Enantioselectivities in Electron-Transfer and Excited State Quenching Reactions of a Chiral Ruthenium Complex Possessing a Helical Structure

Journal of Physical Chemistry A

Volumn 103, Issue 29, 1999, Pages 5645-5654

  Hamada, Taisuke ^a   Brunschwig, Bruce S ^b   Eifuku, Kenji ^a   Fujita, Etsuko ^b   Kórner, Manuela ^c   Sakaki, Shigeyoshi ^a   Van Eldik, Rudi ^c   Wishart, James F ^b  

^a KUMAMOTO UNIVERSITY   (Japan)

^b BROOKHAVEN NATIONAL LABORATORY   (United States)

^c UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000685423     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp991116o     Document Type: Article

References (68)

1. Lappin, A. G.; Marusak, R. Coord. Chem. Rev. 1991, 109, 125- 180.
2. Porter, G. B.; Sparks, R. H. Photochem. 1980, 13, 123-131.
3. Porter, G. B.; Sparks, R. H. J. Chem. Soc., Chem. Commun. 1979, 1094-1095.
4. Kaizu, Y.; Mori, T.; Kobayashi, H. J. Phys. Chem. 1985, 89, 332- 335.
5. Ohkubo, K.; Arikawa, Y. J. Mol. Catal. 1985, 33, 65-70.
6. Sakaki, S.; Satoh, T.; Ohkubo, K. New J. Chem. 1986, 10, 145- 147.
7. Kato, M.; Sasagawa, T.; Ishihara, Y.; Yamada, S.; Fujitani, S.; Kimura, M. J. Chem. Soc., Dalton Trans. 1994, 583-587.
8. Metcalf, D. H.; Bolender, J. P.; Driver, M. S.; Richardson, F. S. J. Phys. Chem. 1993, 97, 553-564.
9. Metcalf, D. H.; Snyder, S. W.; Demas, J. N.; Richardson, F. S. J. Am. Chem. Soc. 1990, 112, 5681-5695.
10. Rexwinkel, R. B.; Meskers, S. C. J.; Riehl, J. P.; Dekkers, H. P. J. M. J. Phys. Chem. 1992, 96, 1112-1120.
11. Rexwinkel, R. B.; Meskers, S. C. J.; Dekkers, H. P. J. M.; Riehl, J. P. J. Phys. Chem. 1992, 96, 5725-5733.
12. Rexwinkel, R. B.; Meskers, S. C. J.; Riehl, J. P.; Dekkers, H. P. J. M. J. Phys. Chem. 1993, 97, 3875-3884.
13. Ohkubo, K.; Fukushima, M.; Ohta, H.; Usui, S. J. Photochem. Photobiol. 1996, 98, 137-140.
14. Ohkubo, K.; Hamada, T.; Inaoka, T.; Ishida, H. Inorg. Chem. 1989, 28, 2021-2022.
15. Ohkubo, K.; Ishida, H.; Hamada, T.; Inaoka, T. Chem. Lett. 1989, 1545-1548.
16. Ohkubo, K.; Hamada, T; Ishida, H. J. Chem. Soc., Chem. Commun. 1993, 1423-1425.
17. Ohkubo, K.; Hamada, T.; Ishida, H.; Fukushima, M.; Watanabe, M.; Kobayashi, H. J. Chem. Soc., Dalton Trans. 1994, 239-241.
18. Ohkubo, K.; Hamada, T.; Fukushima, M. J. Mol. Catal. 1994, 89, L5-L10.
19. Hamada, T.; Sakaki, S.; Brunschwig, B. S.; Fujita, E.; Wishart, J. F. Chem. Lett. 1998, 1259-1260.
20. Sprintschnik, G.; Sprintschnik, H. W.; Kirsh, P. P.; Whitten, D. G. J. Am. Chem. Soc. 1977, 99, 4947.
21. 23
22. Ohkubo, K.; Hamada, T.; Watanabe, M. J. Chem. Soc., Chem. Commun. 1993, 1070-1072.
23. Hamada, T. Personal communication.
24. Lin, C.-T.; Böttcher, W.; Chou, M.; Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6536-6544.
25. Drake, A. F.; Gould, J. M.; Mason, S. F.; Rosini, C.; Woodley, F. Polyhedron 1983, 2, 537-538.
26. Janas, L; Norden, B. Nucl. Chem. Lett. 1976, 12, 43-47.
27. Dwyer, F. P.; Garvan, F. L. Inorg. Synth. 1960, 6, 192-194.
28. Dwyer, F. P.; Gyarfas, E. C.; Mellor, D. J. J. Phys. Chem. 1955, 59, 296-297.
29. Osvath, P.; Lappin, A. G. Inorg. Chem. 1987, 26, 195-202.
30. Gillard, R. D.; Mitchell, P. F.; Weick, C. F. J. Chem. Soc., Dalton Trans. 1974, 1635-1636.
