Temperature-dependent disorder in a natural Mg-Al-Fe2+-Fe3+-spinel

Mineralogical Magazine

Volumn 60, Issue 4, 1996, Pages 603-616

  Della Giusta, Antonio ^a   Carbonin, Susanna ^a   Ottonello, Giulio ^b  

^a UNIVERSITY OF PADOVA   (Italy)

^b UNIVERSITY OF GENOA   (Italy)

Author keywords

Disorder; Italian Alps; Peridotite; Spinel; Temperature dependence

Indexed keywords

DISORDER; MOSSBAUER SPECTROSCOPY; PERIDOTITE; SPINEL; TEMPERATURE DEPENDENCE; XRD;

ITALY, ALPS;

EID: 0030473009     PISSN: 0026461X     EISSN: None     Source Type: Journal    
DOI: 10.1180/minmag.1996.060.401.06     Document Type: Article

References (48)

1. Basso, R., Comin-Chiaramonti, P., Della Giusta, A. and Flora, O. (1984) Crystal chemistry of four Mg-Fe-Al-Cr spinels from the Balmuccia peridotite (Western Italian Alps). Neues Jahrb. Mineral. Abh., 150, 1-10.
2. Blessing, R.H., Coppens, P. and Becker, P. (1972) Computer analysis of step-scanned X-ray data. J. Appl. Cryst. 7, 488-92.
3. Carbonin, S., Russo, U. and Della Giusta, A. (1996) Cation distribution in some natural spinels from X-ray diffraction and Mössbauer spectroscopy. Mineral. Mag., 60, 355-68.
4. 3+ ordered distribution in chromite spinels. Phys. Chem. Miner., 19, 255-9.
5. Comin-Chiaramonti, P., Demarchi, G., Siena, F. and Sinigoi, S. (1982) Relazioni tra fusione e deformazione nella peridotite di Balmuccia (Ivrea-Verbano). Rend. Soc. Ital. Mineral. Petrol., 38, 685-700.
6. 4 spinel observed by rectangular parallelepiped ultrasonic resonance and Raman measurements. Pure Appl. Geophys., 141, 415-44.
7. Della Giusta, A. and Ottonello, G. (1993) Energy and long-range disorder in simple spinels. Phys. Chem. Miner., 20, 228-41.
8. Della Giusta, A., Princivalle, F. and Carbonin, S. (1986) Crystal chemistry of a suite of natural Cr-bearing spinels with 0.15 < Cr < 1.07. Neues Jahrb. Mineral. Abh., 155, 319-30.
9. Della Giusta, A., Princivalle, F. and Carbonin, S. (1987) Crystal structure and cation distribution in some natural magnetites. Mineral. Petrol., 37, 315-21.
10. 2. Contrib. Mineral. Petrol., 85, 186-96.
11. Grimes, N.W., Thompson, P. and Kay, H.F. (1982) New symmetry and structure for spinel. Proc. Royal Soc. London, A386, 333-45.
12. Hafner, S. (1960) Metalloxyde mit Spinellstruktur. Schw. Miner. Petr. Mitt., 40, 208-40.
13. Hill, R.J., Craig, J.R. and Gibbs, G.V. (1979) Systematics of the spinel structure type. Phys. Chem. Mineral. 4, 317-39.
14. Irvine, T.N. (1965) Chromian spinel as a petrogenetic indicator. Part 1. Theory. Canad. J. Earth Sci., 2, 648-72.
15. James, F. and Roos, M. (1975) MINUIT, A system for function minimization and analysis of the parameters errors and correlations. Comp. Phys. Comm., 10, 343-67.
16. 4, spinel. Neues Jahrb. Mineral. Mh., 173-84.
17. 4) from XRD structural refinements and Mössbauer spectroscopy. Eur. J. Mineral., 6, 39-51.
18. Lucchesi, S. and Della Giusta, A. (1994) Crystal chemistry of non-stoichiometric Mg-Al synthetic spinels. Zeit. Kristallogr., 209, 714-9.
19. 17O magic-angle spinning NMR. Amer. Mineral., 77, 44-52.
20. Navrotsky, A. and Kleppa, O.J. (1967) The thermodynamics of cation distribution in simple spinels. J. Inorg. Nucl. Chemistry, 29, 2701-14.
