Single-crystal X-ray diffraction study of cation distribution in MgAl2O4-MgFe2O4 spinel solid solution

Physics and Chemistry of Minerals

Volumn 31, Issue 5, 2004, Pages 278-287

  Nakatsuka, A ^a   Ueno, H ^a   Nakayama, N ^a   Mizota, T ^a   Maekawa, H ^b  

^a YAMAGUCHI UNIVERSITY   (Japan)

^b TOHOKU UNIVERSITY   (Japan)

Author keywords

Cation distribution; Miscibility gap; Single crystal X ray diffraction; Solid solution; Spinel

Indexed keywords

CRYSTALLIZATION; POSITIVE IONS; SINGLE CRYSTALS; SOLUBILITY; SYNTHESIS (CHEMICAL);

ENERGETIC DESTABILIZATION; SPINELS;

MAGNESIUM COMPOUNDS;

CATION; CRYSTALLOGRAPHY; MINERAL SYNTHESIS; SOLID SOLUTION; SPINEL; X-RAY DIFFRACTION;

EID: 3242760820     PISSN: 03421791     EISSN: None     Source Type: Journal    
DOI: 10.1007/s00269-004-0385-z     Document Type: Article

References (31)

1. Allen WC (1964) Solid solution in the refractory magnesium spinels. PhD Thesis. The State University, New Brunswick
2. Allen WC (1966) An X-ray method for defining composition of a magnesium spinel. Am Mineral 51: 239-243
3. Allred AL, Rochow EG (1958) A scale of electronegativity based on electrostatic force. J Inorg Nucl Chem 5: 264-268
4. Becker PJ, Coppens P (1974a) Extinction within the limit of validity of the Darwin transfer equations. I. General formalisms for primary and secondary extinction and their application to spherical crystals. Acta Crystallogr (A)30: 129-147
5. 2 and LiF. Acta Crystallogr (A)30: 148-153
6. Dupree R, Lewis MH, Smith ME (1986) A study of the vacancy distribution in non-stoichiometric spinels by magic-angle spinning NMR. Philosoph Mag (A)53: L17-L20
7. 27Al magic-angle-spinning NMR spectroscopy. Chem Lett 771-774
8. +++. J Chem Phys 22: 1597-1600
9. 4) from in-situ neutron structure refinements. Am Mineral 83: 1092-1099
10. International tables for X-ray crystallography (1974), vol IV. Kynoch Press, Birmingham
11. 4 (0 ≤ × ≤ 2) spinel solid solution. Z Anorg Allg Chem 626: 42-49
12. 3 by emf method. Scand J Metall 31: 374-378
13. 4 system by emf method. Osaka Univ Tech Rep 30: 385-390
14. 3. J Inorg Nucl Chem 9: 65-70
15. 4) from XRD structural refinements and Mössbauer spectroscopy. Eur J Mineral 6: 39-51
16. 27Al NMR study. Am Mineral 82: 1125-1132
17. 17O magic-angle spinning NMR. Am Mineral 77: 44-52
18. 4 spinel. Eur J Mineral 6: 603-609
19. O'Neill HSt, Navrotsky A (1984) Cation distributions and thermodynamic properties of binary spinel solid solutions. Am Mineral 69: 733-753
20. Pauling L (1960) The nature of the chemical bond, 3rd ed. Cornell University Press, Ithaca
21. 4. J Mater Res 12: 2584-2588
22. 4 spinel solid solutions. J C S Faraday I 76: 2448-2456
23. 4 ). J Phys Chem Solids 32: 717-729
24. Sanderson RT (1967) Inorganic chemistry. Van Nostrand-Reinhold, New York
25. Sasaki S (1987) RADY. A FORTRAN program for the least-squares refinement of crystal structures. National Laboratory for High Energy Physics, Japan
26. Shannon RD (1976) Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides. Acta Crystallogr (A)32: 751-767
27. 4. Neues Jb Mineral Monatsh 10: 442-449
28. 2- . Acta Crystallogr 19: 486
29. 4. Acta Crystallogr (B)34: 1093-1096
30. Ulmer GC (1969) Experimental investigations of chromite spinels. In: Wilson HDB (ed) Magmatic ore deposits. Monograph 4. The Economic Geology Publishing Co, pp 114-131
31. 4 spinel. Am Mineral 71: 999-1006