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(a) Laplaza, C. E.; Davis, W. M.; Cummins, C. C. Angew. Chem., Int. Ed. Engl. 1995, 34, 2042.
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Angew. Chem., Int. Ed. Engl
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Laplaza, C.E.1
Davis, W.M.2
Cummins, C.C.3
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2
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33745421616
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(b) Zanetti, N. C.; Schrock, R. R.; Davis, W. M. Angew. Chem., Int. Ed. Engl. 1995, 34, 2044.
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(1995)
Angew. Chem., Int. Ed. Engl
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Zanetti, N.C.1
Schrock, R.R.2
Davis, W.M.3
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3
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37049072982
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Scheer, M.; Schuster, K.; Budzichowski, T. A.; Chisholm, M. H.; Streib, W. E. Chem. Commun. 1995, 1671.
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(1995)
Chem. Commun
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Scheer, M.1
Schuster, K.2
Budzichowski, T.A.3
Chisholm, M.H.4
Streib, W.E.5
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4
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7444242445
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(a) Johnson, B. P.; Balázs, G.; Scheer, M. Top. Curr. Chem. 2004, 232, 1.
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(2004)
Top. Curr. Chem
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Johnson, B.P.1
Balázs, G.2
Scheer, M.3
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5
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33646364544
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(b) Johnson, B. P.; Balázs, G.; Scheer, M. Coord. Chem. Rev. 2006, 250, 1178.
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Coord. Chem. Rev
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Johnson, B.P.1
Balázs, G.2
Scheer, M.3
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7
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17844368330
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For recent work on the subject see: a
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For recent work on the subject see: (a) Shu, Y.; Oyama, S. T. Carbon 2005, 43, 1517.
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(2005)
Carbon
, vol.43
, pp. 1517
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Shu, Y.1
Oyama, S.T.2
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8
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27744592677
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(b) Nagai, M.; Fukiage, T.; Kurata, S. Catal. Today 2005, 106, 201.
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(2005)
Catal. Today
, vol.106
, pp. 201
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Nagai, M.1
Fukiage, T.2
Kurata, S.3
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9
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10944226907
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(c) Milman, V.; Winkler, B.; Gomperts, R. Chem-Eur. J. 2004, 10, 6279.
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(2004)
Chem-Eur. J
, vol.10
, pp. 6279
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Milman, V.1
Winkler, B.2
Gomperts, R.3
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10
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9144229244
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(d) Sun, F.; Wu, W.; Guo, J.; Wei, Z.; Yang, Y.; Jiang, Z.; Tian, F.; Li, C. J. Catal. 2004, 228, 298.
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(2004)
J. Catal
, vol.228
, pp. 298
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Sun, F.1
Wu, W.2
Guo, J.3
Wei, Z.4
Yang, Y.5
Jiang, Z.6
Tian, F.7
Li, C.8
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13
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0038006673
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(g) Oyama, S. T. J. Catal. 2003, 216, 343.
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(2003)
J. Catal
, vol.216
, pp. 343
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Oyama, S.T.1
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15
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0142184908
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García, M. E.; Riera, V.; Ruiz, M. A.; Sáez, D.; Hamidov, H.; Jeffery, J. C.; Riis-Johannessen, T. J. Am. Chem. Soc. 2003, 125, 13044.
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(2003)
J. Am. Chem. Soc
, vol.125
, pp. 13044
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García, M.E.1
Riera, V.2
Ruiz, M.A.3
Sáez, D.4
Hamidov, H.5
Jeffery, J.C.6
Riis-Johannessen, T.7
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16
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33749983331
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Amor, I.; García, M. E.; Ruiz, M. A.; Saéz, D.; Hamidov, H.; Jeffery, J. C. Organometallics 2006, 25, 4857.
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(2006)
Organometallics
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, pp. 4857
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Amor, I.1
García, M.E.2
Ruiz, M.A.3
Saéz, D.4
Hamidov, H.5
Jeffery, J.C.6
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17
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33847199254
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Selected data for 3: v(CO, THF) 1890 (vs, 1811 (s, 31P{1H} NMR (161.97 MHz, 233 K, tol-d8, δ 512.5 (s, μ-PH, 1H NMR (400.13 MHz, 233 K, tol-d 8, δ 12.44 (d, JHP, 179, 1H, PH, 4.65 (s, 3H, C6H3, 13C-{1H} NMR (100.63 MHz, 233 K, tol-d8, δ 247.8 s, br, 2 × CO
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8): δ 247.8 (s, br, 2 × CO).
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18
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0035115224
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(a) Peruzzini, M.; De los Rios, I.; Romerosa, A.; Vizza, F. Eur. J. Inorg. Chem. 2001, 593.
