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Volumn 30, Issue 10, 2006, Pages 1420-1428

Scanning tunnelling microscopy of a foldamer prototype at the liquid/solid interface: Water/Au(111) versus 1-octanol/graphite

Author keywords

[No Author keywords available]

Indexed keywords

CATECHOL; GOLD; GRAPHITE; OCTANOL; WATER;

EID: 33749518563     PISSN: 11440546     EISSN: 13699261     Source Type: Journal    
DOI: 10.1039/b607660m     Document Type: Conference Paper
Times cited : (5)

References (39)
  • 34
    • 33749510205 scopus 로고    scopus 로고
    • Moreover, most likely, the molecules are not folded with a side-on orientation. If side on, intermolecular hydrogen bonding will not be optimized. Furthermore, as the alkyl chains are not very transmissive for tunnelling electrons, having a double layer of alkyl chains could hamper high quality imaging of the adsorbed layer as the tip might interact with the 'upper alkyl chains' under the given experimental conditions
    • Moreover, most likely, the molecules are not folded with a side-on orientation. If side on, intermolecular hydrogen bonding will not be optimized. Furthermore, as the alkyl chains are not very transmissive for tunnelling electrons, having a double layer of alkyl chains could hamper high quality imaging of the adsorbed layer as the tip might interact with the 'upper alkyl chains' under the given experimental conditions
  • 36
    • 33749519343 scopus 로고    scopus 로고
    • As the sample cell is not closed, the solvent evaporates too fast. Faradaic currents due to residual water mask the tunnelling current. Coating of the tip according to the procedure for EC-STM is also not ideal since ethanol might (partly) dissolve the coating
    • As the sample cell is not closed, the solvent evaporates too fast. Faradaic currents due to residual water mask the tunnelling current. Coating of the tip according to the procedure for EC-STM is also not ideal since ethanol might (partly) dissolve the coating
  • 38
    • 33749522173 scopus 로고    scopus 로고
    • As no clear images of the Au(111) lattice could be recorded, and therefore internal calibration is lacking, an accurate analysis of the parameters describing the molecular ordering is not provided
    • As no clear images of the Au(111) lattice could be recorded, and therefore internal calibration is lacking, an accurate analysis of the parameters describing the molecular ordering is not provided


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.