Analysis of the substituent distribution in the glucosyl units and along the polymer chain of hydroxypropylmethyl celluloses and statistical evaluation

Cellulose

Volumn 13, Issue 4, 2006, Pages 459-476

  Adden, Roland ^a   Müller, Romy ^a   Mischnick, Petra ^a  

^a TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

Cellulose ether; Hydroxypropylmethyl cellulose; Mass spectrometry; Substituent pattern in the polymer chain

Indexed keywords

ACETYLATION; HYDROLYSIS; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; MONOMERS; POLYMERS; REDUCTION;

GLUCOSYL UNITS; POLYMER CHAIN; SUBSTITUENT PATTERN;

CELLULOSE DERIVATIVES;

ACETYLATION; CELLULOSE ETHERS; HYDROLYSIS; HYDROXYPROPYL METHYL CELLULOSE; LIQUID CHROMATOGRAPHY; MONOMERS; REDUCTION; SUBSTITUENT DISTRIBUTION;

ACETYLATION; CELLULOSE; DESORPTION; HYDROLYSIS; LASER; MONOMER;

EID: 33747298207     PISSN: 09690239     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10570-005-9028-x     Document Type: Article

References (28)

1. Adden R., Mischnick P. (2005). A novel method for the analysis of the substitution pattern of O-methyl-α- and β-1,4-glucans by means of electrospray ionisation-mass spectrometry/collision induced dissociation. Int. J. Mass Spectrom. 242: 63-73
2. Adden R., Niedner W., Müller R. and Mischnick P. 2005. Comprehensive analysis of the substituent distribution in the glucosyl units and along the polymer chain of hydroxyethylmethyl celluloses and statistical evaluation. Anal. Chem. in press
3. Altaner C., Puls J., Saake B. (2003). Enzyme aided analysis of the substituent distribution along the chain of cellulose acetates regioselectively modified by the action of an Aspergillus niger acetylesterase. Cellulose 10:391-395
4. Arisz P.W., Kauw H.J.J., Boon J.J. (1995). Substituent distribution along the cellulose backbone in O-methylcelluloses using GC and FAB-MS for monomer and oligomer analysis. Carbohydr. Res. 271:1-14
5. Ciucanu I., Kerek F. (1984). A simple and rapid method for the permethylation of carbohydrates. Carbohydr. Res. 131: 209-217
6. Erler U., Mischnick P., Stein A., Klemm D. (1992). Determination of the substitution pattern of cellulose methyl ethers by HPLC and GLC - comparison of methods. Polym. Bull. 29: 349-356
7. Hakomori S. (1964). A rapid permethylation of glycolipid, and polysaccharide catalyzed by methylsulfinyl carbanion in dimethyl sulfoxide. J. Biochem. 55:205-208
8. Harvey D.J. (2000). Electrospray mass spectrometry and fragmentation of N-linked carbohydrates derivatized at the reducing terminus. J. Am. Soc. Mass Spectrom. 11: 900-915
9. Heinrich J., Mischnick P. (1997). Rapid method for the determination of the substitution pattern of O-methylated 1,4-glucans by high-pH anion-exchange chromatography with pulsed amperometric detection. J. Chromatogr. A 749: 41-45
10. Horner S., Puls J., Saake B., Klohr E.-A., Thielking H. (1999). Enzyme-aided characterisation of carboxymethylcellulose. Carbohydr. Polym. 40: 1-7
11. Jorgensen A.D., Picel K.C., Stamoudis V.C. (1990). Prediction of gas chromatography flame ionization detector response factors from molecular structure. Anal. Chem. 62: 683-689
12. Lazik W., Heinze T., Pfeiffer K., Albrecht G., Mischnick P. (2002). Starch derivatives of a high degree of functionatization. VI. Multistep carboxymethylation. J. Appl. Polym. Sci. 86:743-752
13. Lindberg B., Lindquist U., Stenberg O. (1987). Distribution of substituents in O-(2-hydroxyethyl)cellulose. Carbohydr. Res. 170: 207-214
14. Lindberg B., Lindquist U., Stenberg O. (1988). Distribution of substituents in O-ethyl-O-(2-hydroxy-ethyl)cellulose. Carbohydr. Res. 176: 137-144
15. Mischnick P., Kühn G. (1996). Model studies on methyl amyloses: correlation between reaction conditions and primary structure. Carbohydr. Res. 290: 199-207
16. Mischnick P. (1998). Characterization of polysaccharide derivatives with respect to substituent distribution in the monomer unit and the polymer chain. ACS Symp. Ser., Cell. Derivat. 688: 118-130
17. Mischnick P., Hennig C. (2001). A new model for the substitution patterns in the polymer chain of polysaccharide derivatives. Biomacromolecules 2:180-184
18. Mischnick P. (2001a). Specificity of microbial α-amylase and amyloglucosidase hydrolysis of methyl amylose. Starch/Stärke 53: 110-120
19. Mischnick-Lübbecke P., Krebber R. (1989). Characterization of cyclomalto-hexaose and -heptaose derivatives by the reductive-cleavage method. Carbohydr. Res. 187: 197-202
20. Momcilovic D., Schagerlöf H., Röme D., Jörntén-Karlsson M., Karlsson K.-E., Wittgren B., Tjerneld F., Wahlund K.-G., Brinkmalm G. (2005). Derivatization using dimethylamine for tandem mass spectrometric structure analysis of enzymatically and acidically depolymerized methyl cellulose. Anal. Chem. 77: 2948-2959
21. 13C-N.M.R spectra of hydrolyzed and methanolyzed O-methylcelluloses: Monomer composition and models for their description. Carbohydr. Res. 157:201-213
22. Scanlon J.T., Willis D.E. (1985). Calculation of flame ionization detector relative response factors using the effective carbon number concept. J. Chromatogr. Sci. 23: 333-340
23. Schmidt J., Weigel R., Burchard W., Richtering W. (1997). Methyl hydroxylpropyl cellulose-shear induced birefringence measurements in the semidilute region. Macromol. Symp. 120: 247-257
24. Spurlin H.M. (1939). Arrangement of substituents in cellulose derivatives. J. Am. Chem. Soc. 61: 2222-2227
25. Sweet D.P., Shapiro R.H., Albersheim P. (1975). Quantitative analysis by various G.L.C. response-factor theories for partially methylated and partially ethylated alditol acetates. Carbohydr. Res. 40: 217-225
26. Tezuka Y., Tsuchiya Y. (1995). Determination of substituent distribution in cellulose acetate by means of a 13C NMR study on its propanoated derivative. Carbohydr. Res. 273: 83-91
27. Tüting W., Wegemann K., Mischnick P. (2004a). Enzymatic degradation and electrospray tandem mass spectrometry as tools for determining the structure of cationic starches prepared by wet and dry methods. Carbohydr. Res. 339: 637-648
28. Tüting W., Adden R., Mischnick P. (2004b). Fragmentation pattern of regioselectively O-methylated maltooligosaccharides in electrospray ionisation-mass spectrometry/collision induced decay. Int. J. Mass Spectrom. 232: 107-115