Free radical modelling studies during the UK TORCH Campaign in Summer 2003

Atmospheric Chemistry and Physics

Volumn 7, Issue 1, 2007, Pages 167-181

  Emmerson, K M ^a,b   Carslaw, N ^a   Carslaw, D C ^b   Lee, J D ^a   McFiggans, G ^c   Bloss, W J ^b   Gravestock, T ^b   Heard, D E ^b   Hopkins, J ^b   Ingham, T ^b   Pilling, M J ^b   Smith, S C ^b   Jacob, M ^d,e   Monks, P S ^d  

^a UNIVERSITY OF YORK   (United Kingdom)

^b UNIVERSITY OF LEEDS   (United Kingdom)

^c UNIVERSITY OF MANCHESTER   (United Kingdom)

^d UNIVERSITY OF LEICESTER   (United Kingdom)

^e TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; ATMOSPHERIC MODELING; CHEMICAL REACTION; CONCENTRATION (COMPOSITION); FREE RADICAL; TROPOSPHERE;

ENGLAND; ESSEX [ENGLAND]; EURASIA; EUROPE; UNITED KINGDOM; WESTERN EUROPE;

EID: 33846235562     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-7-167-2007     Document Type: Article

References (54)

1. Alicke, B., Geyer, A., Hofzumahaus, A., Holland, F., Konrad, S., Pätz, H. W., Schäfer, J., Stutz, J., Volz-Thomas, A., and Platt, U.: OH formation by HONO photolysis during the BERLIOZ experiment, J. Geophys. Res., 108, doi:10.1029/2001JD000579, 2003.
2. x, Atmos. Env., 34, 2063-2101, 2000.
3. 2, NO and IO by laser-induced fluorescence, J. Env. Monitoring, 5, 21-28, 2003.
4. Brasseur, G. P., Hauglustaine, D. A., Walters, S., Rasch, P. J., Muller, J.-F., Granier, C., and Tie, X. X:. MOZART, a global chemical transport model for ozone and related chemical tracers. 1. Model description, J. Geophys. Res., 103, 28265-28289. 1998.
5. 2 radicals in the marine boundary layer. 1. Model construction and comparison with field measurements, J. Geophys. Res., 104, 30241-30255, 1999.
6. 2 radicals in a forested region of north-western Greece, Atmos. Env., 35, 4725-4737, 2001.
7. Clemitshaw, K. C., Carpenter, L. J., Penkett, S. A., and Jenkin, M. E.: A calibrated peroxy radical chemical amplifier for ground-based tropospheric measurements, J. Geophys. Res., 102, 25405-25416, 1997.
8. Cleveland, W. S.: Robust Locally Weighted Regression And Smoothing Scatterplots, J. Am. Stat. Assoc., 74(368), 829-836, 1979.
9. Derwent, R. G.: The influence of human activities on the distribution of hydroxyl radicals in the troposphere, Phil. Trans. R. Soc. London, Series A, 354, 501-531, 1996.
10. Edwards, G. D. and Monks, P. S.: Performance of a single monochromator didoe array spectroradiometer for the determination of actinic flux and atmospheric photolysis frequencies, J. Geophys. Res., 108, 8546, doi:10.1029/2002JD002844.
11. 2 Concentrations with Measurements. J. Atmos. Chem., 52, no 2, 143-164, 2005a.
12. 2, J. Atmos. Chem., 52, no 2, 165-183, 2005b.
13. Fleming, Z. L., Monks, P. S., Rickard, A. R., Bandy, B. J., Brough, N., Green, T. J., Reeves, C. E., and Penkett, S. A.: Seasonal dependence of peroxy radical concentrations at a Northern hemisphere marine boundary layer site during summer and winter: Evidence for photochemical activity in winter, Atmos. Chem. Phys., 6, 5415-5433, 2006, http://www.atmos-chem-phys.net/6/5415/2006/.
14. Fleming, Z., Monks, P. S., Rickard, A. R., Heard, D. E., Bloss, W. J., Seakins, P. W., Still, T. J., Sommariva, R., Pilling, M. J., Morgan, R. B., Green, T. J., Brough, N., Mills, G. P., Penkett, S. A., Lewis, A. C., Lee, J. D., Saiz-Lopez, A., and Plane, J. M. C.: Peroxy radical chemistry and the control of ozone photochemistry at Mace Head, Ireland during the summer of 2002, Atmos. Chem. Phys., 6, 2193-2214, 2006, http://www.atmos-chem-phys.net/6/2193/ 2006/.
15. Frost, G. J., Trainer, M., Allwine, G., Buhr, M. P., Calvert, J. G., Cantrell, C. A., Fehsenfeld, F. C., Goldan, P. D., Herwehe, J., Hübler, G., Küster, W. C., Martin, R., McMillen, R. T., Montzka, S. A., Norton, R. B., Parrish, D. D., Ridley, B. A., Shelter, R. E., Walega, J. G., Watkins, B. A., Westberg, H. H., and Williams, E. J.: Rural Oxidants in the Southern Environment (ROSE) program, J. Geophys. Res., 103, 22491-22508, 1998.
