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Volumn 62, Issue 17, 1997, Pages 6069-6076

Synthesis of mono-, di-, and trisilyl-substituted alkenes via the hydrosilylation of methylenecyclopropanes catalyzed by Rh(I) complexes

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; CYCLOPROPANE DERIVATIVE; METAL; RHODIUM DERIVATIVE; SILANE DERIVATIVE;

EID: 0030850587     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo961536z     Document Type: Article
Times cited : (90)

References (40)
  • 2
    • 0000880657 scopus 로고
    • Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Oxford: University Press: New York
    • (b) Armitage, D. A. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Oxford: University Press: New York, 1982, vol. 2, pp 117-120.
    • (1982) Comprehensive Organometallic Chemistry , vol.2 , pp. 117-120
    • Armitage, D.A.1
  • 3
    • 8544222125 scopus 로고
    • Organometallic Chemistry Reviews; Seyferth, D., Davies, A. G., Fisher, E. O., Normant J. F., Reutov, O. A., Eds.; Elsevier: Amsterdam
    • (c) Lukevics, E.; Belyakova, Z. V.; Pomerantseva, M. G.; Voronkov, M. G. Organometallic Chemistry Reviews. In Journal of Organometallic Chemistry Library; Seyferth, D., Davies, A. G., Fisher, E. O., Normant J. F., Reutov, O. A., Eds.; Elsevier: Amsterdam, 1977; vol. 5.
    • (1977) Journal of Organometallic Chemistry Library , vol.5
    • Lukevics, E.1    Belyakova, Z.V.2    Pomerantseva, M.G.3    Voronkov, M.G.4
  • 23
    • 8544236466 scopus 로고    scopus 로고
    • note
    • 7
  • 27
    • 8544284015 scopus 로고    scopus 로고
    • note
    • 7
  • 29
    • 8544266269 scopus 로고    scopus 로고
    • note
    • The structure of the compounds 13-15 was determined in comparison with authentic samples prepared by hydrogenation of the methylenecyclopropanes 1-3 in the presence of the Wilkinson catalyst.
  • 30
    • 8544269592 scopus 로고    scopus 로고
    • note
    • The amount of more stable isomers of mono- (16, 18) and disilylated (17, 19) olefins increased on prolonged contact with catalyst retained in the reaction mixture, as observed for hydrosilylation of compounds 1, 2. The isomerization of the double bond in the final products was also observed in the case of the methyl-substituted methylenecyclopropanes 5.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.