38.4 vs C-2 in 1-fluoroadamantane at δ 43.4 (see ref 25);
-
Relevant data demonstrating the β-deshielding effect: (a) C-2 in adamantane at δ 38.4 vs C-2 in 1-fluoroadamantane at δ 43.4 (see ref 25);
-
-
-
-
44
-
-
33947157532
-
-
C-2 in bicyclo[2.2.1]heptane at δ 29.6 vs C-2 in 1-fluorobicyclo-[2.2.1]heptane at δ 32.03 (see refs 25 and 26);
-
(b) C-2 in bicyclo[2.2.1]heptane at δ 29.6 vs C-2 in 1-fluorobicyclo-[2.2.1]heptane at δ 32.03 (see refs 25 and 26);
-
-
-
-
45
-
-
33947178261
-
-
C-2 in bicyclo-[3.3.1]nonane at δ 32.0 vs C-2 in l-fluorobicyclo[3.3.1]nonane at δ 37.3 (see ref 25);
-
(c) C-2 in bicyclo-[3.3.1]nonane at δ 32.0 vs C-2 in l-fluorobicyclo[3.3.1]nonane at δ 37.3 (see ref 25);
-
-
-
-
46
-
-
33947096788
-
-
C-2 in bicyclo[2.2.2]octane at δ 25.9 vs C-2 in 1-fluorobicyclo[2.2.2]octane at δ 31.0 (see ref 25).
-
(d) C-2 in bicyclo[2.2.2]octane at δ 25.9 vs C-2 in 1-fluorobicyclo[2.2.2]octane at δ 31.0 (see ref 25).
-
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47
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0342342722
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The only example that we know of with a β-shielding effect: C-8a in triptycene at δ 144.73 vs C-8a in 9-fluorotriptycene at δ 143.36 see ref 28 and Qiu, Z. W, Grant, D. M, Pugmire, R. J. J. Am. Chem. Soc. 1982, 104, 2747
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It should be noted that even in the present, relatively simple, system while XPS can be used for accurate determination of the C:F ratio, determination of different chemical species (i.e, CF versus CCF) requires fitting of the spectra as described in the text. The presence of multiple overlapping peaks potentially fitted makes quantification somewhat difficult. It is for this reason that XPS can be used for determination of the C:F ratio for comparison with Raman and NMR
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It should be noted that even in the present, relatively simple, system while XPS can be used for accurate determination of the C:F ratio, determination of different chemical species (i.e., CF versus CCF) requires fitting of the spectra as described in the text. The presence of multiple overlapping peaks potentially fitted makes quantification somewhat difficult. It is for this reason that XPS can be used for determination of the C:F ratio for comparison with Raman and NMR.
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