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This is apparent from Figure 1: at 0.5 equiv of Pt, Δδ is already at 85% of the limiting value, showing that more than one aldehyde binds under such conditions. If just free aldehyde and 1:1 complex were in equilibrium, Δ δ would be at 50% of the limiting value
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Details are given in the Experimental Section.
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The fact that the side products stem from Cp*H alone was confirmed by reacting Cp*H with catalytic amounts of [Me3PtOTf] 4, in the absence of a dienophile
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4, in the absence of a dienophile.
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28
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33847335333
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Stereochemistry confirmed by NOE spectroscopy Experimental Section
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Stereochemistry confirmed by NOE spectroscopy (Experimental Section).
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4 are virtually colorless.
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4 are virtually colorless.
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