Direct measurements of rate constants and activation volumes for the binding of H2, D2, N2, C2H 4, and CH3CN to W(CO)3(PCy3) 2: Theoretical and experimental studies with time-resolved step-scan FTIR and UV-Vis spectroscopy

Journal of the American Chemical Society

Volumn 128, Issue 49, 2006, Pages 15728-15741

  Grills, David C ^a   Van Eldik, Rudi ^b   Muckerman, James T ^a   Fujita, Etsuko ^a  

^a BROOKHAVEN NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; FOURIER TRANSFORM INFRARED SPECTROSCOPY; PHOTOLYSIS; TOLUENE; ULTRAVIOLET SPECTROSCOPY;

ACTIVATION VOLUMES; INTERCHANGE MECHANISMS; LASER EXCITATION; PHOTOEJECTION;

RATE CONSTANTS;

HEXANE; LIGAND; METHYL GROUP; NITRILE; PHOSPHINE DERIVATIVE; SOLVENT; TOLUENE; TUNGSTEN DERIVATIVE;

ARTICLE; CHEMICAL BINDING; COMPLEX FORMATION; DENSITY FUNCTIONAL THEORY; ENTROPY; EQUILIBRIUM CONSTANT; INFRARED SPECTROSCOPY; LASER; LIGAND BINDING; MEASUREMENT; MOLECULAR INTERACTION; PHOTOLYSIS; PRESSURE; SIMULATION; ULTRAVIOLET SPECTROSCOPY;

EID: 33845409182     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja064627e     Document Type: Article

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