Molecular and electronic structures of homoleptic nickel and cobalt complexes with non-innocent bulky diimine ligands derived from fluorinated 1,4-diaza-1,3-butadiene (DAD) and bis(arylimino)acenaphthene (BIAN)

European Journal of Inorganic Chemistry

Volumn , Issue 15, 2006, Pages 2985-2996

  Khusniyarov, Marat M ^a   Harms, Klaus ^a   Burghaus, Olaf ^a   Sundermeyer, Jörg ^a  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

Cobalt; EPR spectroscopy; Magnetochemistry; Nickel; Non innocent ligands; X ray diffraction

Indexed keywords

COBALT COMPOUNDS; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRONIC STRUCTURE; GROUND STATE; LIGANDS; METAL IONS; NICKEL COMPOUNDS; SYNTHESIS (CHEMICAL); X RAY CRYSTALLOGRAPHY;

ACENAPHTHENE; COBALT COMPLEXES; COBALT COMPLEXES (III); DIIMINE COMPLEXES; ELECTRONIC.STRUCTURE; EPR SPECTROSCOPY; MAGNETOCHEMISTRY; NON-INNOCENT LIGANDS; SYNTHESISED; X- RAY DIFFRACTIONS;

X RAY DIFFRACTION;

EID: 33747485299     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200600236     Document Type: Article

References (74)