31. Spitzer, M.; Gärtig, F.; van Eldik, R. Rev. Sci. Instrum. 1988, 59, 2092-2093.
32. Wishart, J. F.; van Eldik, R. Rev. Sci. Instrum. 1992, 63, 3224- 3225.
33. Takakuwo, T.; Konno, T.; Meguro, H. Anal. Sci. 1985, 1, 215- 218.
34. Calvert, J.; Pitts, J. N. Photochemistry; Wiley: New York, 1996; pp 783-786.
35. Sahami, S.; Weaver, M. J. J. Electroanal. Chem. 1981, 122, 171- 181.
36. Sahami, S.; Weaver, M. J. J. Electroanal. Chem. 1981, 122, 155- 170.
37. Tsiamis, C.; Cambanis, S.; Hadjikostas, C. Inorg. Chem. 1987, 26, 6, 26-32.
38. Ogino, H.; Ogino, K. Inorg. Chem. 1983, 22, 2208-2211.
39. Sutin, N.; Creutz, C. In Inorganic and Organomatallic Photochemistry; Wrighton, M. S., Ed.; American Chemical Society: Washington, D. C.; 1978; Vol. 168, pp 1-27.
40. Venturi, M.; Emmi, S.; Fuochi, P. G.; Mulazzani, Q. G. J. Phys. Chem. 1980, 84, 2160-2166.
41. Creutz, C.; Sutin, N. Inorg. Chem. 1976, 15, 496-499.
42. Creutz, C.; Sutin, N. J. Am. Chem. Soc. 1976, 98, 6384-6385.
43. Schwarz, H. A.; Dodson, R. W. J. Phys. Chem. 1989, 93, 409- 414.
44. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; Von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85-277.
45. Van Houten, J.; Watts, R. J. J. Am. Chem. Soc. 1975, 97, 3843- 3849.
46. Angel, S. M.; DeArmond, M. K.; Donohoe, R. J.; Hanck, K. W.; Wertz, D. W. J. Am. Chem. Soc. 1984, 106, 3688-3689.
47. Morris, D. E.; Hanck, K. W.; DeArmond, M. K. J. Am. Chem. Soc. 1983, 105, 3032-3038.
48. Sutin, N.; Brunschwig, B. S. In Mechanistic Aspects of Inorganic Reactions; Rorabacher, D. B., Endicott, J. F., Eds.; ACS Symposium Series 198; American Chemical Society: Washington, DC, 1982; Vol. 1989.
49. Sutin, N. Prog. Inorg. Chem. 1983, 30, 441-498.
50. Sutin, N. In Electron Transfer in Inorganic, Organic and Biological Systems; Bolton, J. R., Malaga, N., McLendon, G., Eds.; Advances in Chemistry Series 228; American Chemical Society: Washington, DC, 1991; Vol. 228, pp 25-43.
51. Geselowitz, D. A.; Taube, H. J. Am. Chem. Soc. 1980, 102, 4325- 4526.
52. Sachinidis, J. I.; Shalders, R. D.; Tregloan, P. A. Inorg. Chem. 1994, 33, 6180-6186.
53. -1 due to electrostriction is expected
54. Sachinidis, J. I.; Shalders, R. D.; Tregloan, P. A. Inorg. Chem. 1996, 35, 2497-2503.
55. Meyerstein, D.; Rabani, J.; Matheson, M. S.; Meisel, D. J. Phys. Chem. 1978, 82, 1879-1885.
56. Birks, J. B. Photophysics of Aromatic Molecules; Wiley-Interscience: New York, 1970; pp 518-570.
57. Förster, T. Discuss. Faraday Soc. 1959, 27, 7-17.
58. Dexter, D. L. J. Chem. Phys. 1953, 21, 836-850.
59. -1).
60. Tanabe, Y.; Sugano, S. J. Phys. Soc. Jpn. 1954, 9, 766-779.
61. Figgs, B. N. Introduction to Ligand Fields; Interscience: New York, 1966.
62. D is the lifetime of the ruthenium excited state (s), N is Avogadro's number, and r is the distance between the donor and acceptor centers (cm).
63. 64
64. Lange's Handbook of Chemistry, 11th ed.; Dean, J. A., Ed.; McGraw-Hill Book Co.: New York, 1974.
65. 3 complex using Cerius2 software from MSI gives a metal to metal distance of ≈7.4 Å.
66. -1.
67. Zahir, K.; Böttcher, W.; Haim, A. Inorg. Chem. 1985, 24, 1966- 1968.
68. Meisel, D.; Schmidt, K. H.; Meyerstein, D. Inorg. Chem. 1979, 18, 971-975.