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(2001)
Eur. J. Inorg. Chem
, pp. 593
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Peruzzini, M.1
De los Rios, I.2
Romerosa, A.3
Vizza, F.4
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19
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0034716808
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and references therein
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(b) Borg-Breen, C. C.; Bautista, M. T.; Schauer, C. K.; White, P. S. J. Am. Chem. Soc. 2000, 122, 3952, and references therein.
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(2000)
J. Am. Chem. Soc
, vol.122
, pp. 3952
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Borg-Breen, C.C.1
Bautista, M.T.2
Schauer, C.K.3
White, P.S.4
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20
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84984198544
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(a) Herrmann, W. A.; Koumbouris, B.; Herdtweck, E.; Ziegler, M. L.; Weber, P. Chem. Ber. 1987, 120, 931.
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(1987)
Chem. Ber
, vol.120
, pp. 931
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Herrmann, W.A.1
Koumbouris, B.2
Herdtweck, E.3
Ziegler, M.L.4
Weber, P.5
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21
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33644560279
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(b) Hirsekorn, K. F.; Veige, A. S.; Wolczanski, P. T. J. Am. Chem. Soc. 2006, 128, 2192.
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(2006)
J. Am. Chem. Soc
, vol.128
, pp. 2192
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Hirsekorn, K.F.1
Veige, A.S.2
Wolczanski, P.T.3
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22
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33847220642
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Density functional calculations were performed with the GAUSS-IAN03 program package using the hybrid method B3LYP, together with the standard 6-31G* basis on all atoms except Mo, for which a valence double-ζ quality basis set and LANL2DZ effective core potentials were used. See Supporting Information for further details.
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Density functional calculations were performed with the GAUSS-IAN03 program package using the hybrid method B3LYP, together with the standard 6-31G* basis on all atoms except Mo, for which a valence double-ζ quality basis set and LANL2DZ effective core potentials were used. See Supporting Information for further details.
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23
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33847240389
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Selected data for 4: v(CO, CH2Cl2) 1930 (vs, 1847 (s, 31P{1H} NMR (161.95 MHz, 233 K, CD 2Cl2, δ -120.8 (s, μ-HPBH3, 1H NMR (400.13 MHz, 188 K, CD2Cl2, δ 2.33 (d, JHP, 278, 1H, PH, 0.46, 0.73 (2 × s, br, 2 × 1H, BH2, 9.62 (br, 1H, B-H-Mo, 11B{1H} NMR (128.38 MHz, 298 K, CD2Cl2, δ-62.8 s, br, HPBH3
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3).
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24
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33847238656
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X-ray data for 4: orange crystals, orthorhombic (P212 121, a, 11.3514(5) Å, b, 17.7124(8) Å, c, 29.7652(14) Å, V, 5984.6(5) Å3, T, 100 K, Z, 8 (two independent molecules, Flack param, 0.022-(9, R, 0.0342 (observed data with I > 2σI, GOF, 0.983
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3, T = 100 K, Z = 8 (two independent molecules), Flack param = -0.022-(9), R = 0.0342 (observed data with I > 2σ(I)), GOF = 0.983.
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25
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0001290094
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McNamara, W. F.; Duesler, E. N.; Paine, R. T.; Ortiz, J. V.; Kölle, P.; Nöth, H. Organometallics 1986, 5, 380.
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(1986)
Organometallics
, vol.5
, pp. 380
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McNamara, W.F.1
Duesler, E.N.2
Paine, R.T.3
Ortiz, J.V.4
Kölle, P.5
Nöth, H.6
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27
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33847218187
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Selected data for 5: v(CO, THF) 1920 (vs, 1857 (s) cm-1. 31P-{1H} NMR (162.14 MHz, THF-d8, 243 K, δ1053.3 (s, μ-P) ppm. 1H NMR (400.13 MHz, THF-d8, 243 K, δ 5.46 (br, 2H, C5H4, 5.15 (br, 3H, C 6H3, 4.22 (br, 2H, C5H4) ppm. 13C{1H} NMR (100.63 MHz, THF-d8, 243 K, δ236.9 (s, 2 × CO, 87.1 [s, 2 × CH(C5H 6)L 79.5, 78.2 [2 × s, 2 × CH(C5H 6, 47.9 [s, CH2C5H6
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6].
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28
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0011484776
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Davies, S. G.; Hibberd, J.; Simpson, S. J. J. Organomet. Chem. 1983, 246, 016.
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(1983)
J. Organomet. Chem
, vol.246
, pp. 016
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Davies, S.G.1
Hibberd, J.2
Simpson, S.J.3
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