Structural refinement and crystal chemistry of Mn-doped spinel: A case for tetrahedrally coordinated Mn3+ in an oxygen-based structure

American Mineralogist

Volumn 92, Issue 1, 2007, Pages 27-33

  Bosi, Ferdinando ^a   Hålenius, Ulf ^a   Andreozzi, Giovanni B ^b   Skogby, Henrik ^a   Lucchesi, Sergio ^b  

^a SWEDISH MUSEUM OF NATURAL HISTORY   (Sweden)

^b SAPIENZA UNIVERSITY OF ROME   (Italy)

Author keywords

Chemical analysis (mineral); Crystal structure; Mn3+ in spinel; Optical spectroscopy; Order disorder; Spinel; XRD data

Indexed keywords

ABSORPTION SPECTROSCOPY; CHEMICAL ANALYSIS; CRYSTAL ATOMIC STRUCTURE; CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; GEOMETRY; LIGHT ABSORPTION; ORDER DISORDER TRANSITIONS; OXYGEN; POSITIVE IONS; SINGLE CRYSTALS;

BOND VALENCE APPROACH; DIFFERENT DISTRIBUTIONS; ELECTRON MICROPROBES; OPTICAL SPECTROSCOPY; SPINEL; SPINEL SINGLE CRYSTALS; STRUCTURAL REFINEMENT; X-RAY SINGLE-CRYSTAL DIFFRACTION;

MANGANESE METALLOGRAPHY;

ABSORPTION; CATION; CHEMICAL ANALYSIS; CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; MANGANESE; OXYGEN; SPINEL;

EID: 33846446458     PISSN: 0003004X     EISSN: None     Source Type: Journal    
DOI: 10.2138/am.2007.2266     Document Type: Article

References (33)

1. 4): crystal structure refinements, Mössbauer, and polarized optical absorption spectra. Zeitschrift für Kristallographie, 155, 81-113.
2. 4. spinel. American Mineralogist, 87, 838-844.
3. 3+ clusters in spinel-magnesioferrite solid solution crystals: a potential monitor for ordering in oxide spinels. Physics and Chemistry of Minerals, 28, 435-444.
4. Bosi, F., Andreozzi, G.B., Ferrini, V., and Lucchesi, S. (2004) Behavior of cation vacancy in kenotetrahedral Cr-spinels from Albanian eastern belt ophiolites. American Mineralogist, 89, 1367-1373.
5. Brown, I.D. (2002) The chemical bond in inorganic chemistry: the bond valence model, 12, 288 p. International Union of Crystallography Monographs on Crystallography, Oxford University Press, U.K.
6. Brown, I.D. and Altermatt, D. (1985) Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database. Acta Crystallographica, B41, 244-247.
7. Burns, R.G. (1993) Mineralogical Applications of Crystal Field Theory (2nd edition), 551 p. Cambridge Univeristy Press, U.K.
8. Della Giusta, A. and Ottonello, G. (1993) Energy and long-range disorder in simple spinels. Physics and Chemistry of Minerals, 20, 228-241.
9. 3+-spinel. Mineralogical Magazine, 60, 603-616.
10. Dollase, W. A. (1969) Crystal structure and cation ordering of piemontite. American Mineralogist, 54, 710-717.
11. Golikov, Y.V., Barkhatov, V.P., Balakirev, V.F., and Avdukov, V.I. (1989) High-temperature and quenched states in manganese-containing oxide systems in air. High Temperatures-High Pressures, 21, 685-700.
12. 4,) from in-situ neutron structure refinements. American Mineralogist, 83, 1092-1099.
13. Hill, R.J., Craig, J.R., and Gibbs, G.V. (1979) Systematics of the spinel structure type. Physics and Chemistry of Minerals, 4, 317-340.
14. 4 system. Journal of Physics D: Applied Physics, 7, 2058-2062.
15. Larson, A.C. (1970) Crystallographic Computing, F.R. Ahmed, S.R. Hall, and C.P. Huber, Eds., p. 291-294. Munksgaard, Copenhagen.
16. Lavina, B., Salviulo, G., and Della Giusta, A. (2002) Cation distribution and structure modeling of spinel solid solutions. Physics and Chemistry of Minerals, 29, 10-18.
17. 3+ on structural stability. Physics and Chemistry of Minerals, 30, 599-605.
18. Lucchesi, S., Russo, U., and Della Giusta, A. (1997) Crystal chemistry and cation distribution in some Mn-rich natural and synthetic spinels. European Journal of Mineralogy, 9, 31-42.
19. δ spinels. Journal of Solid State Chemistry, 166, 171-176.
20. 4 tetragonal spinel. Nuclear Instruments and Methods in Physics Research B, 238, 171-174.
21. 4 spinels from in situ high-temperature X-ray diffraction. American Mineralogist, 91, 306-312.
22. 4, a new tetragonal spinelloid mineral from the Gozaisho mine, Fukushima Prefecture, Japan. Mineralogical Journal, 9, 383-391.
23. 4 spinel solid solution. Physics and Chemistry of Minerals, 31, 278-287.
24. North, A.C.T., Phillips, D.C., and Mathews, F.S. (1968) A semi-empirical method of absorption correction. Acta Crystallographica, A24, 351-359.
25. 4 spinel. European Journal of Mineralogy, 6, 603-609.
26. 4 spinel. European Journal of Mineralogy, 17, 581-586.
27. Pouchou, J.L. and Pichoir, F. (1984) A new model for quantitative X-ray microanalysis. I. Application to the analysis of homogeneous samples. La Recherche Aérospatiale, 3, 13-36.
28. 4. Zeitschrift für Kristallographie, 142, 121-126.
29. 4. Physical Status Solid, 37A, 719-722.
30. 3+ in a quartz vein from the Ardennes mountains, Belgium, and its origin. Contributions to Mineralogy and Petrology, 147, 276-287.
31. Shannon, R.D. (1976) Revised Effective Ionic Radii and Systematic Studies of Interatomic Distances in Halides and Chalcogenides. Acta Crystallographica, A32, 751-767.
32. -1. Physics and Chemistry of Minerals, 8, 136-142.
33. 4. Acta Crystallographica, A36, 122-126.