12/10- and 11/13-mixed helices in α/γ- and β/γ- hybrid peptides containing C-linked carbo-γ-amino acids with alternating α- and β-amino acids

Journal of the American Chemical Society

Volumn 128, Issue 45, 2006, Pages 14657-14668

  Sharma, Gangavaram V M ^a   Jadhav, Vivekanand B ^a   Ramakrishna, Kallaganti V S ^a   Jayaprakash, Pagadala ^a   Narsimulu, Kongari ^a   Subash, Velaparthi ^a   Kunwar, Ajit C ^a  

^a INDIAN INSTITUTE OF CHEMICAL TECHNOLOGY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CROSSLINKING; MOLECULAR DYNAMICS; MOLECULAR STRUCTURE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTEINS;

CD SPECTROSCOPY; DIPEPTIDE; HELICAL PATTERNS; PEPTIDES;

AMINO ACIDS;

ALANINE; ALPHA AMINO ACID; AMINO ACID DERIVATIVE; BETA AMINO ACID; C LINKED CARBO BETA AMINO ACID; C LINKED CARBO GAMMA AMINO ACID; DIPEPTIDE; HYBRID PROTEIN; MANNOSE; UNCLASSIFIED DRUG; XYLOSE;

ARTICLE; CIRCULAR DICHROISM; NUCLEAR MAGNETIC RESONANCE; PEPTIDE ANALYSIS; PEPTIDE SYNTHESIS; PROTEIN CONFORMATION; PROTEIN SECONDARY STRUCTURE; STRUCTURE ANALYSIS;

AMINO ACIDS; MODELS, MOLECULAR; NUCLEAR MAGNETIC RESONANCE, BIOMOLECULAR; PEPTIDES; SPECTROMETRY, MASS, ELECTROSPRAY IONIZATION;

EID: 33750999348     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja064875a     Document Type: Article

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21. 3 solutions of the peptides. Small changes in amide proton chemical shift (ΔδNH) have been used as an indication for H-bonding.
22. Of the two isomers observed in peptides 6-8, the results pertaining to the major isomer are presented (minor isomer population was less than 10%).
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