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33845988491
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H 4.76 (d, J = 7.2 Hz, H-1′), 4.37 (dd, J = 7.2, 8.8 Hz, H-2′), 4.18 (dd, J = 3.6, 8.8 Hz, H-3′), 4.32 (br s, H-4′), 4.21 (dd, J = 3.2, 11.2 Hz, H-5′β), 3.71 (overlap, H-5′α).
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H 4.76 (d, J = 7.2 Hz, H-1′), 4.37 (dd, J = 7.2, 8.8 Hz, H-2′), 4.18 (dd, J = 3.6, 8.8 Hz, H-3′), 4.32 (br s, H-4′), 4.21 (dd, J = 3.2, 11.2 Hz, H-5′β), 3.71 (overlap, H-5′α).
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13
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33845986107
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13C NMR (CDCl3, 600 MHz) δC 28.2 (C-1, 30.6 (C-2, 88.1 (C-3, 41.1 (C-4, 48.1 (C-5, 23.2 (C-6, 25.2 (C-7, 41.2 (C-8, 132.2 (C-9, 134.5 (C-10, 37.9 (C-11, 31.7 (C-12, 45.2 (C-13, 42.3 (C-14, 48.9 (C-15, 220.0 (C-16, 60.9 (C-17, 17.8 (C-18, 68.4 (C-19, 27.2 (C-20, 21.0 (C-21, 50.8 (C-22, 213.0 (C-23, 53.6 (C-24, 70.1 (C-25, 29.5 (C-26, 29.6 (C-27, 18.9 (C-28, 24.7 (C-29, 14.7 (C-30, 105.3 (C-1′, 73.0 (C-2′, 71.7 (C-3′, 68.2 (C-4′, 65.6 (C-5′, 1H NMR (CDCl3, 600 MHz, most of the signals appeared broad) OH 4.36 (br d, J, 5.4 Hz, H-1′, 3.91 (br, H-4′, H-5′e, 3.72 (br, H-2′, 3.67 (br, H-3′, 3.53 (overlap, H-5′a, H-19a, 3.47 (br, H-19b, 3.30 (br, H-3, 3.21 (br d, J, 13.8 Hz, H-22a, 2.71 (brd, J, 13.2 Hz, H-1β, 2.66 (d, J, 18.0 Hz, H-24a, 2.56 (d, J, 18.0 Hz, H-24b, 2.34 br overl
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3, 600 MHz, most of the signals appeared broad) OH 4.36 (br d, J = 5.4 Hz, H-1′), 3.91 (br, H-4′, H-5′e), 3.72 (br, H-2′), 3.67 (br, H-3′), 3.53 (overlap, H-5′a, H-19a), 3.47 (br, H-19b), 3.30 (br, H-3), 3.21 (br d, J = 13.8 Hz, H-22a), 2.71 (brd, J = 13.2 Hz, H-1β), 2.66 (d, J = 18.0 Hz, H-24a), 2.56 (d, J = 18.0 Hz, H-24b), 2.34 (br overlap, H-8, H-21, H-22b), 2.19 (d, J = 8.4 Hz, H-17), 2.17 (br d, J = 14.4 Hz, H-12β), 2.11 (d, J = 17.7 Hz, H-15β), 2.04 (br, H-2β), 1.92 (d, J = 17.7 Hz, H-15α), 1.88 (br, H-6β), 1.84 (br, H-12α), 1.78 (br, H-5), 1.74 (br, H-1α), 1.52 (m, H-2α), 1.43 (br, H-7α), 1.25 (s, 3H-27), 1.23 (s, 3H-26), 1.22 (overlap, H-6α, H-7α), 1.07 (s, 3H-18), 1.01 (br overlap. 3H-21, 3H-29), 0.88 (s, 3H-28), 0.68 (s, 3H-30).
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14
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