The first evidence for activation of exogenous O2 on a vanadium(IV) center: Synthesis and characterization of a peroxo vanadium(V) complex with hydrotris(3,5-diisopropylpyrazol-1-yl)-borate

Journal of the Chemical Society - Dalton Transactions

Volumn , Issue 9, 1999, Pages 1369-1371

  Kosugi, Masahiro ^a   Hikichi, Shiro ^a   Akita, Munetaka ^a   Moro oka, Yoshihiko ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 33749094786     PISSN: 03009246     EISSN: None     Source Type: Journal    
DOI: 10.1039/a901054h     Document Type: Article

References (19)

1. Metal-Catalyzed Oxidations of Organic Compounds, eds. R. A. Sheldon and J. K. Kochi, Academic Press, New York, 1981;
2. special thematic issue of Chem. Rev. for "Metal-Dioxygen Complexes", Chem. Rev., 1994, 94, 567-856.
3. A. Butler, M. J. Clague and G. E. Meister, Chem. Rev., 1994, 94, 625;
4. C. Slebodnick, B. J. Hamastra and V. L. Pecoraro, Struct. Bonding (Berlin), 1997, 89, 51.
5. C. J. Chang, J. A. Labinger and H. B. Gray, Inorg. Chem., 1997, 36, 5927.
6. 2 has been reported. However, the origin of the oxygen atoms of the peroxide ligand has not been revealed: M. Shao, X. Dong and Y. Tang, Sci. Sinica, Ser. B (Engl. Ed.), 1988, 31, 789.
7. Co-OOR: S. Hikichi, H. Komatsuzaki, M. Akita and Y. Moro-oka, J. Am. Chem. Soc., 1998, 120, 4699;
8. Co-, Ni-oxo: S. Hikichi, M. Yoshizawa, Y. Sasakura, M. Akita and Y. Moro-oka, J. Am. Chem. Soc., 1998, 120, 10567;
9. Mn-OO(R): H. Komatsuzaki, Y. Nagasu, K. Suzuki, T. Shibasaki, M. Satoh, F. Ebina, S. Hikichi, M. Akita and Y. Moro-oka. J. Chem. Soc., Dalton Trans., 1998, 511;
10. H. Komatsuzaki, M. Satoh, N. Sakamoto, S. Hikichi, M. Akita and Y. Moro-oka, Inorg. Chem., 1998, 37, 6554;
11. Fe-catecholate oxygenation: T. Ogihara, S. Hikichi, M. Akita and Y. Moro-oka, Inorg. Chem., 1998, 37, 2614;
12. 2: M. Akita, T. Miyaji, S. Hikichi and Y. Moro-oka, Chem. Commun., 1998, 1005;
13. 2: Y. Takahashi, M. Hashimoto, S. Hikichi, M. Akita and Y. Moro-oka, submitted.
14. M. Kosugi, S. Hikichi, M. Akita and Y. Moro-oka, Inorg. Chem., submitted.
15. See for examples of six-coordinate cis-dioxo-V(v) complexes: D. C. Crans, A. D. Keramidas, S. S. Amin, O. P. Anderson and S. M. Miller, J. Chem. Soc., Dalton Trans., 1997, 2799;
16. D. C. Crans, A. D. Keramidas, M. Mahroof-Tahir, O. P. Anderson and M. M. Miller, Inorg. Chem., 1996, 35, 3599;
17. D. Schulz, T. Weyhermüller, K. Wieghardt and B. Nuber, Inorg. Chim. Acta, 1995, 240, 217.
18. M. H. Gubelmann and A. F. Williams, Struct. Bonding (Berlin), 1983, 55, 1.
19. Pri2 ligand reported by us: N. Kitajima, M. Osawa, M. Tanaka and Y. Moro-oka, J. Am. Chem. Soc., 1991, 113, 8952.