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The corresponding iodide was isolated in minor yield (70% vs. 79%) with respect to the tosylate.
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24
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29744467021
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note
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4 and concentrated in vacuo. The crude mixture was purified by column chromatography on silica gel.
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25
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29744453762
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note
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4 and concentrated in vacuo. The crude mixture was purified by column chromatography on silica gel.
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29744458611
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note
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With our procedure the propargylic sulfides 4a and 4b have been prepared in higher yields than in the other older procedures reported in ref. 2, 3 and 10a.
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