16. 2 in Los Angeles smog, J. Geophys. Res., 104, 11643-11655, 1999.
17. 2 with gas to particle mass transfer rates calculated using aerosol number size distributions, J. Geophys. Res., 110, D04303, doi:10.1029/2004JD005282, 2005.
18. Harrison, R. M., Yin, J., Tilling, R. M., Cai, X., Seakins, P. W., Hopkins, J. R., Lansley, D. L., Lewis, A. C., Hunter, M. C., Heard, D. E., Carpenter, L. J., Creasey, D. J., Lee, J. D., Pilling, M. J., Carslaw, N., Emmerson, K. M., Redington, A., Derwent, R. G., Ryall, D., Mills, G., and Penkett, S. A.: Measurement and modelling of air pollution and atmospheric chemistry in the U.K. west midlands conurbation: overview of the puma consortium project, Sci. Tot. Env., 360, 5-25, 2006.
19. Heard, D. E., Carpenter, L. J., Creasey, D. J., Hopkins, J. R., Lee, J. D., Lewis, A. C., Pilling, M. J., Seakins, P. W., Carslaw, N., and Emmerson, K. M.: High levels of the hydroxyl radical in the winter urban troposphere, Geophys. Res. Lett., 31, L18112, doi:10.1029/2004GL020544, 2004.
20. 2 in the troposphere, Chem. Reviews. 103, 5163-5198, 2003.
21. 2 radical concentrations and photolysis frequencies during BERLIOZ, J. Geophys. Res., 108, doi: 10.1029/2001JD001393, 2003.
22. Hopkins, J. R., Lewis, A. C., and Read, K. A.: A Two-column method for long-term monitoring of Non-methane hydrocarbons (NMHC) and oxygenated volatile organic compounds (OVOCs), J. Env. Monitor, 5, 8-13, 2002.
23. Hough, A. M.: The calculation of photolysis rates for use in global tropospheric modelling studies, AERE Rep. R-13259, Her Majesty's Stn. Off, Norwich, England, 1988.
24. IUPAC.: Summary of evaluated kinetic and photochemical data for atmospheric chemistry, IUPAC Subcommittee for Gas Kinetic Data Evaluation, 2005.
25. Jenkin, M. E., Saunders, S. M., and Pilling, M. J.: The tropospheric degradation of volatile organic compounds: A protocol for mechanism development, Atmos. Env., 31, 81-104, 1997.
26. Jenkin, M. E., Saunders, S. M., Wagner, V., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part B): Tropospheric degradation of aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 181-193, 2003, http://www.atmos-chem-phys.net/3/181/2003/.
27. Konrad, S., Schmitz, Th., Buers, H.-J., Houben, N., Mannschreck, K., Mihelcic, D., Müsgen, P., Pätz, H.-W., Holland, F., Hofzumahaus, A., Schäfer, H.-J., Schröder, S., and Volz-Thomas, A.: Hydrocarbon measurements at Pabstthum during the BERLIOZ campaign and modelling of free radicals, J. Geophys. Res., 108, DOI:10.1029/2001JD000866, 2003.
28. Kurtenbach, R., Becker, K. H., Gomes, J. A. G., Kleffmann, J., Lorzer, J. C., Spittler, M., Wiesen, P., Ackermann, R., Geyer, A., and Platt, U.: Investigations of emissions and heterogeneous formation of HONO in a road traffic tunnel, Atmos. Env., 35, 3385-3394, 2001.
29. Lee, J. L., Lewis, A. C., Monks P. S., et al.: Ozone photochemistry during the UK heatwave of August 2003, Atmos. Env., 40, 7598-7613, 2006.
30. Lewis, A. C., Carslaw, N., Marriott, P. J., Kinghorn, R. M., Morrison, P., Lee, A. L., Bartle, K. D., and Pilling, M. J.: A larger pool of ozone-forming carbon compounds in urban atmospheres, Nature, 405, 778-781, 2000.
31. 2 concentrations, sources, and loss rates during the Southern Oxidants Study in Nashville, Tennessee, summer 1999, J. Geophys. Res., 108, doi:10.1029/ 2003JD003551, 2003.
32. Mihelcic, D., Holland, F., Hofzumahaus, A., Hoppe, L., Konrad, S., Müsgen, P., Pätz, H.-W., Schäfer, H.-J., Schmitz, T., Volz-Thomas, A., Bächmann, Schlomski, S., Platt, U., Geyer, A., Alicke, B., and Moortgat, G. K.: Peroxy radicals during BERLIOZ at Pabstthum: Measurements, radical budgets and ozone production, J. Geophys. Res., 108, doi:10.1029/2001JD001014, 2003.
33. Monks, P. S.: Gas-phase radical chemistry in the troposphere, Chem. Soc. Rev., 34, 376-395, 2005.
