Ambiphilic vinylcarbenoid reactivity of (α-(tributylstannyl)-,π- allyl)palladium(II) species

Organometallics

Volumn 26, Issue 1, 2007, Pages 30-32

  Trépanier, Vincent É ^a   Fillion, Eric ^a  

^a UNIVERSITY OF WATERLOO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

DIMERIZATION; OLEFINS; ORGANOMETALLICS; TIN COMPOUNDS;

CARBENE; CYCLOPROPANATION; DIMETALLIC INTERMEDIATES; NUCLEOPHILIC NATURE;

PALLADIUM COMPOUNDS;

EID: 33846263429     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0609416     Document Type: Article

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25. Determined by NOE experiments (see the Supporting Information).
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37. All products had >98% deuterium incorporation and were one stereoisomer, except for 3-d-5a, isolated as a 1:1 (E:Z) mixture.