AgOC(CF3)3 and AgOSiiPr3 - Synthesis and characterization of a donor-free silver(I) alkoxide and silyl oxide

Angewandte Chemie - International Edition

Volumn 45, Issue 42, 2006, Pages 6997-7000

  Reisinger, Andreas ^a   Himmel, Daniel ^a   Krossing, Ingo ^a  

^a UNIVERSITY OF FREIBURG   (Germany)

Author keywords

Fluorinated ligands; Silver; Structure elucidation X ray diffraction

Indexed keywords

CHEMICAL VAPOR DEPOSITION; ORGANOMETALLICS; SYNTHESIS (CHEMICAL); X RAY DIFFRACTION ANALYSIS;

ALKOXIDES; FLUORINATED LIGANDS; SILYL OXIDE; STRUCTURE ELUCIDATION;

SILVER COMPOUNDS;

EID: 33750624939     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200600805     Document Type: Article

References (48)

1. L. G. Hubert-Pfalzgraf, Coord. Chem. Rev. 1998, 178-180, 967;
2. L. G. Hubert-Pfalzgraf, H. Guillon, Appl. Organomet. Chem. 1998, 12, 221;
3. D. C. Bradley, Chem. Rev. 1989, 89, 1317;
4. M. Veith, S. Weidner, K. Kunze, D. Kaefer, J. Hans, V. Huch, Coord. Chem. Rev. 1994, 137, 297.
5. H. Schmidbaur, J. Adlkofer, A. Shiotani, Chem. Ber. 1972, 105, 3389.
6. T. Tsuda, T. Hashimoto, T. Saegusa, J. Am. Chem. Soc. 1972, 94, 958.
7. T. Greiser, E. Weiss, Chem. Ber. 1976, 109, 3142.
8. M. J. McGeary, R. C. Wedlich, P. S. Coan, K. Folting, K. G. Caulton, Polyhedron 1992, 11, 2459.
9. K. W. Terry, C. G. Lugmair, P. K. Gantzel, T. D. Tilley, Chem. Mater. 1996, 8, 274.
10. C. Lopes, M. Hakansson, S. Jagner, Inorg. Chem. 1997, 36, 3232.
11. M. Hakansson, C. Lopes, S. Jagner, Inorg. Chim. Acta 2000, 304, 178.
12. I. J. Drake, K. L. Fujdala, S. Baxamusa, A. T. Bell, T. D. Tilley, J. Phys. Chem. B 2004, 108, 18421;
13. K. L. Fujdala, I. J. Drake, A. T. Bell, T. D. Tilley, J. Am. Chem. Soc. 2004, 126, 10864;
14. P. M. Jeffries, G. S. Girolami, Chem. Mater. 1989, 1, 8.
15. M. Veith, K. L. Woll, Chem. Ber. 1993, 126, 2383.
16. R. L. Geerts, J. C. Huffman, K. Folting, T. H. Lemmen, K. G. Caulton, J. Am. Chem. Soc. 1983, 105, 3503;
17. M. Hakansson, C. Lopes, S. Jagner, Organometallics 1998, 17, 210.
18. C. Lopes, M. Hakansson, S. Jagner, Inorg. Chim. Acta 1997, 254, 361.
19. T. H. Lemmen, G. V. Goeden, J. C. Huffman, R. L. Geerts, K. G. Caulton, Inorg. Chem. 1990, 29, 3680.
20. B. R. Sutherland, K. Folting, W. E. Streib, D. M. Ho, J. C. Huffman, K. G. Caulton, J. Am. Chem. Soc. 1987, 109, 3489;
21. S. Komiya, M. Iwata, T. Sone, A. Fukuoka, J. Chem. Soc. Chem. Commun. 1992, 1109.
22. D. A. Edwards, R. M. Harker, M. F. Mahon, K. C. Molloy, J. Chem. Soc. Dalton Trans. 1997, 3509.
23. T. J. Barbarich, S. T. Handy, S. M. Miller, O. P. Anderson, P. A. Grieco, S. H. Strauss, Organometallics 1996, 15, 3776;
24. S. M. Ivanova, B. G. Nolan, Y. Kobayashi, S. M. Miller, O. P. Anderson, S. H. Strauss, Chem. Eur. J. 2001, 7, 503;
25. I. Krossing, H. Brands, R. Feuerhake, S. Koenig, J. Fluorine Chem. 2001, 112, 83;
26. I. Krossing, Chem. Eur. J. 2001, 7, 490;
27. I. Krossing, I. Raabe, Angew. Chem. 2004, 116, 2116;
28. Angew. Chem. Int. Ed. 2004, 43, 2066.
29. I. Krossing, A. Reisinger, Inorg. Chem. Focus II 2005, 65;
30. I. Krossing, J. Am. Chem. Soc. 2001, 123, 4603;
31. I. Krossing, I. Raabe, Angew. Chem. 2001, 113, 4544;
32. Angew. Chem. Int. Ed. 2001, 40, 4406;
33. T. S. Cameron, A. Decken, I. Dionne, M. Fang, I. Krossing, J. Passmore, Chem. Eur. J. 2002, 8, 3386;
34. I. Krossing, A. Bihlmeier, I. Raabe, N. Trapp, Angew. Chem. 2003, 42, 1569;
35. Angew. Chem. Int. Ed. 2003, 42, 1531;
36. I. Krossing, A. Reisinger, Angew. Chem. 2003, 115, 5725;
37. Angew. Chem. Int. Ed. 2003, 42, 5725;
38. M. Gonsior, I. Krossing, L. Müller, I. Raabe, M. Jansen, L. van Wüllen, Chem. Eur. J. 2002, 8, 4475.
39. -1 (m).
40. -1 (vs).
41. A. Reisinger, I. Krossing, unpublished results; a detailed discussion of the solvent-containing structure will take place in an upcoming full paper.
42. -1 (w).
43. J. T. Hill, J. Fluorine Chem. 1977, 9, 97.
44. 2O (33 %) or Ag (31 %) would be accompanied by a higher mass loss and, therefore, seems unlikely.
45. CCDC-299939 and CCDC-299940 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
46. -1, direct methods with SHELXS-97 (G. M. Sheldrick, SHELXS-97, Program for the Solution of Crystal Structures, Universität Göttingen, 1997),
47. int = 0.0206), 18 restraints, 430 parameters, R1 = 0.0190, wR2 (all data) = 0.0404, GOF = 1.275.
48. int = 0.0475), 271 parameter, R1 = 0.0352, wR2 (all data) = 0.0493, GOF = 1.133.