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Volumn , Issue 8, 2007, Pages 878-888

Lanthanide-3d cyanometalate chains Ln(III)-M(III) (Ln = Pr, Nd, Sm, Eu, Gd, Tb; M = Fe) with the tridentate ligand 2,4,6-tri(2-pyridyl)-1,3,5-triazine (tptz): Evidence of ferromagnetic interactions for the Sm(III)-M(III) compounds (M = Fe, Cr)

Author keywords

[No Author keywords available]

Indexed keywords

FERROMAGNETIC MATERIALS; MAGNETIC FIELDS; MAGNETIC SUSCEPTIBILITY; SAMARIUM COMPOUNDS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

EID: 33847013712     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b616016f     Document Type: Article
Times cited : (74)

References (74)
  • 61
    • 84942830823 scopus 로고    scopus 로고
    • note
    • Preparation of Ln(tptz)(NO3)3(solvent)n: Ln(NO3)3·6H2O (0.1 mmol) was dissolved in 3 mL of methanol. Gradual addition of a solution of 2,4,6-tri(2-pyridyl)-1,3, 5-triazine (tptz) in methanol (3 ml) with stirring induced the precipitation of an off-white solid. The precipitate was filtered off, washed with methanol and dried in air. Yield 60-70%. Suitable crystals of Ln(tptz)(NO3) 3(solvent)n for X-ray crystallographic determination were obtained by slow diffusion of diethyl ether into a solution of the product in H2O-MeOH.
  • 62
    • 84942816456 scopus 로고    scopus 로고
    • note
    • Crystal data for [Nd(tptz)(NO3)3(H 2O)][Nd(tptz)(NO3)3(CH3OH)] ·3(H2O), M = 1448.36, P1, a = 9.7474(19), b = 10.855(2), c = 13.452(3) Å, α = 97.22(3), β = 107.19(3), γ = 90.23(3)°, V = 1347.6(5) Å3, Z = 1, Dc = 1.785 g cm-3, μ = 2.006 cm-1, T = 110(2) K, R1 = 0.0329, wR2 = 0.0894 for 7243 reflections with I > 2σ(I)
  • 71
    • 0003591858 scopus 로고    scopus 로고
    • Bruker AXS Inc., Madison, Wisconsin, USA
    • SAINT. Version, 6.02, Bruker AXS Inc., Madison, Wisconsin, USA, 2001
    • (2001) SAINT. Version, 6.02
  • 72
    • 33847008539 scopus 로고    scopus 로고
    • Bruker AXS Inc.: Madison, Wisconsin, USA
    • SADABS, Bruker AXS Inc.: Madison, Wisconsin, USA, 1998
    • (1998) SADABS


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.