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In 2004 35 mio tons of PE-LD/PE-LLD and 25 mio tons of PE-HD were consumed worldwide, and consumption is estimated to grow by 5% p.a. at least until 2010. PlasticsEurope Deutschland, WG Statistics and Market Research; cf
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In 2004 35 mio tons of PE-LD/PE-LLD and 25 mio tons of PE-HD were consumed worldwide, and consumption is estimated to grow by 5% p.a. at least until 2010. PlasticsEurope Deutschland, WG Statistics and Market Research; cf. http://www.vke.de/de/infomaterial/download/.
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(n) Liu, H. R.; Gomes, P. T.; Costa, S. I.; Duarte, M. T.; Branquinho, R.; Fernandes, A.C.; Chien, J. C. W.; Singh, R. P.; Marques, M. M. J. Organomet. Chem. 2005, 690 (5), 1314-1323.
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(p) Camacho, D. H.; Salo, E. V.; Ziller, J. W.; Guan Z. Angew. Chem. 2004, 116 (14), 1857-1861.
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33847175786
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2 complexes of sterically bulky ligands, such as N,N′-bis(2,6-(4-tert-butylphenyl) phenyl)-1,4-diazabutadiene. Therefore, the monoanionic Ni(acac) complexes were applied. Moody, L. S, Mackenzie, P. B, Killian, C. M, Lavoie, G. G, Ponasik, J. A, Jr, Barrett, A. G, Smith, T. W, Pearson, J. C. WO 00/50470, 2000
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2 complexes of sterically bulky ligands, such as N,N′-bis(2,6-(4-tert-butylphenyl) phenyl)-1,4-diazabutadiene. Therefore, the monoanionic Ni(acac) complexes were applied. Moody, L. S.; Mackenzie, P. B.; Killian, C. M.; Lavoie, G. G.; Ponasik, J. A., Jr.; Barrett, A. G.; Smith, T. W.; Pearson, J. C. WO 00/50470, 2000.
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33847182325
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Recently, investigations on monomeric anilido-imine Ni(I) complexes were published the following, (a) Wang, H.-Y.; Meng, X.; Jin, G.-X. Dalton Trans. 2006, 2579
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Recently, investigations on monomeric anilido-imine Ni(I) complexes were published the following, (a) Wang, H.-Y.; Meng, X.; Jin, G.-X. Dalton Trans. 2006, 2579
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26
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3042743491
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(b) Zhang, D.; Jin, G.-X.; Weng, L.-H.; Wang, F. Organometallics 2004, 23 (13), 3270
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33847234904
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Due to the paramagnetic character of 1b,c NMR experiments were unsuccessful.
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Due to the paramagnetic character of 1b,c NMR experiments were unsuccessful.
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28
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Polymerization behavior of la was published earlier; see ref 1. The experimental results for 2a,b will be presented in future works
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Polymerization behavior of la was published earlier; see ref 1. The experimental results for 2a,b will be presented in future works.
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31
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0033317096
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Treatment of 1a and 2a with TMA in solution afforded the rapid precipitation of Ni(0). We observed, however, dissolution of this black precipitate and a blue, soluble but polymerization-inactive species formed in the presence of Al(III) activators and ethylene monomer. All trials to grow crystals suitable for X-ray analysis of the blue compound remained unsuccessful until now. Therefore, we cannot give a structural suggestion yet. UV/vis spectroscopy points toward the formation of a Ni(II)-dialkyl species. For a similar observation of such a blue compound, see: Peruch, F.; Cramail, H.; Deffieux, A. Macromolecules 1999, 32 (24), 7977-7983.
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Treatment of 1a and 2a with TMA in solution afforded the rapid precipitation of Ni(0). We observed, however, dissolution of this black precipitate and a "blue, soluble but polymerization-inactive species" formed in the presence of Al(III) activators and ethylene monomer. All trials to grow crystals suitable for X-ray analysis of the blue compound remained unsuccessful until now. Therefore, we cannot give a structural suggestion yet. UV/vis spectroscopy points toward the formation of a Ni(II)-dialkyl species. For a similar observation of such a blue compound, see: Peruch, F.; Cramail, H.; Deffieux, A. Macromolecules 1999, 32 (24), 7977-7983.
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