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Crystal data for Δ-1PF6: Bruker CCD diffractometer, C22H32CuF6N4P, fw, 561.03, 0.4 x 0.1 x 0.05 mm, orthorhombic, space group P212 12, a, 16.921(3) Å, b, 34.176(6) Å, c, 8.4534(15) Å, α, 90°, β, 90°, γ, 90°, V, 4888.4(15) Å3, Dc, 1.525 g cm-3, Z, 4, monochromated Mo Kα radiation, φ and ω scan methods, T, 100(2) K, μ, 1.023 mm-1, 76 923 reflections collected, 11 939 independent reflections (Rint, 0.0480, GOF, 1.065, R [I > 2σ(I, 0.0415, wR, 0.1013 refined against |F2
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2|).
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4), but in all cases, Λ-1X is the single product isolated.
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4), but in all cases, Λ-1X is the single product isolated.
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II complexes were formed upon reaction with metallic Zn, as ascertained by NMR spectroscopy.
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II complexes were formed upon reaction with metallic Zn, as ascertained by NMR spectroscopy.
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(b) Lee, C.; Yang, W.; Parr, R. G. Phys. Rev. B 1988, 37, 785.
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Lee, C.1
Yang, W.2
Parr, R.G.3
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