Photochemical ozone production in the rural southeastern United States during the 1990 Rural Oxidants in the Southern Environment (ROSE) program

Journal of Geophysical Research Atmospheres

Volumn 103, Issue D17, 1998, Pages 22491-22508

  Frost, G J ^a,b   Trainer, M ^a   Allwine, G ^c   Buhr, M P ^a,b,d   Calvert, J G ^e   Cantrell, C A ^e   Fehsenfeld, F C ^a,b   Goldan, P D ^a   Herwehe, J ^a   Hubler G ^a,b   Kuster, W C ^a   Martin, R ^c,f   McMillen, R T ^a   Montzka, S A ^a,g   Norton, R B ^a   Parrish, D D ^a   Ridley, B A ^e   Shetter, R E ^e   Walega, J G ^e   Watkins, B A ^a,b   Westberg, H H ^c   Williams, E J ^a,b   more..

^a NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^b UNIVERSITY OF COLORADO   (United States)

^c Washington State University   (United States)

^d Regional Air Quality Council   (United States)

^e NATIONAL CENTER FOR ATMOSPHERIC RESEARCH   (United States)

^f NEW MEXICO INSTITUTE OF MINING AND TECHNOLOGY   (United States)

^g EARTH SYSTEM RESEARCH LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOGENIC MATERIAL; NITROGEN OXIDES; OZONE; PHOTOCHEMISTRY; RURAL AREA;

ALABAMA; UNITED STATES;

EID: 0032552718     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/98JD00881     Document Type: Article

References (62)

