Solution chemistry of a water-soluble η2-H2 ruthenium complex: Evidence for coordinated H2 acting as a hydrogen bond donor

Journal of the American Chemical Society

Volumn 128, Issue 49, 2006, Pages 15830-15835

  Szymczak, Nathaniel K ^a   Zakharov, Lev N ^a   Tyler, David R ^a  

^a UNIVERSITY OF OREGON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ENZYMES; HYDROGEN BONDS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; SOLUBILITY; WATER;

DIHYDROGEN HYDROGEN BONDING (DHHB); H-BOND ACCEPTORS; INTERMOLECULAR HYDROGEN BONDING; ROTATIONAL DYNAMICS;

RUTHENIUM COMPOUNDS;

HYDROGENASE; RUTHENIUM COMPLEX; SOLVENT;

ARTICLE; CHEMICAL STRUCTURE; HYDROGEN BOND; MOLECULAR DYNAMICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTON TRANSPORT; STRUCTURE ANALYSIS; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY;

CRYSTALLOGRAPHY, X-RAY; HYDROGEN; HYDROGEN BONDING; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; ORGANOMETALLIC COMPOUNDS; RUTHENIUM; SOLUBILITY; SOLUTIONS; SPECTROPHOTOMETRY, ULTRAVIOLET; STEREOISOMERISM; WATER;

EID: 33845435788     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja065532f     Document Type: Article

References (52)