1. A. L. Balch, R. H. Holm, J. Am. Chem. Soc. 1966, 88, 5201-5209.
2. a) M. D. Ward, J. A. McCleverty, J. Chem. Soc., Dalton Trans. 2002, 275-288;
3. b) A. Vlček, Jr., Coord. Chem. Rev. 2002, 230, 225-242;
4. c) P. Chaudhuri, K. Wieghardt, Prog. Inorg. Chem. 2001, 50, 151-216.
5. H. tom Dieck, H. Bruder, J. Chem. Soc., Chem. Commun. 1977, 24-25.
6. H. tom Dieck, M. Svoboda, J. Kopf, Z. Naturforsch. B: Chem. Sci. 1978, 33, 1381-1385.
7. D. von Walther, G. Kreisel, R. Kirmse, Z. Anorg. Allg. Chem. 1982, 487, 149-160.
8. R. Kirmse, J. Stach, D. von Walther, R. Boettcher, Z. Chem. 1980, 29, 224-225.
9. D. von Walther, Z. Anorg. Allg. Chem. 1974, 405, 8-18.
10. a) M. Svoboda, H. tom Dieck, Z. Naturforsch. B: Chem. Sci. 1981, 36, 814-822;
11. b) H. tom Dieck, M. Svoboda, T. Greiser, Z. Naturforsch. B: Chem. Sci. 1981, 36, 823-832.
12. a) H. Görls, D. Walther, J. Sieler, Cryst. Res. and Technol. 1987, 22, 1145-1151;
13. b) W. Bonrath, K. R. Pörschke, R. Mynott, C. Krüger, Z. Naturforsch. B: Chem. Sci. 1990, 45, 1647-1650.
14. a) D. Herebian, E. Bothe, F. Neese, T. Weyhermüller, K. Wieghardt, J. Am. Chem. Soc. 2003, 125, 9116-9128;
15. b) D. Herebian, K. E. Wieghardt, F. Neese, J. Am. Chem. Soc. 2003, 125, 10997-11005;
16. c) V. Bachler, G. Olbrich, F. Neese, K. Wieghardt, Inorg. Chem. 2002, 41, 4179-4193.
17. a) S.-M. Peng, Y. Wang, C.-K. Chiang, Acta Crystallogr., Sect. C: Cryst. Struct. Commun. 1984, 40, 1541-1542;
18. b) C.-S. Lee, T.-S. Hwang, Y. Wang, S.-M. Peng, C.-S. Hwang, J. Phys. Chem. 1996, 100, 2934-2941.
19. L. S. Hegedus, Transition Metals in the Synthesis of Complex Organic Molecules; University Science Books: Mill Valley, CA, 1994, p. 3.
20. C. K. Jörgensen, Oxidation Numbers and Oxidation States, Springer: Heidelberg, Germany, 1969.
21. P. Chaudhuri, C. N. Verani, E. Bill, E. Bothe, T. Weyhermüller, K. Wieghardt, J. Am. Chem. Soc. 2001, 123, 2213-2223.
22. M. M. Khusniyarov, K. Harms, J. Sundermeyer, J. Fluorine Chem. 2006, 127, 200-204.
23. a) R. van Asselt, C. J. Elsevier, W. J. J. Smeets, A. L. Spek, R. Benedix, Reel. Trav. Chim. Pays-Bas 1994, 113, 88-98;
24. b) R. van Asselt, C. J. Elsevier, C. Amatore, A. Jutand, Organometallics 1997, 16, 317-328;
25. c) L. K. Johnson, C. M. Killian, M. Brookhart, J. Am. Chem. Soc. 1995, 117, 6414-6415;
26. d) C. M. Killian, D. J. Tempel, L. K. Johnson, M. Brookhart, J. Am. Chem. Soc. 1996, 118, 11664-11665.
27. I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, V. K. Cherkasov, S. Dechert, H. Schumann, Russ. Chem. Bull. Int. Ed. 2004, 53, 2142-2147.
28. S. Blanchard, F. Neese, E. Bothe, E. Bill, T. Weyhermüller, K. Wieghardt, Inorg. Chem. 2005, 44, 3636-3656.
29. a) L. R. Chamberlain, L. D. Durfee, P. E. Fanwick, L. M. Kobriger, S. L. Latesky, A. K. McMullen, B. D. Steffey, I. P. Rothwell, K. Folting, J. C. Huffman, J. Am. Chem. Soc. 1987, 109, 6068-6076;
30. b) S. L. Latesky, A. K. McMullen, G. P. Niccolai, I. P. Rothwell, J. C. Huffman, Organometallics 1985, 4, 1896-1898;
31. c) W. A. Herrmann, M. Denk, W. Scherer, F.-R. Klingan, J. Organomet. Chem. 1993, 444, C21-C24;
32. d) K. Mashima, Y. Matsuo, K. Tani, Organometallics 1999, 18, 1471-1481;
33. e) R. L. Huff, S.-Y. S. Wang, K. A. Abboud, J. M. Boncella, Organometallics 1997, 16, 1779-1785;
34. f) K. Mashima, Y. Matsuo, K. Tani, Chem. Lett. 1997, 767-768;
35. g) T.-G. Ong, D. Wood, G. P. A. Yap, D. S. Richeson, Organometallics 2002, 21, 1-3;
36. h) Y. Matsuo, K. Mashima, K. Tani, Angew. Chem. Int. Ed. 2001, 40, 960-962;
37. i) J. Scholz, M. Dlikan, D. Strohl, A. Dietrich, H. Schumann, K.-H. Thiele, Chem. Ber. 1990, 123, 2279-2285;
38. j) J. Wunderle, J. Scholz, U. Baumeister, H. Hartung, Z. Kristallogr. 1996, 211, 423-424;
39. k) G. A. Hadi, J. Wunderle, K.-H. Thiele, R. Froehlich, Z. Kristallogr. 1994, 209, 372;