1. Angevine, W. M., M. Trainer, D. D. Parrish, M. P. Buhr, F. C. Fehsenfeld, and G. L. Kok, Wind profiler mixing depth and entrainment measurements with chemical applications, paper presented at 8th Joint Conference on Applications of Air Pollution Meteorology With A&WMA, Am. Meteorol. Soc., Nashville, Tenn., 1994.
2. Atkinson, R., Gas-phase tropospheric chemistry of organic compounds, J. Phys. Chem. Ref. Data, Monogr. 2, 1994.
3. 2 photooxidations suitable for inclusion in atmospheric simulation models, Atmos. Environ., 16, 1341-1355, 1982.
4. Berkowitz, C. M., and W. J. Shaw, Airborne measurements of boundary layer chemistry during the Southern Oxidants Study: A case study, J. Geophys. Res., 102, 12,795-12,804, 1997.
5. Bertman, S. B., J. M. Roberts, D. D. Parrish, M. P. Buhr, P. D. Goldan, W. C. Kuster, and F. C. Fehsenfeld, Evolution of alkyl nitrates with air mass age, J. Geophys. Res., 100, 22,805-22,813, 1995.
6. Bey, I., B. Aumont, and G. Toupance, The nighttime production of OH radicals in the continental troposphere, Geophys. Res. Lett., 24, 1067-1070, 1997.
7. Buhr, M., et al., Evaluation of ozone precursor source types using principal component analysis of ambient air measurements in rural Alabama, J. Geophys. Res., 100, 22,853-22,860, 1995.
8. Cantrell, C. A., et al., Peroxy radicals in the ROSE Experiment: Measurement and theory, J. Geophys. Res., 97, 20,671-20,686, 1992.
9. Cantrell, C. A., R. E. Shetter, J. A. Lind, A. H. McDaniel, J. G. Calvert, D. D. Parrish, F. C. Fehsenfeld, M. P. Buhr, and M. Trainer, An improved chemical amplifier technique for peroxy radical measurements, J. Geophys. Res., 98, 2897-2909, 1993a.
10. Cantrell, C. A., et al., Peroxy radicals as measured in ROSE and estimated from photostationary state deviations, J. Geophys. Res., 98, 18,355-18,366, 1993b.
11. Cantrell, C. A., R. E. Shetter, T. M. Gilpin, J. G. Calvert, F. L. Eisele, and D. J. Tanner, Peroxy radical concentrations measured and calculated from trace gas measurements in the Mauna Loa Observatory Photochemistry Experiment 2, J. Geophys. Res., 101, 14,653-14,664, 1996.
12. Carter, W. P. L., Condensed atmospheric photooxidation mechanisms for isoprene, Atmos. Environ., 30, 4275-4290, 1996.
13. x, Int. J. Chem. Kinet., 28, 497-530, 1996.
14. Chameides, W. L., and D. D. Davis, Iodine: Its possible role in tropospheric photochemistry, J. Geophys. Res., 85, 7383-7398, 1980.
15. 2/NO ratios in tropospheric air sampled during the NASA GTE/CITE-2 field study, J. Geophys. Res., 95, 10,235-10,247, 1990.
16. Chatfield, R. B., and P. J. Crutzen, Are there interactions of iodine and sulfur species in marine air photochemistry?, J. Geophys. Res., 95, 22,319-22,341, 1990.
17. 2-NO system based on airborne observations from the western and central North Pacific, J. Geophys. Res., 101, 2053-2072, 1996.
18. Dahlback, A., and K. Stamnes, A new spherical model for computing the radiation field available for photolysis and heating at twilight, Planet. Space Sci., 39, 671-683, 1991.
19. DeMore, W. B., S. P. Sander, D. M. Golden, R. F. Hampson, M. J. Kurylo, C. J. Howard, A. R. Ravishankara, C. E. Kolb, and M. J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, Evaluation number 11, JPL Pub., 94-26, 1994.
20. Dütsch, H. U., Vertical ozone distribution on a global scale, Pure Appl. Geophys., 116, 511-529, 1978.
21. 2 radicals with NO, Int. J. Chem. Kinet., 28, 731-740, 1996.
22. Friedman, R. M., J. Milford, R. Rapoport, N. Szabo, K. Harrison, S. V. Van Aller, R. W. Niblock, and J. Andelin, Urban ozone and the Clean Air Act: Problems and proposals for change, 160 pp., Off. of Technol. Assess., U.S. Congr., Washington, D. C., 1988.
23. Goldan, P. D., W. C. Kuster, F. C. Fehsenfeld, and S. A. Montzka, Hydrocarbon measurements in the southeastern United States: The Rural Oxidants in the Southern Environment (ROSE) program 1990, J. Geophys. Res., 100, 25,945-25,963, 1995.
24. Guenther, A., P. Zimmerman, L. Klinger, J. Greenberg, C. Ennis, K. Davis, W. Pollock, H. Westberg, G. Allwine, and C. Geron, Estimates of regional natural volatile organic compound fluxes from enclosure and ambient measurements, J. Geophys. Res., 101, 1345-1359, 1996.
25. 3 with a series of monoterpenes, J. Atmos. Chem., 18, 75-102, 1994.
26. Hauglustaine, D. A., S. Madronich, B. A. Ridley, J. G. Walega, C. A. Cantrell, R. E. Shetter, and G. Hübler, Observed and model-calculated photostationary state at Mauna Loa Observatory during MLOPEX 2, J. Geophys. Res., 101, 14,681-14,696, 1996.
27. Heck, W. W., W. W. Cure, J. O. Rawlings, L. J. Zaragoza, A. S. Heagle, H. E. Heggestad, R. J. Kohut, L. W. Kress, and P. J. Temple, Assessing impacts of ozone on agricultural crops, II, Crop yield functions and alternative exposure statistics, J. Air Pollut. Control Assoc., 34, 810-817, 1984.
28. Jacob, D. J., J. A. Logan, G. M. Gardner, R. M. Yevich, C. M. Spivakovsky, S. C. Wofsy, S. Sillman, and M. J. Prather, Factors regulating ozone over the United States and its export to the global atmosphere, J. Geophys. Res., 98, 14,817-14,826, 1993.
29. Kirchner, F., and W. R. Stockwell, Effect of peroxy radical reactions on the predicted concentrations of ozone, nitrogenous compounds, and radicals, J. Geophys. Res., 101, 21,007-21,022, 1996.
30. Kleinman, L., et al., Ozone formation at a rural site in the southeastern United States, J. Geophys. Res., 99, 3469-3482, 1994.