1. Belkova, N. V.; Shubina, E. S.; Epstein, L. M. Acc. Chem. Res. 2005, 38, 624-631.
2. Bakhmutov, V. I. Eur. J. Inorg. Chem. 2005, 245-255.
3. Epstein, L. M.; Shubina, E. S. Coord. Chem. Rev. 2002, 231, 165-181.
4. Lee, J. C., Jr.; Peris, E.; Rheingold, A. L.; Crabtree, R. H. J. Am. Chem. Soc. 1994, 116, 11014-11019.
5. Lough, A. J.; Park, S.; Ramachandran, R.; Morris, R. H. J. Am. Chem. Soc. 1994, 116, 8356-8357.
6. 5 respectively.
7. Albinati, A. et al.; J. Am. Chem. Soc. 1993, 115, 7300-7312.
8. Van der Sluys, L. S.; Eckert, J.; Eisenstein, O.; Hall, J. H.; Huffman, J. C.; Jackson, S. A.; Koetzle, T. F.; Kubas, G. J.; Vergamini, P. J.; Caulton, K. G. J. Am. Chem. Soc. 1990, 112, 4831-4841.
9. Webster, C. E.; Gross, C. L.; Young, D. M.; Girolami, G. S.; Schultz, A. J.; Hall, M. B.; Eckert, J. J. Am. Chem. Soc. 2005, 127, 15091-15101.
10. Schlaf, M.; Lough, A. J.; Maltby, P. A.; Morris, R. H. Organometallics 1996, 15, 2270-2278.
11. Belkova, N. V.; Besora, M.; Epstein, L. M.; Lledos, A.; Maseras, F.; Shubina, E. S. J. Am. Chem. Soc. 2003, 125, 7715-7725.
12. Basallote, M. G.; Besora, M.; Duran, J.; Fernandez-Trujillo, M. J.; Lledos, A.; Manez, M. A.; Maseras, F. J. Am. Chem. Soc. 2004, 126, 2320-2321.
13. Belkova, N. V.; Ionidis, A. V.; Epstein, L. M.; Shubina, E. S.; Gruendemann, S.; Golubev, N. S.; Limbach, H.-H. Eur. J. Inorg. Chem. 2001, 1753-1761.
14. Fong, T. P.; Forde, C. E.; Lough, A. J.; Morris, R. H.; Rigo, P.; Rocchini, E.; Stephan, T. J. Chem. Soc. Dalton Trans. 1999, 4475-4486.
15. Gutsul, E. I.; Belkova, N. V.; Babakhina, G. M.; Epstein, L. M.; Shubina, E. S.; Bianchini, C.; Peruzzini, M.; Zanobini, F. Russ. Chem. Bull. 2003, 52, 1204-1206.
16. Braga, D.; De Leonardis, P.; Grepioni, F.; Tedesco, E. Inorg. Chim. Acta 1998, 273, 116-130.
17. Orlova, G.; Scheiner, S. J. Phys. Chem. A 1998, 102, 260-269.
18. Orlova, G.; Scheiner, S. J. Phys. Chem. A 1998, 102, 4813-4818.
19. Kovacs, G.; Schubert, G.; Joo, F.; Papai, I. Organometallics, 2005, 24, 3059-3065.
20. Chu, H. S.; Xu, Z.; Ng, S. M.; Lau, C. P.; Lin, Z. Eur. J. Inorg. Chem. 2000, 993-1000.
21. Gusev, D. G. J. Am. Chem. Soc. 2004, 126, 14249-14257.
22. Bautista, M. T.; Cappellani, E. P.; Drouin, S. D.; Morris, R. H.; Schweitzer, C. T.; Sella, A.; Zubkowski, J. J. Am. Chem. Soc. 1991, 113, 4876-4887.
23. Mathew, N.; Jagirdar, B. R.; Gopalan, R. S.; Kulkarni, G. U. Organometallics 2000, 19, 4506-4517.
24. Hamilton, D. G.; Crabtree, R. H. J. Am. Chem. Soc. 1988, 110, 4126-4133.
25. Maltby, P. A.; Schlaf, M.; Steinbeck, M.; Lough, A. J.; Morris, R. H.; Klooster, W. T.; Koetzle, T. F.; Srivastava, R. C. J. Am. Chem. Soc. 1996, 118, 5396-5407.
26. Luther, T. A.; Heinekey, D. M. Inorg. Chem. 1998, 37, 127-132.
27. Heinekey, D. M.; Lledos, A.; Lluch, J. M. Chem. Soc. Rev. 2004, 33, 175-182.
28. Hadzi, D.; Bratos, S. In The Hydrogen Bond: Recent Developments in Theory and Experiments; Schuster, P., Zundel, G., Sandorfy, C., Eds.; North-Holland: New York, 1976; pp 565-611.
29. Kubas, G. J. Metal Dihydrogen and σ-Bond Complexes: Structure, Theory and Reactivity; Kluwer Academic/Plenum: New York. 2001.
30. Sweany, R. L. In Transition Metal Hydrides; Dedieu, A. Ed.; VCH: New York, 1992; pp 65-101.
31. Tucker, E. E.; Lippert, E. In The Hydrogen Bond: Recent Developments in Theory and Experiments; Schuster, P., Zundel, G., Sandorfy, C., Eds.; North-Holland: New York, 1976; pp 791-830.
32. Organic fluorine has been purported to almost never accept a hydrogen bond (see ref. 33).
33. Dunitz, J. D.; Taylor, R. Chem.-Eur. J. 1997, 3, 89-98.
34. a determinations.
35. Bisson, A. P.; Hunter, C. A.; Morales, J. C.; Young, K. Chem.-Eur. J. 1998, 4, 845-851.
36. 8, an opposite but much smaller (∼40-80 ppb) trend was observed that is likely due to breaking up an ion-pair by a more polar titrant or to a dielectric effect.
37. Lagalante, A. F.; Jacobson, R. J.; Bruno, T. J. J. Org. Chem. 1996, 61, 6404-6406.
38. Szymczak, N. K.; Oelkers, A. B.; Tyler, D. R. Phys. Chem. Chem. Phys. 2006, 8, 4002-4008.
39. a value for pyridine N-oxide is 9.92 (in acetonitrile at 298 K: see ref. 40).
40. Kaczmarczyk, E.; Wrobel, R.; Liwo, A.; Chmurzynski, L. J. Mol. Struct. 1999, 477, 113-118.
41. Abragam, A. The Principles of Nuclear Magnetism; Oxford University Press: Oxford, 1961.
42. Bakhmutov, V. I. Practical NMR Relaxation for Chemists; John Wiley & Sons, Ltd: West Sussex, 2004.
43. Wamsler, T.; Nielsen, J. T.; Pedersen, E. J.; Schaumburg, K. J. Magn. Res. 1978, 31, 177-186.
44. Barnes, R. G.; Bloom, J. W. J. Chem. Phys. 1972, 57, 3082-3086.
45. Henry, R. M.; Shoemaker, R. K.; Dubois, D. L.; Dubois, M. R. J. Am. Chem. Soc. 2006, 129, 3002-3010.
46. Ayllon, J. A.; Gervaux, C.; Sabo-Etienne, S.; Chaudret, B. Organometallics 1997, 16, 2000-2002.
47. Morris, R. H. In Recent Advances in Hydride Chemistry, Peruzzini, M., Poli, R., Eds.; Elsevier: Amsterdam, 2001; pp 1-38.
48. Papish, E. T.; Magee, M. P.; Norton, J. R. In Recent Advances in Hydride Chemistry; Peruzzini, M., Poli, R., Eds.; Elsevier: Amsterdam, 2001; pp 39-74.
49. Miller, W. K.; Gilbertson, J. D.; Leiva-Paredes, C.; Bernatis, P. R.; Weakley, T. J. R.; Lyon, D. K.; Tyler, D. R. Inorg. Chem. 2002, 41, 5453-5465.
50. Hughes, R. P.; Lindner, D. C.; Rheingold, A. L.; Yap, G. P. A. Inorg. Chem. 1997, 36, 1726-1727.
51. Albers, M. O.; Ashworth, T. V.; Oosthuizen, H. E.; Singleton, E. Inorg. Synth. 1989, 26, 68-77.
52. Sheldrick, G. M. SADABS (2.01), Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin, U.S.A.