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33748282214
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6 Other 2,4-diphenylselenyl-1-butenes were prepared in a similar way.
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29
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33748271162
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note
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1-Phenylselenylcyclobutanol 3 - Typical Procedure. A solution of(diphenylmethylene)cyclopropane (1a, 0.062 g, 0.3 mmol), diphenyl diselenide (0.094 g, 0.3 mmol) and dibenzoyl peroxide (0.073 g, 0.3 mmol) in 5 mL of EtOH was irradiated with a tungsten lamp (300 W) in air. The temperature rose to 40 °C because of the irradiation. The reaction was monitored by TLC (eluent: PE). After 5 h, the reaction terminated, the solvent was evaporated under vacuum and the residue was subjected to preparative TLC (eluent: EtOAc) to afford 3a (0.075 g, 66%). Other 1-(phenylselenyl)cyclobutanols were prepared in a similar way.
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30
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33748275153
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note
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+], 198 (33), 183 (40), 105 (100).
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