31. Kleinman, L., Y.-N. Lee, S. R. Springston, J. H. Lee, L. Nunnermacker, J. Weinstein-Lloyd, X. Zhou, and L. Newman, Peroxy radical concentration and ozone formation rate at a rural site in the southeastern United States, J. Geophys. Res., 100, 7263-7273, 1995.
32. 2 during the Mauna Loa Observatory Photochemistry Experiment 2, J. Geophys. Res., 101, 14,613-14,629, 1996.
33. Lee, J. H., D. F. Leahy, I. N. Tang, and L. Newman, Measurement and speciation of gas phase peroxides in the atmosphere, J. Geophys. Res., 98, 2911-2915, 1993.
34. Lee, Y.-N., X. Zhou, and K. Hallock, Atmospheric carbonyl compounds at a rural southeastern U.S. site, J. Geophys. Res., 100, 25,933-25,944, 1995.
35. Lenschow, D. H., The measurement of air velocity and temperature using the NCAR Buffalo aircraft measuring system, NCAR Tech. Note NCAR-TN/EDD-74, Natl. Cent. for Atmos. Res., Boulder, Colo., 1972.
36. Lenschow, D. H., R. Pearson Jr., and B. B. Stankov, Measurements of ozone vertical flux to ocean and forest, J. Geophys. Res., 87, 8833-8837, 1982.
37. Lin, X., M. Trainer, and S. C. Liu, On the nonlinearity of the tropospheric ozone production, J. Geophys. Res., 93, 15,879-15,888, 1988.
38. Lin, X., B. A. Ridley, J. Walega, G. F. Hübler, S. A. McKeen, E.-Y. Hsie, M. Trainer, F. C. Fehsenfeld, and S. C. Liu, Parameterization of subgrid scale convective cloud transport in a mesoscale regional chemistry model, J. Geophys. Res., 99, 25,615-25,630, 1994.
39. Liu, S. C., M. Trainer, F. C. Fehsenfeld, D. D. Parrish, E. J. Williams, D. W. Fahey, G. Hübler, and P. C. Murphy, J. Geophys. Res., 92, 4191-4207, 1987.
40. x-air photooxidations of isoprene and α-pinene under ambient conditions, Atmos. Environ., 17, 1931-1950, 1983.
41. Logan, J. A., M. J. Prather, S. C. Wofsy, and M. B. McElroy, Tropospheric chemistry: A global perspective, J. Geophys. Res., 86, 7210-7254, 1981.
42. Lurmann, F. W., A. C. Lloyd, and R. Atkinson, A chemical mechanism for use in long-range transport/ acid deposition computer modeling, J. Geophys. Res., 91, 10,905-10,936, 1986.
43. 2 photodissociation and U.V. radiometer measurements, Atmos. Environ., 21, 569-578, 1987.
44. McKeen, S. A., E.-Y. Hsie, M. Trainer, R. Tallamraju, and S. C. Liu, A regional model study of the ozone budget in the eastern United States, J. Geophys. Res., 96, 10,809-10,845, 1991a.
45. McKeen, S. A., E.-Y. Hsie, and S. C. Liu, A study of the dependence of rural ozone on ozone precursors in the eastern United States, J. Geophys. Res., 96, 15,377-15,394, 1991b.
46. McKeen, S. A., et al., Photochemical modeling of hydroxyl and its relationship to other species during the tropospheric OH photochemistry experiment, J. Geophys. Res., 102, 6467-6493, 1997.
47. Montzka, S. A., M. Trainer, P. D. Goldan, W. C. Kuster, and F. C. Fehsenfeld, Isoprene and its oxidation products, methyl vinyl ketone and methacrolein, in the rural troposphere, J. Geophys. Res., 98, 1101-1111, 1993.
48. Montzka, S. A., M. Trainer, W. M. Angevine, and F. C. Fehsenfeld, Measurements of 3-methyl furan, methyl vinyl ketone, and methacrolein at a rural forested site in the southeastern United States, J. Geophys. Res., 100, 11,393-11,401, 1995.
49. Oort, A. H., and E. M. Rasmussen, Atmospheric circulation statistics, Prof. Pap. 5, NOAA Rep. 72032903, Natl. Oceanic and Atmos. Admin., Silver Spring, Md., 1971.
50. 3 photostationary state at Niwot Ridge, Colorado, J. Geophys. Res., 91, 5361-5370, 1986.
51. x in the boundary layer, Geophys. Res. Lett., 23, 3727-3730, 1996.
52. 3 to 12 km altitude during the summer monsoon season over New Mexico, J. Geophys. Res., 99, 25,519-25,534, 1994.
53. Ridley, B. A., J. G. Walega, F. E. Grahek, M. Trainer, G. F. Hübler, X. Lin, and F. C. Fehsenfeld, Measurements of reactive nitrogen and ozone to 5 km altitude in June 1990 over the southeastern United States, J. Geophys. Res., 103, 8369-8388, 1998.
54. Schultz, M., Die Bedeutung von Stickoxiden für die Ozonbilanz in Reinluftgebieten, Ph.D. thesis, Univ. of Wuppertal, Wuppertal, Germany, 1995.
55. 2 photolysis rate coefficient during the Mauna Loa Observatory Photochemistry Experiment, J. Geophys. Res., 97, 10,349-10,359, 1992.
56. Southern Oxidants Study, 1993 Data analysis workshop report, edited by F. Fehsenfeld, J. Meagher, and E. Cowling, N. C. State Univ., Raleigh, 1994.
57. Trainer, M., E. Y. Hsie, S. A. McKeen, R. Tallamraju, D. D. Parrish, F. C. Fehsenfeld, and S. C. Liu, Impact of natural hydrocarbons on hydroxyl and peroxy radicals at a remote site, J. Geophys. Res., 92, 11,879-11,894, 1987.
58. Trainer, M., et al., Observations and modeling of the reactive nitrogen photochemistry at a rural site, J. Geophys. Res., 96, 3045-3063, 1991.
59. U.S. Environmental Protection Agency (EPA), Air quality criteria for ozone and other photochemical oxidants, Rep. EPA-600/8-78-004, Washington, D.C., 1978.
60. 2 + NO reaction using chemical ionization mass spectrometry, J. Phys. Chem., 100, 13,624-13,628, 1996.
61. 2 + NO reaction using chemical ionization mass spectrometry, J. Phys. Chem., 99, 12,829-12,834, 1995.
62. Watkins, B. A., D. D. Parrish, S. Buhr, R. B. Norton, M. Trainer, J. E. Yee, and F. C. Fehsenfeld, Factors influencing the concentration of gas phase hydrogen peroxide during the summer at Kinterbish, Alabama, J. Geophys. Res., 100, 22,841-22,851, 1995.