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Volumn 46, Issue 1, 2007, Pages 309-320

Modulating the M-M distance in dinuclear complexes. New ligand with a 2,2′-biphenol fragment as key unit: Synthesis, coordination behavior, and crystal structures of Cu(II) and Zn(II) dinuclear complexes

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EID: 33846411416     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic061474n     Document Type: Article
Times cited : (26)

References (76)
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    • The ±gauche conformation is by far the preferred one for the biphenol (CSD data). The fully protonated BPH shows the largest range of torsion values (mean τ and d values: 68.5°, 3.1 Å; 39 hits retrieved), while the mononegative BPH species appears to be more rigid and definitely more planar, essentially thanks to the intramolecular OH⋯O hydrogen bond (mean τ and d values: 41.7°, 2.5 Å; 5 hits retrieved). Uncoordinated dinegative BPH moieties were not found, and only two hits feature dinuclear metal complexes involving this species in a coordination pattern similar to 6 and 7 (τ > 55°, d > 2.8 Å).
    • The ±gauche conformation is by far the preferred one for the biphenol (CSD data). The fully protonated BPH shows the largest range of torsion values (mean τ and d values: 68.5°, 3.1 Å; 39 hits retrieved), while the mononegative BPH species appears to be more rigid and definitely more planar, essentially thanks to the intramolecular OH⋯O hydrogen bond (mean τ and d values: 41.7°, 2.5 Å; 5 hits retrieved). Uncoordinated dinegative BPH moieties were not found, and only two hits feature dinuclear metal complexes involving this species in a coordination pattern similar to 6 and 7 (τ > 55°, d > 2.8 Å).


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