Demonstration by 2H ENDOR spectroscopy that myo-inositol binds via an alkoxide bridge to the mixed-valent diiron center of myo-inositol oxygenase

Journal of the American Chemical Society

Volumn 128, Issue 32, 2006, Pages 10374-10375

  Kim, Sun Hee ^a   Xing, Gang ^b   Bollinger Jr , J Martin ^b   Krebs, Carsten ^b   Hoffman, Brian M ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

^b PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BRIDGED COMPOUND; INOSITOL; INOSITOL OXYGENASE; IRON DERIVATIVE; OXIDE; OXYGENASE; UNCLASSIFIED DRUG; IRON;

ANISOTROPY; ARTICLE; DIPOLE; ELECTRON SPIN RESONANCE; ENZYME ACTIVE SITE; ENZYME CONFORMATION; HYDROGEN BOND; MOLECULAR INTERACTION; SIMULATION; SPECTRAL SENSITIVITY; SPECTROSCOPY; CHEMICAL MODEL; CHEMICAL STRUCTURE; CHEMISTRY; METABOLISM; METHODOLOGY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PROTEIN BINDING;

INOSITOL; INOSITOL OXYGENASE; IRON; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, CHEMICAL; MOLECULAR STRUCTURE; PROTEIN BINDING;

EID: 33747584909     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja063602c     Document Type: Article

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