Formation and decomposition of 3-chloropropane-1,2-diol esters in models simulating processed foods

Czech Journal of Food Sciences

Volumn 24, Issue 4, 2006, Pages 172-179

  Svejkovská, Blanka ^a   Doležal, Marek ^a   Velíšek, Jan ^a  

^a INSTITUTE OF CHEMICAL TECHNOLOGY   (Czech Republic)

Author keywords

3 chloropropane 1,2 diol; 3 MCPD; Bound 3 MCPD, 3 MCPD esters; Chloropropanols; Contaminants; Lipids

Indexed keywords

GLYCINE MAX;

EID: 33747162156     PISSN: 12121800     EISSN: None     Source Type: Journal    
DOI: 10.17221/3314-cjfs     Document Type: Article

References (15)

1. CERBULIS J., PARKS O.W., LIU R.H., PIOTROWSKI E.G., FARRELL H.M. jr. (1984): Occurrence of diesters of 3-chloro-1,2-propanediol in the neutral lipid fraction of goat's milk. Journal of Agricultural and Food Chemistry, 32: 474-476.
2. COLLIER P.D., CROMIE D.D.O., DAVIES A.P. (1991): Mechanism of formation of chloropropanols present in protein hydrolysates. Journal of the American Oil Chemists' Society, 68: 785-790.
3. DAVÍDEK J., VELÍŠEK J., KUBELKA V., JANÍČEK G., ŠIMICOVÁ Z. (1980): Glycerol chlorohydrins and their esters as products of the hydrolysis of tripalmitin, tristearin and triolein with hydrochloric acid. Zeitschrift für Lebensmittel-Untersuchung und - Forschung, 171: 14-17.
4. DIVINOVÁ V., SVEJKOVSKÁ B., DOLEŽAL M., VELÍŠEK J. (2004): Determination of free and bound 3-chloropropane-1,2-diol by gas chromatography with mass spectrometric detection using deuterated 3-chloropropane-1,2-diol as internal standard. Czech Journal of Food Sciences, 22: 182-189.
5. DOLEŽAL M., CHALOUPSKÁ M., DIVINOVÁ V., SVEJKOVSKÁ B., VELÍŠEK J. (2005): Occurrence of 3-chloropropane-1,2-diol and its esters in coffee. European Food Research and Technology, 221: 221-225.
6. HAMLET C.G., SADD P.A. (2004): Chloropropanols and their esters in cereal products. Czech Journal of Food Sciences, Special Issue, 22: 259-262.
7. HAMLET C.G., SADD P.A., CREWS C., VELÍŠEK J., BAXTER D.E. (2002): Occurrence of 3-chloro-propane-1,2-diol (3-MCPD) and related compounds in foods: a review. Food Addition and Contamination, 19: 619-631.
8. HAMLET G.G., SADD P.A., GRAY D.A. (2004): Generation of monochloropropanediols (MCPDs) in model dough systems. 2. Unleavened doughs. Journal of Agricultural and Food Chemistry, 52: 2067-2072.
9. KRAFT R., BRACHWITZ H., ETZOLD G., LANGEN P., ZÖPEL H.J. (1979): Massenspektrometrische Strukturuntersuchung stellungsisomerer Fettsäureester der Halogenpropandiole (Desoxyhalogen-glyceride). Journal für praktische Chemie, 321: 756-768.
10. ROBERT M.-C., OBERSON J.-M., STADLER R.H. (2004): Model studies on the formation of monochloropropanediols in the presence of lipase. Journal of Agricultural and Food Chemistry, 52: 5102-5108.
11. SVEJKOVSKÁ B., NOVOTNÝ O., DIVINOVÁ V., RÉBLOVÁ Z., DOLEŽAL M., VELÍŠEK J. (2004): Esters of 3-chloropropane-1,2-diol in foodstuffs. Czech Journal of Food Sciences, 22: 190-196.
12. VELÍŠEK J., DAVÍDEK J., KUBELKA V., JANÍČEK G., SVOBODOVÁ Z., ŠIMICOVÁ Z. (1980): New chlorine-containing organic compounds in protein hydrolysates. Journal of Agricultural and Food Chemistry, 28: 1142-1144.
13. VELÍŠEK J., DAVÍDEK J., ŠIMICOVÁ Z., SVOBODOVÁ Z. (1982): Glycerol chlorohydrins and their esters-reaction products of lipids with hydrochloric acid. Sborník VŠCHT v Praze, E53: 55-65.
14. WARNER K. (1998): Chemistry of Frying Fats. In: AKOH C.C., MIN D.B. (eds): Food Lipids. Marcel Dekker, Inc., New York, Basel: 167-180.
15. ZELINKOVÁ Z., SVEJKOVSKÁ B., VELÍŠEK J., DOLEŽAL M. (2006): Fatty acids estars of 3-chloropropane-1,2-diol in edible iols. Food Additives and Contaminants, in press.