21. 4 spinels from thermopower and conductivity measurements. Amer. Mineral., 74, 339-51.
22. North, A.C.T., Phillips, D.C. and Scott-Mattews, F. (1968) A semi-empirical method of absorption correction. Acta Cryst., A24, 351-2.
23. 4) from powder XRD structural refinements. Eur. J. Mineral., 4, 571-80.
24. 4. Phys. Chem. Miner., 20, 541-55.
25. O'Neill, H.St.C. and Navrotsky, A. (1983) Simple spinels: crystallographic parameters, cation radii, lattice energies, and cation distribution. Amer. Mineral., 68, 181-94.
26. O'Neill, H.St.C. and Navrotsky, A. (1984) Cation distribution and thermodynamic properties of binary spinel solid solutions. Amer. Mineral., 69, 733-53.
27. 4) spinel: a powder XRD study. Phys. Chem. Miner., 18, 302-19.
28. 4) from powder XRD structural refinements and Mössbauer spectroscopy. Amer. Mineral., 77, 725-40.
29. 3+ ordering in chromite and Cr-bearing spinels. Contrib. Mineral. Petrol., 77, 251-5.
30. Ottonello, G. (1986) Energetics of multiple oxides with spinel structure. Phys. Chem. Miner., 13, 79-90.
31. 4 at temperatures up to 1273 K. Amer. Mineral., 76, 1455-8.
32. 4 spinel solid solutions. J. Amer. Ceramic Soc., 65, 117-23.
33. Pizzolon, M. (1991) Cristallochimica e modellizzazione di spinelli di Mg-Al-Fe-Cr. Thesis, University of Padova, Padova, Italy.
34. Princivalle, F., Della Giusta, A. and Carbonin, S. (1989) Comparative crystal chemistry of spinels from some suites of ultramafic rocks. Mineral. Petrol., 40, 117-26.
35. Raudsepp, M., Hawthorne, F.C. and Turnock, A.C. (1990) Evaluation of the Rietveld method for the characterization of fine-grained products of mineral synthesis: the diopside-hedenbergite join. Canad. Mineral., 28, 93-109.
36. Rieck, G.D. and Driessens, F.C.M. (1966) The structure of manganese-iron-oxygen spinels. Acta Cryst., 20, 521-5.
37. Sack, R.O. (1982) Spinels as petrogenetic indicators: activity-composition relations at low pressure. Contrib. Mineral Petrol., 79, 169-86.
38. Sack, R.O. and Ghiorso, M.S. (1991a) Chromian spinels as petrogenetic indicators: thermodynamics and petrological applications. Amr. Mineral., 76, 827-47.
39. Sack, R.O. and Ghiorso, M.S. (1991b) An internally consistent model for the thermodynamic properties of Fe-Mg-titanomagnetite-aluminate spinels. Contrib. Mineral. Petrol., 106, 474-505.
40. Sheldrick, G.M. (1993) SHELX-93. Program for crystal structure refinement. University of Göttingen, Germany.
41. 4 spinels. J. Phys., C: Solid State Physics, 9, L235-7.
42. 4. J. Amer. Ceramic Soc., 66, 829-34.
43. 4 spinel. Geochem. Intern., 24(2), 124-30.
44. Urusov, V.S. (1983) Interaction of cations on octahedral and tetrahedral sites in simple spinels. Phys. Chem. Mineral., 9, 1-5.
45. 4 (O < × ≤ 1) spinels annealed at different temperatures. Phys. Chem. Miner., 21, 460-8.
46. Wu, C.C. and Mason, T.O. (1981) Thermopower measurement of cation distribution in magnetite. J. Amer. Ceramic Soc., 64, 520-2.
47. 4 spinel at high temperatures up to 1700°C. Zeit. Kristall., 165, 65-78.
48. Young, R.A. (1995) Introduction to the Rietveld method. In The Rietveld Method (R.A. Young, ed.). International Union of Crystallography, Oxford University Press Inc., New York, pp. 1-38.