Unusual oxidation of phosphines employing water as the oxygen atom source and tris(benzene-1,2-dithiolate)molybdenum(VI) as the oxidant. A functional molybdenum hydroxylase analogue system

Inorganic Chemistry

Volumn 45, Issue 18, 2006, Pages 7357-7366

  Cervilla, Antonio ^a   Pérez Pla, Francisco ^a   Llopis, Elisa ^a   Piles, Maria ^a  

^a UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

MIXED FUNCTION OXIDASE; MOLYBDENUM; ORGANOMETALLIC COMPOUND; OXIDIZING AGENT; OXYGEN; PHOSPHINE DERIVATIVE; TRIS(BENZENE 1,2 DITHIOLATE)MOLYBDENUM(VI); TRIS(BENZENE-1,2-DITHIOLATE)MOLYBDENUM(VI); WATER;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CHEMISTRY; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; KINETICS; MASS FRAGMENTOGRAPHY; OXIDATION REDUCTION REACTION; SENSITIVITY AND SPECIFICITY; TIME;

CATALYSIS; CHROMATOGRAPHY, HIGH PRESSURE LIQUID; GAS CHROMATOGRAPHY-MASS SPECTROMETRY; KINETICS; MIXED FUNCTION OXYGENASES; MOLECULAR STRUCTURE; MOLYBDENUM; ORGANOMETALLIC COMPOUNDS; OXIDANTS; OXIDATION-REDUCTION; OXYGEN; PHOSPHINES; SENSITIVITY AND SPECIFICITY; TIME FACTORS; WATER;

EID: 33748800230     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic052161f     Document Type: Article

References (32)

1. Hille, R. Chem. Rev. 1996, 96, 2757-2816.
2. Doonan, C. J.; Stockert, A.; Hille, R.; George, G. N. J. Am. Chem. Soc. 2005, 127, 4518-4522.
3. Stiefel, E. I. J. Chem. Soc., Dalton Trans. 1997, 3915-3923.
4. Xia, M.; Dempski, R.; Hille. R. J. Biol. Chem. 1999, 274, 3323-3330.
5. Truglio, J. J.; Theis, K.; Leimkuhler, S.; Rappa, R.; Rajagopalan, K. V.; Kisher, C. Structure 2002, 10, 115-125.
6. Hille, R. Arch. Biochem. Biophy. 2005, 433, 107-116.
7. Das, K. S.; Chaudhury, P. K.; Biswas, D.; Sarkar, S. J. Am. Chem. Soc. 1994, 116, 9061-9070.
8. Xiao, Z.; Bruck, M. A.; Enemark, J. H.; Young, C. G.; Wedd, A. G. Inorg. Chem. 1996, 35, 7508-7515.
9. Enemark, J. H.; Cooney, J. J.; Wang, J.; Holm, R. H. Chem. Rev. 2004, 104, 1175-1200.
10. Doonan C. J.; Nielsen, D. J.; Smith, P. D.; White, J. M.; George, G. N.; Young, C. G. J. Am. Chem. Soc. 2006, 128, 305-316.
11. Huber, R.; Hof, P.; Duarte, R. O.; Moura, J. J. G.; Moura, I.; Liu, M.; LeGall, J.; Hille, R.; Archer, M.; Romão, M. Proc. Natl. Acad. Sci. U.S.A. 1996, 93, 8846.
12. (a) Mueller-Westerhoff, U. T.; Vance, B. In Comprehensive Coordination Chemistry; Wilkinson, G., Ed.; Pergamon Press: Oxford, England, 1987; Vol. 2, Chapter 16, Part 5.
13. (b) McCleverty, J. A. Prog. Inorg. Chem. 1968, 10, 1.
14. (c) Eisenberg, R. Prog. Inorg. Chem. 1970, 12, 295.
15. (d) Burns, R. P.; McAuliffe, C. A. Adv. Inorg. Chem. Radiochem. 1979, 22, 303.
16. Cervilla, A.; Pérez-Pla, F.; Llopis, E.; Piles, M. Dalton Trans. 2004, 1461-1465.
17. Cervilla, A.; Pérez-Pla, F.; Llopis, E. Chem. Commun. 2001, 2332-2333.
18. Cervilla, A.; Pérez-Pla, F.; Llopis, E.; Piles, M. Inorg. Chem. 2005, 44, 4106-4108.
19. Cervilla, A.; Llopis, E.; Marco, D.; Pérez-Pla, F. Inorg. Chem. 2001, 40, 6525-6528.
20. Kawashima, M.; Koyama, M.; Fujinaga, T. J. Inorg. Nucl. Chem. 1976, 38, 801-805.
21. Connors. K. E. In Chemical Kinetics. The Study of Reaction Rates in Solution; VCH Publishers: New York, 1990; p 317.
22. Young, C. G. In Biomimetic Oxidations Catalyzed by Transition Metal Complexes; Meunier, B., Ed.; Imperial College Press: London, 2000; pp 415-459.
23. Reynolds, M. S.; Berg, J. M.; Holm, R. H. Inorg. Chem. 1984, 23, 3057-3062.
24. Smith, P. D.; Millar, A. J.; Young, G. C. Ghosh, A.; Basu, P. J. Am. Chem. Soc. 2000, 122, 9298-9299.
25. Nemykin, V. N.; Davie, S. R.; Mondal. S.; Rubie, N.; Kirk, M. L.; Somogyi, A.; Basu, P. J. Am. Chem. Soc. 2002, 124, 756-757.
26. Holm, R. H. Coord.Chem. Rev. 1990, 100, 183-221.
27. Doonan, C. J.; Millar, A. J.; Nielsen, D. J.; Young, C. G. Inorg. Chem. 2005, 44, 4506-4514.
28. Argyropoulos, D.; Lyris, E.; Mitsopoulou, C. A.; Katakis, D. J. Chem. Soc., Dalton Trans. 1997, 615-621.
29. Ilich, P.; Hille, R. J. Phys. Chem. B 1999, 103, 5406-5412.
30. Stiefel, E. I.; Eisenberg, R.; Rosenberg, R. C.; Gray, H. B. J. Am. Chem. Soc. 1966, 88, 2956-2966.
31. Cervilla, A.; Corma. A.; Fornes, V.; Llopis, E.; Palanca, P.; Rey, F.; Ribera, A. J. Am. Chem. Soc. 1994, 116, 1595-1596.
32. Fomitchev, D. V.; Lim, B. S.; Holm, R. H. Inorg. Chem. 2001, 40, 645-654.