메뉴 건너뛰기




Volumn 26, Issue 4, 2007, Pages 938-944

Lewis-acidity of trimethylplatinum(IV) with labile oxygen-donor ligands

Author keywords

[No Author keywords available]

Indexed keywords

ACIDITY; CATALYSTS; COORDINATE MEASURING MACHINES; NEGATIVE IONS; OXYGEN; SILICON COMPOUNDS;

EID: 33847321585     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om060787n     Document Type: Article
Times cited : (7)

References (52)
  • 22
    • 33847296895 scopus 로고    scopus 로고
    • This is apparent from Figure 1: at 0.5 equiv of Pt, Δδ is already at 85% of the limiting value, showing that more than one aldehyde binds under such conditions. If just free aldehyde and 1:1 complex were in equilibrium, Δ δ would be at 50% of the limiting value
    • This is apparent from Figure 1: at 0.5 equiv of Pt, Δδ is already at 85% of the limiting value, showing that more than one aldehyde binds under such conditions. If just free aldehyde and 1:1 complex were in equilibrium, Δ δ would be at 50% of the limiting value.
  • 24
    • 33847274964 scopus 로고    scopus 로고
    • Details are given in the Experimental Section
    • Details are given in the Experimental Section.
  • 27
    • 33847253718 scopus 로고    scopus 로고
    • The fact that the side products stem from Cp*H alone was confirmed by reacting Cp*H with catalytic amounts of [Me3PtOTf] 4, in the absence of a dienophile
    • 4, in the absence of a dienophile.
  • 28
    • 33847335333 scopus 로고    scopus 로고
    • Stereochemistry confirmed by NOE spectroscopy Experimental Section
    • Stereochemistry confirmed by NOE spectroscopy (Experimental Section).
  • 29
    • 0000978921 scopus 로고    scopus 로고
    • For the uncatalyzed reaction of Cp*H with other (somewhat related) dienophiles: Letourneau, J. E.; Wellman, M. A.; Burnell, D. J. J. Org. Chem. 1997, 62, 7272.
    • For the uncatalyzed reaction of Cp*H with other (somewhat related) dienophiles: Letourneau, J. E.; Wellman, M. A.; Burnell, D. J. J. Org. Chem. 1997, 62, 7272.
  • 31
    • 33847312037 scopus 로고    scopus 로고
    • 4 are virtually colorless.
    • 4 are virtually colorless.
  • 33
    • 23744514171 scopus 로고    scopus 로고
    • For spectroscopic data on the 1,4-adduct, see
    • For spectroscopic data on the 1,4-adduct, see: Teo, Y.-C.; Loh, T.-P. Org. Lett. 2005, 7, 2539.
    • (2005) Org. Lett , vol.7 , pp. 2539
    • Teo, Y.-C.1    Loh, T.-P.2
  • 34
    • 3843138035 scopus 로고    scopus 로고
    • For a review on weakly coordinating anions
    • For a review on weakly coordinating anions: Krossing, I.; Raabe, I. Angew. Chem., Int. Ed. 2004, 43, 2066.
    • (2004) Angew. Chem., Int. Ed , vol.43 , pp. 2066
    • Krossing, I.1    Raabe, I.2
  • 35
    • 33847319476 scopus 로고    scopus 로고
    • - are known: Powell, J.; Lough; A; Saeed, T. J. Chem. Soc., Dalton Trans. 1997, 4137.
    • - are known: Powell, J.; Lough; A; Saeed, T. J. Chem. Soc., Dalton Trans. 1997, 4137.
  • 42
    • 85165726007 scopus 로고    scopus 로고
    • Kobayashi, S.; Mori, Y.; Yamashita, Y. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. B., Eds.; Elsevier Pergamon: Amsterdam; Boston, 2004; 9.8, p 399.
    • Kobayashi, S.; Mori, Y.; Yamashita, Y. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. B., Eds.; Elsevier Pergamon: Amsterdam; Boston, 2004; Vol. 9.8, p 399.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.