34. Monks, P. S., Rickard, A. R., Hall, A. L., and Richards, N. A. D.: Attenuation of spectral actinic flux and photolysis frequencies at the surface through homogeneous cloud fields, J. Geophys. Res., 109, 17 206, 2004.
35. 2 radical by water: Molecular dynamics calculations and their implications for atmospheric modelling, J. Geophys. Res., 109, Art. No. D09201, 2004.
36. Paulson, S. E., Chung, M., Sen, A. D., and Orzechowska, G.: Measurement of OH radical formation from the reaction of ozone with several biogenic alkenes, J. Geophys. Res. 103, 25 533-25 539, 1998.
37. 2 in the winter atmosphere in New York City, Atmos. Env. 40, supplement 2, 252-263, 2006.
38. Ren, X., Brune, W. H., Cantrell, C. A., Edwards, G. D., Shirley, T., Metcalf, A. R., and Lesher, R. L.: Hydroxyl and peroxy radical chemistry in a rural area of central Pennsylvania: Observations and model comparisons, J. Atmos. Chem., 52, 231-257, 2005.
39. 2 chemistry in the urban atmosphere of New York City, Atmos. Env., 37, 3639-3651, 2003.
40. Salisbury, G., Rickard, A. R., Monks, P. S., Allan, B. J., Baugitte, S., Penkett, S. A., Carslaw, N., Lewis, A. C., Creasey, D. J., Heard, D. E., Jaobs, P. J., and Lee, J. D.: Production of peroxy radicals at night via reactions of ozone and the nitrate radical in the marine boundary layer, J. Geophys. Res., 106, 12669-12687, 2001.
41. Saunders, S. M., Jenkin, M. E., Derwent, R. G., and Pilling, M. J.: Protocol for the development of the Master Chemical Mechanism, MCM v3 (Part A): Tropospheric degradation of non-aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 161-180, 2003, http://www.atmos-chem-phys.net/3/161/2003/.
42. Saylor, R. D.: An estimate of the potential significance of heterogenous loss to aerosols as an additional sink for hydroperoxy radicals in the troposphere, Atmos. Environ., 31, 3653-3658, 1997.
43. Shirley, T. R., Brune, W. H., Ren, X., Mao, J., Lesher, R., Cardenas, B., Volkamer, R., Molina, L. T., Molina, M. J., Lamb, B., Velasco, E., Jobson, T., and Alexander, M.: Atmospheric oxidation in the Mexico City metropolitan area (MCMA) during April 2003, Atmos. Chem. Phys. Discuss., 5, 6041-6076, 2005, http://www.atmos-chem-phys-discuss.net/5/6041/2005/.
44. x and hydrocarbons in urban and polluted rural environments, Atmos. Env., 33, 1821-1845, 1999.
45. 2 during NAMBLEX: Measurements and Steady State analysis, Atmos. Chem. Phys., 5, 12403-12464, 2005.
46. 2 chemistry during NAMBLEX: roles of oxygenates, halogen oxides and heterogeneous uptake, Atmos. Chem. Phys., 6, 1135-1153, 2006.
47. 2 chemistry in clean marine air during SOAPEX-2, Atmos. Chem. Phys., 4, 839-856, 2004, http://www.atmos-chem-phys.net/ 4/839/2004/.
48. Stedman, J. R.: The predicted number of air pollution related deaths in the UK during the August 2003 heatwave, Atmos. Env., 38, 1087-1090, 2004.
49. 2 ratios during the Tropospheric OH Photochemistry Experiment: Measurement and theory, J. Geophys. Res., 102, 6379-6391, 1997.
50. Stockwell, W. R., Kirchner, F., and Kuhn, M.: A new mechanism for regional atmospheric chemistry modelling, J. Geophys. Res., 102, 25847-25879, 1997.
51. Tan, D., Faloona, I., Simpas, J. B., Brune, W., Shepson, P. B., Couch, T. L., Sumner, A. L., Carroll, M. A., Thornberry, T., Apel, E., Riemer, D., and Stockwell, W.: HOx budgets in a deciduous forest: results from the prophet summer campaign. J. Geophys. Res., 106, 24407-24427, 2001.
52. 2 uptake to aqueous aerosol: Mass accommodation coefficients and net reactive loss, J. Geophys. Res., 110, Art. No. D08309, 2005.
53. Thornton, J. A., Wooldridge, P. J., Cohen, R. C., Martinez, M., Harder H., Brune, W. H., Williams, E. J., Roberts, J. M., Fehsenfeld, F. C., Hall, S. R., Shelter, R. E., Wert, B. P., and Fried, A.: Ozone production rates as a function of NOx abundances and HOx production rates in the Nashville urban plume, JGR, 107, NO. D12, 4146, 10.1029/2001JD000932, 2002.
54. 3, J. Geophys. Res., 108, doi:10.1029/2001JD001255, 2003.