40. l) B. Richter, J. Scholz, J. Sieler, K.-H. Thiele, Angew. Chem. Int. Ed. Engl. 1995, 34, 2649-2651;
41. m) A. Merkoulov, K. Harms, J. Sundermeyer, Z. Anorg. Allg. Chem. 2005, 631, 2877-2880.
42. M. G. Gardiner, G. R. Hanson, M. J. Henderson, F. C. Lee, C. L. Raston, Inorg. Chem. 1994, 33, 2456-2461.
43. a) G. S. Hall, R. H. Soderberg, Inorg. Chem. 1968, 7, 2300-2303;
44. b) A. V. Reshetnikov, A. A. Sidorov, S. S. Talismanov, G. G. Aleksandrov, Y. A. Ustynyuk, S. E. Nefedov, I. L. Eremenko, I. I. Moiseev, Russ. Chem. Bull. (Translation Izv. Akad. Nauk SSSR, Ser. Khim.) 2000, 49, 1771-1774;
45. c) H.-Y. Cheng, C.-C. Lin, B.-C. Tzeng, S.-M. Peng, J. Chin. Chem. Soc. (Taipei) 1994, 41, 775-781.
46. M. M. Khusniyarov, K. Harms, J. Sundermeyer, B. Sarkar, W. Kaim, J. van Slageren, J. Fiedler, manuscript in preparation.
47. S. Lorenzo, G. R. Lewis, I. Dance, New J. Chem. 2000, 24, 295-304.
48. M. P. Thornberry, C. Slebodnick, P. A. Deck, F. R. Fronczek, Organometallics 2000, 19, 5352-5369.
49. a) M. J. Blandamer, J. Burgess, J. Fawcett, P. Guardado, C. D. Hubbard, S. Nuttall, L. J. S. Prouse, S. Radulovic, D. R. Russell, Inorg. Chem. 1992, 31, 1383-1389;
50. b) P. J. Daff, M. Etienne, B. Donnadieu, S. Z. Knottenbelt, J. E. McGrady, J. Am. Chem. Soc. 2002, 124, 3818-3819;
51. c) K.-H. Thiele, B. Richter, B. Neumuller, Z. Anorg. Allg. Chem. 1994, 620, 1627-1630;
52. d) M. N. Bochkarev, A. A. Trifonov, F. G. N. Cloke, C. I. Dalby, P. T. Matsunaga, R. A. Anderson, H. Schumann, J. Loebel, H. Hemling, J. Organomet. Chem. 1995, 486, 177-182;
53. e) B. Chaudret, H. Koster, R. Poilblanc, J. Chem. Soc., Chem. Commun. 1981, 266-268;
54. f) B. Chaudret, C. Cayret, H. Koster, R. Poilblanc, J. Chem. Soc., Dalton Trans. 1983, 941-945;
55. g) B. Richter, J. Scholz, B. Neumuller, R. Weimann, H. Schumann, Z. Anorg. Allg. Chem. 1995, 621, 365-372.
56. D. J. Szalda, C. Creutz, D. Mahajan, N. Sutin, Inorg. Chem. 1983, 22, 2372-2379.
57. S. Ye, B. Sarkar, F. Lissner, T. Schleid, J. van Slageren, J. Fiedler, W. Kaim, Angew. Chem. Int. Ed. 2005, 44, 2103-2106.
58. O. Kahn, Molecular Magnetism, VCH Publishers, New York, 1993.
59. C. J. O'Connor, Prog. Inorg. Chem. 1982, 29, 203-283.
60. a) I. L. Fedushkin, A. A. Skatova, V. K. Cherkasov, V. A. Chudakova, S. Dechert, M. Hummert, H. Schumann, Chem. Eur. J. 2003, 9, 5778-5783;
61. b) I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, V. K. Cherkasov, G. K. Fukin, M. A. Lopatin, Eur. J. Inorg. Chem. 2004, 388-393;
62. c) I. L. Fedushkin, N. M. Khvoinova, A. Y. Baurin, G. K. Fukin, V. K. Cherkasov, M. P. Bubnov, Inorg. Chem. 2004, 43, 7807-7815;
63. d) I. L. Fedushkin, A. A. Skatova, M. Hummert, H. Schumann, Eur. J. Inorg. Chem. 2005, 1601-1608.
64. J. C. Gordon, P. Shukla, A. H. Cowley, J. N. Jones, D. W. Keogh, B. L. Scott, Chem. Commun. 2002, 2710-2711.
65. L. G. L. Ward, D. M. Paul, Inorg. Synth. 1971, 13, 154-164.
66. M. Gasperini, F. Ragaini, S. Cenini, Organometallics 2002, 21, 2950-2957.
67. F. A. Cotton, E. A. Hillard, C. A. Murillo, X. Wang, Inorg. Chem. 2003, 42, 6063-6070.
68. PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, The Netherlands, A. L. Spek, 2005.
69. SHELX97 - Programs for Crystal Structure Analysis (Release 97-2). G. M. Sheldrick, Institute of Inorganic Chemistry, University of Göttingen, Göttingen, Germany, 1998.
70. A. Altomare, G. Cascarano, C. Giacovazzo, A. Guagliardi, J. Appl. Crystallogr. 1993, 26, 343-350.
71. T. Schleis, T. P. Spaniol, J. Okuda, J. Heinemann, R. Mülhaupt, J. Organomet. Chem. 1998, 569, 159-167.
72. T. Spaniel, H. Görls, J. Scholz, Angew. Chem. Int. Ed. 1998, 37, 1862-1865.
73. J. O. Liimatta, B. Lofgren, M. Miettinen, M. Ahlgren, M. Haukka, T. T. Pakkanen, J. Polym. Sci., Part A: Polym. Chem. 2001, 39, 1426-1434.
74. I. L. Fedushkin, A. A. Skatova, V. A. Chudakova, G. K. Fukin, S. Dechert, H. Schumann, Eur. J. Inorg. Chem. 2003, 3336-3346.