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note
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All new compounds were characterized by spectroscopic and mass data. Preparation of the initial mannose building blocks employed standard protocols.
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33748722950
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note
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Purification of 10 from the reaction by-products was accomplished by chromatography on silica gel. Purification of the deprotected compounds 11 and 12 was afforded by gel filtration using Sephadex G25 as the stationary phase and water as the eluent. However, 10 and 12 exist as an inseparable 5:1 and 2:1 α:β mixture of anomers, respectively.
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33748717920
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note
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72Na requires 2567). (Chemical Equation Presented)
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33
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