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note
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Similar results were obtained in various solvents in the presence of Pd catalysts on various supports such as carbon, alumina, calcium carbonate, and barium sulfate. In general, in less polar solvents (such as cyclohexane and THF), the reactions were slower but cleaner; while in polar solvents (such as ethanol and DMF), the reactions were faster but they often produced alcohols as minor 1,2-reduction byproducts.
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51
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note
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This ratio may vary from 3:1 to 1:3 depending on the reaction condition; for example, epimerization proceeded faster than cyclization at lower temperature than at ambient temperature.
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note
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Crystallographic data (excluding structure factors) for the structure in this paper have been deposited with the Cambridge Crystallographic Data Centre as a supplementary publication number CCDC 622865. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1 EZ, UK [fax: +44 1223 336033 or e-mail: deposit@ccdc.cam.ac.uk].
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0000553555
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3 afforded trans-indanes; however, it was later found out that the reduction products were actually cis-indanes, see:
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3 afforded trans-indanes; however, it was later found out that the reduction products were actually cis-indanes, see:. Bauduin G., and Pietrasanta Y. Tetrahedron 29 (1973) 4225
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Tetrahedron
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Bauduin, G.1
Pietrasanta, Y.2
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